纺织学报 ›› 2018, Vol. 39 ›› Issue (04): 93-99.doi: 10.13475/j.fzxb.20160802507

• 染整与化学品 • 上一篇    下一篇

超疏水气凝胶涂层超高分子量聚乙烯织物的制备与表征

  

  • 收稿日期:2016-08-10 修回日期:2017-12-25 出版日期:2018-04-15 发布日期:2018-04-20

Preparation and characterization of super hydrophobic aerogel coated ultra-high molecular weight polyethylene fabric

  • Received:2016-08-10 Revised:2017-12-25 Online:2018-04-15 Published:2018-04-20

摘要:

为提高超高分子量聚乙烯织物的疏水性能,基于荷叶效应原理,采用涂层方法在织物表面构筑纳米微米结构。将二氧化硅气凝胶分散于聚偏氟乙烯(PVDF)溶液中制成涂层液,并对超高分子量聚乙烯织物进行涂层处理。借助X 射线光电子能谱仪、扫描电子显微镜、原子力显微镜等测试织物表面的化学组成及微结构,并采用集灰实验测定织物的自清洁性能。结果表明:当PVDF质量分数为12%、二氧化硅气凝胶质量分数为8% 时,涂层织物表面的最大接触角为157.8°,滚动角为3°;涂层膜表面有微米级突起和纳米级颗粒状突起;水滴可将涂层后织物表面的污物带走,织物具有良好的自清洁效果。

关键词: 超高分子量聚乙烯织物, 拒水整理, 自清洁性能, 二氧化硅气凝胶, 聚偏氟乙烯

Abstract:

In order to improve the hydrophobic of ultra-high molecular weight polyethylene fabric, micro- and nano-scale structures were built by coating the fabric surface based on the lotrs effect. Silica aerogel was dispersed in polyvinylidene fluoride for preparing coating solution, and ultra-high molecular weight polyethylene fabric was coated by the solutio. The chemical composition and microstructure of the fabric surface were deteced by a X-ray photoelectron spectrograph, a scanning electron microscope and an atomic force microscope. The self-cleaning properties of the fabric were mearsured by the ash collection test. The results show that when the mass fraction of  PVDF is 12% and that of the silica aerogel is 8%, the maximum contact angel of the coated fabric surface is 157.8°, and the rolling angel is 3°. The coated film surface has micro-scale projections and nano-scale particle projections. Stain on the coated fabric surface can be taken away by water droplets, so the fabric surface has excellent self-cleaning property.

Key words: ultra-high molecular weight polyethylene fabric, wate repellent finishing, self-cleaning property, silica aerogel, polyvinylidene fluoride

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