抗菌防螨防霉功能改性粘胶纤维的制备及其性能

doi:10.13475/j.fzxb.20180501405

纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 19-23.doi: 10.13475/j.fzxb.20180501405

抗菌防螨防霉功能改性粘胶纤维的制备及其性能

吴娇¹, 于湖生²(), 万兴云¹, 田平¹, 李慧敏², 侯晓欣²

^1. 无限极(中国)有限公司, 广东广州 510623
^2. 青岛大学纺织服装学院, 山东青岛 266071

收稿日期:2018-05-04 修回日期:2019-03-27 出版日期:2019-07-15 发布日期:2019-07-25
通讯作者: 于湖生
作者简介:吴娇(1986-),女,工程师,硕士生。主要研究方向为家用功能纺织品。

Preparation and properties of anti-bacterial, anti-mite and anti-mildew functional modified viscose fibers

WU Jiao¹, YU Husheng²(), WAN Xingyun¹, TIAN Ping¹, LI Huimin², HOU Xiaoxin²

^1. Infinitus (China) Co., Ltd., Guangzhou, Guangdong 510623, China
^2. College of Textiles and Garment, Qingdao University, Qingdao, Shandong 266071, China

Received:2018-05-04 Revised:2019-03-27 Online:2019-07-15 Published:2019-07-25
Contact: YU Husheng

摘要/Abstract

摘要：

为制备兼具抗菌、防螨、防霉功能且耐久性的功能性粘胶纤维,利用水溶解制备的植物中药山苍子和小茴香提取物溶液,以及由百里香精油制备的微胶囊与粘胶纤维纺丝液进行共混,通过湿法纺丝制备抗菌防螨防霉功能改性粘胶纤维。借助扫描电子显微镜、傅里叶红外光谱仪、X射线衍射仪、单纤强力仪以及抗菌防螨防霉相关测试仪对改性粘胶纤维的结构和性能进行表征与分析。结果表明:与普通粘胶纤维相比,制备的改性粘胶纤维的晶胞结构没有改变,结晶度和取向度分别为41.3%、77.1%,与普通粘胶纤维基本一致;改性粘胶纤维纵横向形态无显著变化,断裂伸长率有所增加,但断裂强度略有降低,由该纤维制成的非织造布具有良好的抗菌、防螨、防霉功能及耐水洗性能。

关键词: 功能纤维, 粘胶纤维, 百里香精油, 抗菌性能, 防螨防霉性能, 湿法纺丝

Abstract:

In order to prepare functional viscose fiber with antibacterial, anti-mite and anti-mildew functions and durability, the extract solution of traditional Chinese medicine Litsea cubeba and Foeniculum vulgare prepared by water dissolution and the thyme essential oil microcapsule were blended with viscose spinning solution. Then the modified viscose fiber with antibacterial, anti-mite and anti-mildew functions was prepared by wet spinning. The structure and properties of the fiber were characterized by scanning electron microscopy, Fourier infrared spectroscopy, X-ray diffraction, single fiber strength tester and antibacterial, anti-mite and anti-mildew related testing instruments. The results show that compared with the ordinary viscose fiber, the crystal cell structure of the modified viscose fiber is not changed, and the crystallinity and orientation are 41.3% and 77.1%, respectively, which are in accordance with the common viscose fiber. The nonwovens made of the fibers have good anti-bacterial, anti-mite and anti-mildew functions and wash resistance.

Key words: functional fiber, viscose fiber, thyme essential oil, antibacterial property, anti-mite and anti-mildew property, wet spinning

中图分类号:

TS102.6

吴娇, 于湖生, 万兴云, 田平, 李慧敏, 侯晓欣. 抗菌防螨防霉功能改性粘胶纤维的制备及其性能[J]. 纺织学报, 2019, 40(07): 19-23.

WU Jiao, YU Husheng, WAN Xingyun, TIAN Ping, LI Huimin, HOU Xiaoxin. Preparation and properties of anti-bacterial, anti-mite and anti-mildew functional modified viscose fibers[J]. Journal of Textile Research, 2019, 40(07): 19-23.

图/表 5

图1

图2

表1

表2

表3

参考文献 16

[1]	陆艳 . 抗菌防螨多功能家用纺织品的研究与产品开发[D]. 杭州:浙江理工大学, 2010: 1.
	LU Yan . Research and product development of antibacterial and antimite multifunctional household textiles [D]. Hangzhou: Zhejiang Sci-Tech University, 2010: 1.
[2]	彭湘莲, 付红军 . 山苍子精油的提取及其抑菌研究现状[J]. 林产工业, 2018,45(11):51-54.
	PENG Xianglian, FU Hongjun . Extraction of essential oil and its antibacterial research status[J]. Forestry Industry, 2018,45(11):51-54.
[3]	王有年 . 植物杀螨活性物质研究进展[J]. 林业科学, 2010,46(6):118-127.
	WANG Younian . Advances in research on plant acaricide active substances[J]. Forestry Science, 2010,46(6):118-127.
[4]	杨敏 . 百里香研究进展[J]. 园艺与种苗, 2018,38(11):68-70.
	YANG Min . Research progress in thyme[J]. Horticulture and Seedlings, 2018,38(11):68-70.
[5]	闫浩, 牟玉兰, 喻彦 , 等, 海南木兰科植物抗菌性初探[J]. 农村科学实验, 2018 ( 11):57-58.
	YAN Hao, MOU Yulan, YU Yan , et al. Hainan magnoliaceae plant antibacterial probe[J]. Rural Science Experiment, 2018(11):57-58.
[6]	李娟, 陈中华, 华梅 , 等. 蒜头果中植物内生真菌烟曲霉的抗菌活性研究[J]. 西部林业科学, 2018,47(4):89-94.
	LI Juan, CHEN Zhonghua, HUA Mei , et al. The antibacterial activity of Aspergillus aeruginosa, an endophytic fungus in garlic fruit[J]. Western Forestry Science, 2018,47(4):89-94.
[7]	潘亚平, 张振海, 蒋艳荣 . 中药粉体改性技术的研究进展[J]. 中国中药杂志, 2013(22):21-26.
	PAN Yaping, ZHANG Zhenhai, JIANG Yanrong . Research progress of powder modification technology in Chinese medicine[J]. Chinese Journal of Chinese Medicine, 2013 ( 22):21-26.
[8]	于海龙 . 基于微胶囊技术制备芳香粘胶纤维的研究[D]. 青岛:青岛大学, 2016: 22-25.
	YU Hailong . Study on the preparation of aromatic viscose fiber based on microencapsulation technology[D]. Qingdao:Qingdao University, 2016: 22-25.
[9]	孙梦尧 . 面膜用高吸湿、抗菌、护肤粘胶纤维的制备及性能研究[D]. 青岛:青岛大学, 2017: 28-30.
	SUN Mengyao . Preparation and properties of viscose fiber for high moisture absorption, antibacterial and skin care[D]. Qingdao:Qingdao University, 2017: 28-30.
[10]	于伟东 . 纺织材料学[M]. 北京: 中国纺织出版社, 2014: 199-201.
	YU Weidong. Textile Materials [M]. Beijing: China Textile & Apparel Press, 2014: 199-201.
[11]	刘治刚, 高艳, 金华 , 等. XRD分峰法测定天然纤维素结晶度的研究[J]. 中国测试, 2015,41(2):38-41.
	LIU Zhigang, GAO Yan, JIN Hua , et al. Determination of crystallinity of natural cellulose by XRD peak separation method[J]. Chinese Test, 2015,41(2):38-41.
[12]	侯晓欣, 于湖生, 赵艳芹 , 等. 中药抗菌止血粘胶纤维的制备及性能研究[J]. 上海纺织科技, 2017(8):47-49.
	HOU Xiaoxin, YU Husheng, ZHAO Yanqin , et al. Preparation and properties of antibacterial and hemostasis viscose fiber[J]. Shanghai Textile Science & Technology, 2017(8):47-49.
[13]	赵艾明 . 粘胶纤维纺丝凝固浴中加入变性剂的作用[J]. 人造纤维, 2016,46(2):5-6.
	ZHAO Aiming . The effect of adding denaturant in spinning coagulation bath of viscose fiber[J]. Artificial Fiber, 2016,46(2):5-6.
[14]	于湖生, 吴娇, 刘逸新 , 等. 植物源功能黏胶纤维的性能研究[J]. 针织工业, 2016(8):7-8.
	YU Husheng, WU Jiao, LIU Yixin , et al. Research on the properties of plant derived functional viscose fiber[J]. Knitting Industries, 2016 ( 8):7-8.
[15]	丁伟, 张永强, 冉春 , 等. 类控制剂的开发研究与应用[J]. 中国科技成果, 2013(18):61-64.
	DING Wei, ZHANG Yongqiang, RAN Chun , et al. Development and application of plant mite control agents[J]. China Science and Technology Results, 2013(18):61-64.
[16]	申莉莉 . 百里香微胶囊制备及抑菌效果和机理研究[D]. 武汉:华中农业大学, 2015: 1-3.
	SHEN Lili . Thymus microcapsule preparation and its bacteriostatic effect and mechanism[D]. Wuhan:Huazhong Agricultural University, 2015: 1-3.

相关文章 15

[1]	秦益民. 含银海藻酸盐医用敷料的临床应用[J]. 纺织学报, 2020, 41(09): 183-190.
[2]	庞雅莉, 孟佳意, 李昕, 张群, 陈彦锟. 石墨烯纤维的湿法纺丝制备及其性能[J]. 纺织学报, 2020, 41(09): 1-7.
[3]	刘稀, 王冬, 张丽平, 李敏, 付少海. 低折射率树脂对原液着色粘胶纤维结构和性能的影响[J]. 纺织学报, 2020, 41(07): 9-14.
[4]	贾琳, 王西贤, 陶文娟, 张海霞, 覃小红. 聚丙烯腈抗菌复合纳米纤维膜的制备及其抗菌性能[J]. 纺织学报, 2020, 41(06): 14-20.
[5]	王婷婷, 刘梁, 曹秀明, 王清清. 竹红菌素-聚( 甲基丙烯酸甲酯-co-甲基丙烯酸)纳米纤维的制备及其光敏抗菌性能[J]. 纺织学报, 2020, 41(05): 1-7.
[6]	刘艳春, 白刚. 小檗碱在聚丙烯腈/ 醋酸纤维素复合纤维染色中的应用[J]. 纺织学报, 2020, 41(05): 94-98.
[7]	王晓菲, 万爱兰. 紫外线辐照聚吡咯/ 银导电涤纶织物的制备[J]. 纺织学报, 2020, 41(04): 112-116.
[8]	岳程飞, 丁长坤, 李璐, 程博闻 . 碳化二亚胺/ 羟基丁二酰亚胺交联改性胶原蛋白纤维制备及其性能[J]. 纺织学报, 2020, 41(03): 1-7.
[9]	马君志, 王冬, 付少海. 氧化石墨烯协同二硫代焦磷酸酯阻燃粘胶纤维的制备及其性能[J]. 纺织学报, 2020, 41(03): 15-19.
[10]	欧阳鹏飞, 张玉芳, 贾春紫, 张嘉煜. 用竹浆粕/ 离子液体复配体系纺制的再生纤维及其性能 [J]. 纺织学报, 2020, 41(01): 21-25.
[11]	吴倩倩, 李珂, 杨立双, 付译鋆, 张瑜, 张海峰. 载药聚偏氟乙烯伤口敷料的制备及其性能 [J]. 纺织学报, 2020, 41(01): 26-31.
[12]	李阵群, 许多, 魏春艳, 钱永芳, 吕丽华. 棉秆皮纤维素/ 氧化石墨烯纤维的制备及其力学性能和吸附性能 [J]. 纺织学报, 2020, 41(01): 15-20.
[13]	张治斌, 李刚, 毛森贤, 厉巽巽, 陈玉霜, 毛青山, 李翼, 潘志娟, 王晓沁. 丝素蛋白/ 壳聚糖微球制备及其抗菌性能[J]. 纺织学报, 2019, 40(10): 7-12.
[14]	尹思力杨洋江文石业新周小华黄金洪. 接枝蚕蛹肽羧基化粘胶纤维的制备及其优化工艺[J]. 纺织学报, 2019, 40(08): 14-19.
[15]	王文聪范静静丁超王鸿博. 多功能复合导电毛织物的制备及其性能[J]. 纺织学报, 2019, 40(08): 117-123.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

纤维名称	断裂强度/(cN·dtex^-1)		断裂伸长率/%
纤维名称	干态	湿态	干态	湿态
普通粘胶纤维	2.32	1.62	17.45	25.28
改性粘胶纤维	2.10	1.48	18.32	26.76

水洗情况	金黄色葡萄球菌	大肠杆菌	白色念珠菌
未洗涤	95.50	99.12	79.35
水洗20次	96.00	91.53	80.43

试样	未洗涤	洗涤20次
改性粘胶纤维	0	0
对照组	4	4
空白对照组	0	0

抗菌防螨防霉功能改性粘胶纤维的制备及其性能

Preparation and properties of anti-bacterial, anti-mite and anti-mildew functional modified viscose fibers

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 16

相关文章 15

Metrics

本文评价

推荐阅读 0