涤纶基材表面银/铜薄膜制备及其性能

doi:10.13475/j.fzxb.20180700905

纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 108-112.doi: 10.13475/j.fzxb.20180700905

涤纶基材表面银/铜薄膜制备及其性能

孟灵灵¹, 魏取福², 黄新民¹, 纪丹丹¹

^1. 盐城工学院纺织服装学院, 江苏盐城 224051
^2. 生态纺织教育部重点实验室(江南大学), 江苏无锡 214122;

收稿日期:2018-07-02 修回日期:2019-03-31 出版日期:2019-07-15 发布日期:2019-07-25
作者简介:孟灵灵 (1980-),女,副教授,博士。主要研究方向为功能纳米纺织材料。E-mail: mllwx1022@163.com。
基金资助:
江苏省产学研前瞻性项目(BY2016065-51);江苏省产学研前瞻性项目(BY2016065-28);江苏省生态环保重点实验室开放课题(JH201832);盐城市科技局项目(YKN2015011);中国纺织工业联合会项目(2014052);中国纺织工业联合会项目(2016044)

Preparation and properties of Ag/Cu film deposited on surface of polyester substrates

MENG Lingling¹, WEI Qufu², HUANG Xinmin¹, JI Dandan¹

^1. College of Textile & Clothing, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China;
^2. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China;

Received:2018-07-02 Revised:2019-03-31 Online:2019-07-15 Published:2019-07-25

摘要/Abstract

摘要：

为探索涤纶基Ag/Cu薄膜结构及性能,采用直流和射频共溅法,以不同组织结构纯涤纶织物为基材,金属银和铜为靶材,制备纳米薄膜。借助场发射扫描电子显微镜、X射线衍射仪、光电子能谱仪、织物感应式静电仪、纺织品防紫外线性能测试仪和电磁防辐射性能测试仪对试样表面薄膜形貌及结构、抗静电、防紫外线、电磁屏蔽性能进行表征。结果表明:非织造布表面薄膜均匀连续,机织布表面纳米颗粒直径较小,针织布表面颗粒分布较为连续,但仍然存在部分岛状颗粒;试样表面Cu(111)、Cu(200)、Ag(111)和Ag(200)衍射峰均不明显,结晶度低;纳米薄膜没有被氧化,以单质形式存在;以非织造布为基材的试样其抗静电、抗紫外线、电磁屏蔽性能最优,针织布最差。

关键词: 涤纶基材, Ag/Cu薄膜, 纳米薄膜, 结构, 性能

Abstract:

In order to explore the structure and properties of polyester-based Ag/Cu films, nanoscale films were prepared by direct current and radio frequency co-sputtering using pure polyester fabrics of different structures as the substrate and metallic silver and copper as targets. Field emission scanning electron microscopy, X-ray diffractometry, photoelectron spectroscopy, fabric inductive electrostatic analysis, fabric UV protection and electromagnetic radiation test were utilized to characterize the surface morphology and structure and antistatic, anti-UV and anti-electromagnetic shielding performance of the samples. The experimental results show that the film on the surface of the nonwoven fabric is uniform and continuous, the diameter of the nano-particles on the surface of the woven fabric is small, and the surface distribution of the knitted fabric is continuous, but some island-like particles still exist. Cu(111), Cu(200), Ag(111) and Ag(200) diffraction peaks of Cu/Ag film on the surface of the sample are not obvious, and the crystallinity is low. XPS image shows that the nano-film is not oxidized, and exists in elemental form. The nonwoven fabric is used as the substrate, the antistatic, anti-UV, anti-electromagnetic shielding performance of the sample is the best, and the knitted fabric is the worst.

Key words: polyester substrate, Ag/Cu film, nano film, structure, performance

中图分类号:

TS174

孟灵灵, 魏取福, 黄新民, 纪丹丹. 涤纶基材表面银/铜薄膜制备及其性能[J]. 纺织学报, 2019, 40(07): 108-112.

MENG Lingling, WEI Qufu, HUANG Xinmin, JI Dandan. Preparation and properties of Ag/Cu film deposited on surface of polyester substrates[J]. Journal of Textile Research, 2019, 40(07): 108-112.

图/表 6

图1

图2

图3

表1

图4

图5

参考文献 10

[1]	师艳丽, 李娜娜, 付元静 , 等. 用于纺织品表面改性的磁控溅射技术研究进展[J]. 纺织学报, 2016,37(4):165-169.
	SHI Yanli, LI Nana, FU Yuanjing , et al. Research progress of magnetron sputtering in textiles[J]. Journal of Textile Research, 2016,37(4):165-169.
[2]	盛澄成 . 表面沉积Cu薄膜复合材料屏蔽效能优化及抗氧化性能研究[D]. 无锡: 江南大学, 2017: 15-20.
	SHENG Chengcheng . Optimization of shielding effectiveness and anti-oxidation performance of Cu film composites with surface deposition[D]. Wuxi:Jiangnan University, 2017: 15-20.
[3]	黄美林, 鲁圣国, 杜文琴 , 等. 磁控溅射法制备柔性纺织面料基纳米薄膜的研究与进展[J]. 真空科学与技术学报, 2017,37(12):1194-1200.
	HUANG Meilin, LU Shengguo, DU Wenqin , et al. Research and development of magnetron sputtering method for preparation of nanofilms based on flexible textile fabrics[J]. Journal of Vacuum Science and Technology, 2017,37(12):1194-1200.
[4]	YUAN X H, WEI Q F, CHEN D , et al. Electrical and optical properties of polyester fabric coated with Ag/TiO₂ composite films by magnetron sputtering[J]. Textile Research Journal, 2015,86(8):887-894.
[5]	彭灵慧, 郭荣辉, 兰建武 , 等. 激光前处理磁控溅射镀铜涤纶织物的制备及性能[J]. 电镀与涂饰, 2017(13):684-688.
	PENG Linghui, GUO Ronghui, LAN Jianwu , et al. Preparation and performance of magnetron sputtering copper-coated polyester fabric before laser treat-ment[J]. Electroplating and Coating, 2017(13):684-688.
	HUANG X M, MENG L L, WEI Q F , et al. Effect of substrate structures on the morphology and interfacial bonding properties of copper films sputtered on polyester fabrics.[J]. International Journal of Clothing Science and Technology, 2017,29(1):39-46.
[6]	李超荣, 舒顺新, 谢勇 . 磁控溅射纳米纤维基银膜的结构和性能[J]. 纺织学报, 2014,35(4):32-34.
	LI Chaorong, SHU Shunxin, XIE Yong . Structure and properties of Ag coatings on nanofibers prepared by magnetron sputtering[J]. Journal of Textile Research, 2014,35(4):32-34.
[7]	JIANG S X, PENG L H, GUO R H , et al. Preparation and characterization of Fe₂O₃ coating on quartz fabric by electron beam evaporation[J]. Ceramics International, 2016(42):19386-19392.
[8]	谈淑咏, 张旭海, 朱迪 , 等. 直流脉冲磁控溅射铜膜的结构与性能研究[J]. 功能材料, 2017,48(2):2144-2148.
	TAN Shuyong, ZHANG Xuhai, ZHU Di , et al. Study on structure and performance of DC pulse magnetron sputtering copper film[J]. Functional Materials, 2017,48(2):2144-2148.
[9]	MENG L L, HUANG X M, WEI Q F , et al. Study on the conductive effectiveness of nanoscale copper films sputtered on the surface of polyester nonwoven fabrics[J]. Journal of The Textile Institute, 2018,109(11):1395-1399.
[10]	徐文正, 魏取福, 杨莉 , 等. 磁控溅射玄武岩纤维基纳米Cu薄膜微观结构分析的研究[J]. 化工新型材料, 2016(7):136-138.
	XU Wenzheng, WEI Qufu, YANG Li , et al. Study on microstructure analysis of magnetron sputtering basalt fiber with nano Cu thin films[J]. New Chemical Materials, 2016(7):136-138.

相关文章 15

[1]	李伟, 张正桥, 吴兰娟, 徐珍珍, 倪庆清, 鲁育豪. 磷酸酯-己酸酯化淀粉的制备及其浆膜性能[J]. 纺织学报, 2020, 41(10): 81-86.
[2]	沈岳, 蒋高明, 刘其霞. 梯度结构活性碳纤维毡吸声性能分析[J]. 纺织学报, 2020, 41(10): 29-33.
[3]	应丽丽, 李长龙, 王宗乾, 王邓峰, 吴开明, 谢伟, 程欢. 植酸作用下锆离子修饰羽绒及其保温性能[J]. 纺织学报, 2020, 41(10): 94-100.
[4]	孙焕惟, 张恒, 甄琪, 朱斐超, 钱晓明, 崔景强, 张一风. 丙烯基纳微米弹性过滤材料的熔喷成型及其过滤性能[J]. 纺织学报, 2020, 41(10): 20-28.
[5]	翟丽娜, 李俊, 杨允出. 热防护服装测评用传感器的发展及其研究现状[J]. 纺织学报, 2020, 41(10): 188-196.
[6]	秦益民. 含银海藻酸盐医用敷料的临床应用[J]. 纺织学报, 2020, 41(09): 183-190.
[7]	彭稀, 周赳. 中国古代织锦重组织结构的特征及其演变规律[J]. 纺织学报, 2020, 41(09): 67-75.
[8]	刘沐黎, 袁理, 杨亚莉, 刘军平, 龚雪, 鄢煜尘. 色纺机织物组织结构对其呈色特性的影响[J]. 纺织学报, 2020, 41(09): 45-53.
[9]	朵永超, 钱晓明, 赵宝宝, 钱幺, 邹志伟. 超细纤维合成革基布的制备及其性能[J]. 纺织学报, 2020, 41(09): 81-87.
[10]	王凤龙, 王建明, 周羿恬, 赵明会. 吸水树脂吸液性能研究[J]. 纺织学报, 2020, 41(09): 21-26.
[11]	庞雅莉, 孟佳意, 李昕, 张群, 陈彦锟. 石墨烯纤维的湿法纺丝制备及其性能[J]. 纺织学报, 2020, 41(09): 1-7.
[12]	展晓晴, 李凤艳, 赵健, 李海琼. 超高分子量聚乙烯纤维的热力学稳定性能[J]. 纺织学报, 2020, 41(08): 9-14.
[13]	杨凯, 张啸梅, 焦明立, 贾万顺, 刁泉, 李咏, 张彩云, 曹健. 高邻位酚醛基纳米活性碳纤维制备及其吸附性能[J]. 纺织学报, 2020, 41(08): 1-8.
[14]	张祝辉, 张典堂, 钱坤, 徐阳, 陆健. 广角机织物的织造工艺及其偏轴拉伸力学性能[J]. 纺织学报, 2020, 41(08): 27-31.
[15]	朱清, 徐丹丹, 潘园歌, 王成龙, 郑今欢. 水性聚丙烯酸酯对涂层商标织物图案打印效果的影响[J]. 纺织学报, 2020, 41(08): 55-62.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

涤纶基材表面银/铜薄膜制备及其性能

Preparation and properties of Ag/Cu film deposited on surface of polyester substrates

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 10

相关文章 15

Metrics

本文评价

推荐阅读 0