纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 119-127.doi: 10.13475/j.fzxb.20180703409

• 染整与化学品 • 上一篇    下一篇

纯棉水刺非织造材料的单向导水无氟整理

齐国瑞1, 柯勤飞1, 李祖安2, 黄族健2, 靳向煜1, 黄晨1()   

  1. 1. 东华大学 纺织学院, 上海 201620
    2. 福建南纺有限责任公司, 福建 南平 353000
  • 收稿日期:2018-07-16 修回日期:2019-04-17 出版日期:2019-07-15 发布日期:2019-07-25
  • 作者简介:齐国瑞(1992-),女,硕士生。主要研究方向为非织造材料与工程。

Single-guide water non-fluorinated finishing of cotton spunlace non-woven materials

QI Guorui1, KE Qinfei1, LI Zu'an2, HUANG Zujian2, JIN Xiangyu1, HUANG Chen1()   

  1. 1. School of Textiles, Donghua University, Shanghai 201620, China
    2. Fujian Nanfang Co., Ltd., Nanping, Fujian 353000, China
  • Received:2018-07-16 Revised:2019-04-17 Online:2019-07-15 Published:2019-07-25

摘要:

为实现纯棉水刺非织造材料单向导水无氟整理工艺的工业化,采用自制的雾化设备,并利用体积分数为0.67%的德国无氟拒水剂RUCO-DRY ECO 对纯棉水刺非织造材料进行单面拒水喷雾整理,测试了不同喷雾时间整理材料的物理力学性能、接触角、液态水分动态管理能力等性能,分析讨论了其物理力学性能基本无变化以及接触角、液态水分动态管理能力变化的原因,并采用经过此种工艺整理过的纯棉水刺非织造材料进行了纸尿裤面层性能测试。结果表明:其单向传递指数(AOTC)可达1 093%,液态水动态传递综合指数(OMMC)可达0.960 6;在保证纯棉材料不反渗的前提下,液体穿透时间可达4 s。

关键词: 自制雾化设备, 纯棉水刺非织造材料, 单面拒水, 无氟整理, 纸尿裤面层材料

Abstract:

In order to realize the industrialization of pure cotton spunlace non-woven materials single-directional water-free fluorine-free finishing process, self-made atomization equipment and the German fluorine-free water repellent RUCO-DRY ECO with a volume fraction of 0.67% were adopted to one-side water-repellent spray finish the cotton spunlace non-woven materials. This paper studied the physical and mechanical properties, contact angle and moisture management tester(MMT)performance of the materials after finishing for different spray time, discussed the reasons for the little change of physical and mechanical properties and the changes of contact angle and MMT performance, and carried out the diaper surface performance test of the finished cotton spunlace non-woven materials. The results show that its one-way transfer index (AOTC) can reach 1 093%, the liquid water dynamic transfer index (OMMC) can reach 0.960 6. Under the premise of ensuring pure cotton material does not reverse osmosis, the liquid penetration time can reach 4 s.

Key words: self-made spray device, pure cotton spunlace non-woven material, one-sided water repellent, non-fluorine finishing, side layer material of diaper

中图分类号: 

  • TS174.8

图1

自制雾化装置"

图2

工艺路线图"

表1

梳理参数"

梳理元件 喂给罗拉 锡林 杂乱辊 道夫 成卷
梳理速度/
(m·min-1)
0.84 251 6.31 7.64 12.54

表2

水刺参数"

水刺工艺 速度/(m·min-1) 顺序 压力/kPa
预水刺 2 2 500
第1道 2 3 500
第2道 2 4 500
第3道 2 6 500
第4道 2 7 500

图3

雾化拒水整理前后电镜照片对比图"

图4

雾化拒水整理前后FI-TR对比图"

图5

雾化拒水整理前后质量增加率"

图6

雾化拒水整理前后最大断裂强力对比"

图7

雾化整理前后孔径变化"

图8

雾化整理前后透气性变化"

图9

处理前后亲疏水面接触角"

表3

喷雾时间为20、25和30 s时液体穿透情况"

喷雾时间/s 方向 t/s B/% A/% C/%
20 3.2 26 6 68
3.2 28 64 8
25 4.0 20 5 75
4.0 25 75 0
30 5.2 24 18 58
5.2 22 78 0

图10

液体穿透过程示意图"

表4

AOTC和OMMC性能评级表"

评语 单向传递指数
(AOTC)/%
液态水动态传
递指数(OMMC)
非常差 <-50 0~0.2
<-50 0.2~0.4
100~200 0.4~0.6
非常好 200~400 0.6~0.8
极好 >400 >0.8

图12

不同喷雾处理时间的MMT示意图"

图11

不同喷雾处理时间的AOTC和OMMC示意图"

图13

A、B试样外观形貌图"

表5

试样A和B的液体穿透时间、滑移量和返湿量"

试样 液体穿透
时间/s
滑移量/
g
返湿量/g
A 1.06 0.092 3 0.052 2
B 2.24 0.918 1 0.124 8
A与B比值 0.47 0.10 0.42
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