自着色水性聚氨酯制备及其在棉织物涂层中的应用

doi:10.13475/j.fzxb.20180708406

纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 85-89.doi: 10.13475/j.fzxb.20180708406

自着色水性聚氨酯制备及其在棉织物涂层中的应用

徐艳, 籍晓倩, 陈坤林, 王潮霞

江南大学纺织服装学院, 江苏无锡 214122

收稿日期:2018-07-30 修回日期:2019-04-17 出版日期:2019-07-15 发布日期:2019-07-25
通讯作者: 王潮霞
作者简介:徐艳(1994-),女,硕士生。主要研究方向为功能聚氨酯制备及性能研究。
基金资助:
国家自然科学基金项目(21174055)

Synthesis of self-colored waterborne polyurethane and its application in coating of cotton fabric

XU Yan, JI Xiaoqian, CHEN Kunlin, WANG Chaoxia

College of Textiles and Clothing, Jiangnan University, Wuxi, Jiangsu 214122, China

Received:2018-07-30 Revised:2019-04-17 Online:2019-07-15 Published:2019-07-25
Contact: WANG Chaoxia

摘要/Abstract

摘要：

为解决低分子染料的耐热迁移性差和涂层色浆配制时外添加涂料、染料等着色剂的烦琐性,将1-氨基-4-羟基-2(6-羟基己氧基)蒽醌通过共价键引入水性聚氨酯骨架中合成端羟基自着色水性聚氨酯。借助红外光谱仪、紫外-可见光谱仪和热重分析仪研究了自着色水性聚氨酯的化学结构和热稳定性。考察了蒽醌发色体质量分数、固化剂质量分数和焙烘条件对涂层棉织物K/S值、色牢度和手感的影响。结果表明:随着自着色水性聚氨酯制备过程中蒽醌发色体质量分数增加,涂层棉织物K/S值增大;当固化剂质量分数为20%,于150 ℃焙烘5 min,涂层棉织物K/S值为5.20,干、湿摩擦色牢度为4~5级,褪色牢度为3~4级,沾色牢度为4~5级,手感为3级。

关键词: 水性聚氨酯, 发色体, 涂层, 固化剂, 自着色, 棉织物

Abstract:

Hydroxyl terminated self-colored waterborne polyurethane was synthesized by covalently bonding 1-amino-4-hydroxy-2-(6-hydroxy-hexyloxy) anthraquinone into waterborne polyurethane skeleton to solve the poor thermal migration of low molecular dye and complexity of pigment, dye or extra colorant for coating slurry. The chemical structure and thermal stability were studied by Fourier transform infrared spectrometer, ultraviolate-visible spectrometer and thermal gravity analysis. The effects of chromophore mass fraction, curing agent mass fraction and baking conditions on K/S value, color fastness and hand feeling were investigated. Results show that the K/S value of coated cotton fabric increases with the increase of anthraquinone chromophore dosages in the preparation of self-colored waterborne polyurethane. The K/S value of coated cotton fabric is 5.20 under the condition of 20% curing agent and baking at 150 ℃ for 5 min. The dry rubbing fastness and wet rubbing fastness are 4-5 grade. The fading fastness can reach 3-4 grade and staining fastness is 4-5 grade. The hand feeling is 3 grade.

Key words: waterborne polyurethane, chromophore, coating, curing agent, self-color, cotton fabric

中图分类号:

TS195.597

徐艳, 籍晓倩, 陈坤林, 王潮霞. 自着色水性聚氨酯制备及其在棉织物涂层中的应用[J]. 纺织学报, 2019, 40(07): 85-89.

XU Yan, JI Xiaoqian, CHEN Kunlin, WANG Chaoxia. Synthesis of self-colored waterborne polyurethane and its application in coating of cotton fabric[J]. Journal of Textile Research, 2019, 40(07): 85-89.

图/表 9

图1

图2

图3

表1

表2

图4

表3

图5

表4

参考文献 10

[1]	杨虎, 朱谱新, 吴大诚 . 高分子染料的合成与应用及展望[J]. 染料工业, 2000,32(6):4-7.
	YANG Hu, ZHU Puxin, WU Dacheng . Polymeric dyes-synjournal, applications and prospects[J]. Dyestuff Industry, 2000,32(6):4-7.
[2]	冒海燕, 张淼, 强思雨 , 等. 偶氮苯-聚氨酯基抗皱功能高分子染料制备及性能[J]. 纺织学报, 2016,37(2):79-84.
	MAO Haiyan, ZHANG Miao, QIANG Siyu , et al. Synjournal and properties of azobenzene-polyurethane based anti-wrinkle polymeric dye[J]. Journal of Textile Research, 2016,37(2):79-84.
[3]	LI Y Y, NOORDOVER B A J, BENTHEM R A T M V, et al. Reactivity and regio-selectivity of renewable building blocks for the synjournal of water-dispersible polyurethane prepolymers[J]. ACS Sustainable Chemistry & Engineering, 2014(2):788-797.
[4]	刘拥君, 吴红艳, 陈华宝 . 一种高分子染料的合成及染色性能研究[J]. 纺织学报, 2005,26(3):79-81.
	LIU Yongjun, WU Hongyan, CHEN Huabao . Study on synjournal and properties of a polymeric dye[J]. Journal of Textile Research, 2005,26(3):79-81.
[5]	WANG H H, LIU Y T . Silicon-containing anionic water-borne polyurethane with covalently bonded reactive dye[J]. Journal of Applied Polymer Science, 2003,90:2045-2052. doi: 10.1002/(ISSN)1097-4628
[6]	吴海婷, 蒋小娟, 蔡再生 . 阻燃型静电植绒黏合剂的合成及其应用[J]. 纺织学报, 2018,39(6):96-100.
	WU Haiting, JIANG Xiaojuan, CAI Zaisheng . Preparation and application of environment-friendly flame-retardant silicon-acrylic flocking adhesive[J]. Journal of Textile Research, 2018,39(6):96-100.
[7]	刘素素, 姜蕾, 隋晓峰 , 等. 水性聚氨酯-丙烯酸酯包覆颜料色浆在涂料染色中的应用[J]. 纺织学报, 2018,39(9):71-76,83.
	LIU Susu, JIANG Lei, SUI Xiaofeng , et al. Application of waterborne polyurethane-acrylate coated pigment adhesives in pigment dyeing[J]. Journal of Textile Research, 2018,39(9):71-76,83.
[8]	LI W D, DING E Y . Preparation and characterization of cross-linking PEG/MDI/PE copolymer as solid-solid phase change heat storage material[J]. Solar Energy Material and Solar Cells, 2007,91:764-768. doi: 10.1016/j.solmat.2007.01.011
[9]	ZHANG S B, JIANG H M, XU Y M , et al. Thermal and crystalline properties of water-borne polyurethanes based on IPDI, DMPA, and PEBA/HNA[J]. Journal of Applied Polymer Science, 2007,103(3):1936-1941. doi: 10.1002/(ISSN)1097-4628
[10]	HU K, YUAN Y, YAN P Y , et al. Green synjournal process and properties of polyurethane completely using ethanol as solvent[J]. Journal of Polymer Research, 2017,24(5):80. doi: 10.1007/s10965-017-1240-5

相关文章 15

[1]	王博, 凡力华, 原韵, 殷允杰, 王潮霞. 可拉伸聚吡咯/ 棉针织物的制备及其储电性能[J]. 纺织学报, 2020, 41(10): 101-106.
[2]	刘国金, 石峰, 陈新祥, 张国庆, 周岚. 聚氨酯/ 相变蜡蓄热调温功能整理剂的制备及其在棉织物上的应用[J]. 纺织学报, 2020, 41(07): 129-134.
[3]	成世杰, 王晨洋, 张宏伟, 左丹英. 硼氮掺杂碳点对棉织物防紫外线性能的影响[J]. 纺织学报, 2020, 41(06): 93-98.
[4]	周青青, 陈嘉毅, 祁珍明, 陈为健, 邵建中. 阻燃抗菌棉织物的制备及其性能表征[J]. 纺织学报, 2020, 41(05): 112-120.
[5]	谭淋, 施亦东, 周文雅. 棉织物的硅溶胶疏水整理[J]. 纺织学报, 2020, 41(04): 106-111.
[6]	赵兵, 黄小萃, 祁宁, 钟洲, 车明国, 葛亮亮. 基于共价结合的纳米银抗菌棉织物研究进展[J]. 纺织学报, 2020, 41(03): 188-196.
[7]	高思梦, 王鸿博, 杜金梅, 王文聪. 甜菜碱聚合物的合成及其在棉织物抗菌整理中的应用[J]. 纺织学报, 2020, 41(02): 89-94.
[8]	易领, 张何, 傅昕, 李雯. 石墨烯基锆钛复合材料改性棉织物的制备及其远红外发射性能 [J]. 纺织学报, 2020, 41(01): 102-109.
[9]	李育洲, 张雨凡, 周青青, 陈国强, 邢铁玲. 二氧化锰/ 石墨烯/ 棉织物复合电极的制及其电化学性能 [J]. 纺织学报, 2020, 41(01): 96-101.
[10]	陈莹, 周爽, 韦恬静, 方浩霞, 李宇菲. 聚吡咯复合织物的软模板法制备及其性能[J]. 纺织学报, 2019, 40(12): 93-97.
[11]	崔一帆, 侯巍, 周千熙, 闫俊, 路艳华, 何婷婷. 丝胶温敏凝胶对棉织物性能的影响[J]. 纺织学报, 2019, 40(12): 74-78.
[12]	孙玉发, 周向东. 棉用新型含磷氮阻燃剂的合成及其应用[J]. 纺织学报, 2019, 40(12): 79-85.
[13]	王浩, 杜兆芳, 许云辉. 氧化壳聚糖/丝胶复合物的制备及其对棉织物的功能整理[J]. 纺织学报, 2019, 40(11): 119-124.
[14]	杨建, 张国庆, 刘国金, 柯孝明, 周岚. 复合相变微胶囊制备及其在棉织物上的应用[J]. 纺织学报, 2019, 40(10): 127-133.
[15]	贾高鹏, 宋小红, 李　莹, 刘晓丹, 潘雪茹. 铜镍金属涂层机织物拉伸过程中电流的响应[J]. 纺织学报, 2019, 40(10): 68-72.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

涂层织物	K/S值	L^*	a^*	b^*	C^*	h°
PU1	0.70	76.59	34.05	5.48	34.49	9.15
PU2	2.66	62.36	49.18	9.12	50.01	10.51
PU3	4.13	58.00	54.77	11.52	55.96	11.87
PU4	4.56	55.39	53.51	10.26	54.48	10.85

自着色水性聚氨酯制备及其在棉织物涂层中的应用

Synthesis of self-colored waterborne polyurethane and its application in coating of cotton fabric

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 10

相关文章 15

Metrics

本文评价

推荐阅读 0

涂层织物	摩擦牢度/级		皂洗牢度/级		手感/级
涂层织物	干	湿	棉沾色	褪色	手感/级
PU1	4~5	4~5	4~5	2	3
PU2	4~5	4~5	4~5	2~3	3
PU3	4~5	4	4~5	3	3
PU4	4~5	4	4~5	3	3

固化剂质量分数/%	摩擦牢度/级			皂洗牢度/级		手感/级
固化剂质量分数/%	干	湿		棉沾色	褪色	手感/级
0	4~5	2~3	4~5		1	4
5	4~5	3	4~5		2	4
10	4~5	4	4~5		3	3
15	4~5	4~5	4~5		3	3
20	4~5	4~5	4~5		3~4	3

焙烘条件		K/S值	摩擦牢度/级		皂洗牢度/级		手感/ 级
温度/ ℃	时间/ min	K/S值			皂洗牢度/级
温度/ ℃	时间/ min	干			湿	棉沾色		褪色
130	3	5.49	4~5	2~3	4~5	1	3
130	5	5.25	4~5	3	4~5	1	3
150	3	5.29	4~5	4	4~5	2	3
150	5	5.20	4~5	4~5	4~5	3~4	3