纺织学报 ›› 2020, Vol. 41 ›› Issue (03): 188-196.doi: 10.13475/j.fzxb.20181205709

• 综合述评 • 上一篇    

基于共价结合的纳米银抗菌棉织物研究进展

赵兵1,2,3(), 黄小萃4, 祁宁1, 钟洲2, 车明国2, 葛亮亮3   

  1. 1.苏州大学 纺织与服装工程学院, 江苏 苏州 215006
    2.超美斯新材料股份有限公司, 江苏 苏州 215200
    3.苏州吉晟信纺织有限公司, 江苏 苏州 215104
    4.苏州市职业大学 丝绸应用技术研究所, 江苏 苏州 215104
  • 收稿日期:2018-12-26 修回日期:2019-12-04 出版日期:2020-03-15 发布日期:2020-03-27
  • 作者简介:赵兵(1984—),男,副研究馆员,博士。主要研究方向为功能纳米材料的制备及应用。E-mail:zhaobing@suda.edu.cn。
  • 基金资助:
    中国博士后科学基金资助项目(2018M642313);江苏省博士后科学基金项目(2018K110C);江苏省双创博士项目(2018);中国纺织工业联合会科技指导性计划项目(2019035)

Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond

ZHAO Bing1,2,3(), HUANG Xiaocui4, QI Ning1, ZHONG Zhou2, CHE Mingguo2, GE Liangliang3   

  1. 1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215006, China
    2. X-FIPER New Material Co., Ltd., Suzhou, Jiangsu 215200, China
    3. Suzhou Jctex Co., Ltd., Suzhou, Jiangsu 215104, China
    4. Institute of Applied Technology of Silk, Suzhou Vocational University, Suzhou, Jiangsu 215104, China
  • Received:2018-12-26 Revised:2019-12-04 Online:2020-03-15 Published:2020-03-27

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摘要：

针对棉织物与纳米银之间缺乏亲和性,主要依靠物理吸附结合,水洗牢度差等问题,总结了基于共价结合的纳米银抗菌棉织物的最新研究进展,探讨了席夫碱反应和酯化反应这2种共价结合机制。以纳米银与棉织物之间的共价交联剂(超支化聚合物、树状大分子、丝素、丝胶、半胱氨酸、蛋氨酸、巯基乙酸、壳聚糖衍生物、聚苯乙烯-b-聚丙烯酸、丁烷四羧酸)种类进行分类介绍,结合抑菌率和银含量的数据讨论了基于共价结合的纳米银抗菌棉织物的制备工艺、抗菌性能和抗菌耐洗性能。最后对基于共价结合的纳米银抗菌棉织物领域存在的不足和未来需要深入关注的地方进行了探讨。研究指出,共价交联法大幅提高了纳米银的抗菌耐洗性能,为开发环境友好和长效抗菌的纳米银纺织品提供了新思路和新途径。

关键词: 棉织物, 共价键, 纳米银, 抗菌性, 席夫碱反应, 酯化反应

Abstract:

In view of unaffinity, weak physical adsorption and poor washing fastness between cotton fabric and silver nanoparticles (AgNPs), the latest research progress of AgNPs antibacterial cotton fabric based on covalent bond was systematically reviewed. Two covalent bond mechanisms, schiff base reaction and esterification reaction, were described. Combined with the data of inhibition rate and silver content, preparation process, antibacterial property and wash fastness of AgNPs antibacterial cotton fabric based on covalent bond were discussed, which were classified by covalent crosslinkers between AgNPs and cotton fabric, such as hyperbranched polymers, dendrimers, silk fibroin, sericin, cysteine, methionine, mercaptoacetic acid, chitosan derivatives, polystyrene-b-polyacrylic acid, butane tetracarboxylic acid, and so on. Finally, the shortcomings and the concerns in future of AgNPs antibacterial cotton fabric based on covalent bond were introduced. It is pointed out that the covalent crosslinking methods greatly improve the antibacterial washability of AgNPs and provide a new thought and a new way for developing environmentally friendly and durable antibacterial AgNPs textiles.

Key words: cotton fabric, covalent bond, silver nanoparticles, antibacterial property, schiff base reaction, esterification reaction

中图分类号: 

  • TB333

图1

二醛织物素与AgNPs-NH2反应机制示意图"

图2

丝素/AgNPs整理氧化棉织物反应原理示意图"

图3

L-半胱氨酸/羧甲基壳聚糖/棉织物共价交联AgNPs反应原理图"

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