纺织学报 ›› 2020, Vol. 41 ›› Issue (06): 81-85.doi: 10.13475/j.fzxb.20190203505

• 染整与化学品 • 上一篇    下一篇

蚕丝织物的栀子蓝色素染色

宋慧君1(), 翟亚丽2, 钞意元1, 朱超宇1   

  1. 1.河南工程学院 材料与化学工程学院, 河南 郑州 450007
    2.河南工程学院 纺织学院, 河南 郑州 450007
  • 收稿日期:2019-02-20 修回日期:2020-02-21 出版日期:2020-06-15 发布日期:2020-06-28
  • 作者简介:宋慧君(1969—),女,教授,博士。主要研究方向为天然高分子材料及天然染料染色。E-mail:syy66688@126.com
  • 基金资助:
    国家级大学生创新创业训练计划项目(201811517002);河南省科技发展计划项目(182102310852);河南工程学院博士基金项目(D2016008)

Silk fabric dyed with gardenia blue pigment

SONG Huijun1(), ZHAI Yali2, CHAO Yiyuan1, ZHU Chaoyu1   

  1. 1. School of Material and Chemical Engineering, Henan University of Engineering, Zhengzhou, Henan 450007, China
    2. School of Textiles, Henan University of Engineering, Zhengzhou, Henan 450007, China
  • Received:2019-02-20 Revised:2020-02-21 Online:2020-06-15 Published:2020-06-28

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摘要：

为解决蚕丝织物的天然染料染色缺少蓝色的问题,丰富天然染料染色蚕丝织物的色谱,用栀子蓝色素对蚕丝织物染色,研究了染色工艺对上染百分率的影响,依据栀子蓝色素上染蚕丝织物的上染速率曲线及吸附等温线分别研究了其染色动力学和染色热力学。得到栀子蓝色素上染蚕丝织物的最佳工艺为:染色pH值3,染色时间50 min,染色温度60 ℃。在60 ℃,pH值为3条件下染色,染色吸附过程符合准二级动力学模型,为化学吸附,吸附等温线为朗缪尔型,为定位吸附。据此计算,得到栀子蓝色素上染蚕丝织物的染色饱和值为 97.465 9 g/kg。

关键词: 蚕丝织物, 染色, 动力学, 热力学, 栀子蓝

Abstract:

Facing the problem that silk fabrics dyed with natural dyes has insufficient blue color, gardenia blue was used in dyeing silk fabrics as an attempt to enrich the chromatogram of silk fabrics dyed with natural dyes. The effects of the dyeing process on dye uptake was studied, and dyeing kinetics and dyeing thermodynamics of silk fabrics dyed with gardenia blue were studied according to the dyeing rate curve and adsorption isotherm respectively. The results show that the optimum dyeing condition is dyeing at pH=3 and 60 ℃ for 50 min. When dyeing at pH=3 and 60 ℃, the adsorption of pigments to silk fabrics responds to the quasi-second-order kinetic, indicating chemical adsorption. The adsorption isotherm conforms to Langmuir-type adsorption isotherm, suggesting a localized adsorption. The dyeing saturation value of gardenia blue dyeing silk is 97.465 9 g/kg according to Langmuir's adsorption isotherm formula.

Key words: silk fabric, dyeing, kinetics, thermodynamics, gardenia blue

中图分类号: 

  • TS193.1

图1

pH值对上染百分率的影响"

图2

染色温度对上染百分率的影响"

图3

栀子蓝色素对蚕丝的上染速率曲线"

图4

栀子蓝色素对蚕丝的准一级吸附动力学模型"

图5

栀子蓝色素对蚕丝的准二级吸附动力学模型"

图6

栀子蓝色素上染蚕丝的吸附等温线"

图7

栀子蓝色素对蚕丝的弗莱因德利胥型吸附等温线"

图8

栀子蓝色素对蚕丝的朗缪尔型吸附等温线"

表1

染色织物的K/S值和染色牢度"

K/S值 耐摩擦色牢度/级 耐皂洗色牢度/级 日晒牢
度/级
干摩 湿摩 变色 丝沾 棉沾
7.085 3~4 3 2~3 3 4 1~2
[1] SWAMY V N, GOWDA K N, SUDHAKAR R. Natural dye extracted from vitex negundo as a potential alternative to synthetic dyes for dyeing of silk[J]. Journal of the Institution of Engineers (India): Series E, 2016,97(1):31-38.
doi: 10.1007/s40034-015-0069-x
[2] 陈美云, 袁德宏, 张玉萍. 碱性条件提取茶叶天然染料及其在蚕丝织物染色中的应用[J]. 纺织学报, 2011,32(11):73-77.
CHEN Meiyun, YUAN Dehong, ZHANG Yuping. Alkaline extraction of natural dye from tea and its dyeing on silk fabric[J]. Journal of Textile Research, 2011,32(11):73-77.
[3] SAFAPOUR S, SADEGHI-KIAKHANI M, ESHAGHLOO-GALUGAHI S. Extraction, dyeing, and antibacterial properties of crataegus elbursensis fruit natural dye on wool yarn[J]. Fibers and Polymers, 2018,19(7):1428-1434.
[4] CHO Y J, KIM S Y, KIM J, et al. One-step enzymatic synjournal of blue pigments from geniposide for fabric dyeing[J]. Biotechnology and Bioprocess Engineering, 2006,11:230-234.
[5] 付学军, 董新伟, 金海珠. 天然色素栀子蓝的稳定性研究[J]. 冷饮与速冻食品工业, 2005,11(1):22-25.
FU Xuejun, DONG Xinwei, JIN haizhu. Study on the stability of gardenia blue pigment[J]. Beverage & Fast Frozen Food Industry, 2005,11(1):22-25.
[6] 耿宇. 栀子蓝色素制备的工艺研究[D]. 郑州: 郑州大学, 2010: 1-40.
GENG Yu. Study on preparation of gardenia blue pig-ment[D]. Zhengzhou: Zhengzhou University, 2012: 1-40.
[7] 王怡龄, 赵云蛟, 吴昊天, 等. 多种水溶性天然色素的热稳定性研究[J]. 中国食品添加剂, 2015(10):88-92.
WANG Yiling, ZHAO Yunjiao, WU Haotian, et al. Study on thermal stability of water-soluble natural pigment[J]. China Food Additives, 2015(10):88-92.
[8] 陈峰, 陈剑锋. 栀子色素稳定性的对比研究[J]. 食品工业, 2014,35(1):124-128.
CHEN Feng, CHEN Jianfeng. Comparative study on stability of gardenia pigment[J]. Food Industry, 2014,35(1):124-128.
[9] 陈峰, 陈剑锋. 栀子蓝色素稳定性的研究[J]. 宁德师范学院学报(自然科学版), 2013,25(3):236-239.
CHEN Feng, CHEN Jianfeng. Study on the stability of gardenia blue pigment[J]. Journal of Ningde Normal University(Natural Science Ediction), 2013,25(3):236-239.
[10] 杨丽, 田俊莹. 天然染料栀子蓝对羊毛织物的染色性能[J]. 毛纺科技, 2011,39(6):11-13.
YANG Li, TIAN Junying. Research of dyeing properties of natural gardenia blue on wool fabric[J]. Wool Textile Journal, 2011,39(6):11-13.
[11] 马晓东, 周胜华. 栀子蓝上染羊毛纤维的热力学研究[J]. 毛纺科技, 2016,44(3):37-40.
MA Xiaodong, ZHOU Shenghua. Thermodynamics and dynamics of dyeing on wool with gardenia blue[J]. Wool Textile Journal, 2016,44(3):37-40.
[12] 沈加加, 高普, 杨颖, 等. 栀子蓝上染壳聚糖处理羊毛的染色动力学[J]. 纺织学报, 2014,35(11):85-88.
SHEN Jiajia, GAO Pu, YANG Ying, et al. Dyeing dynamics of gardenia blue on wool pretreated with chitosan[J]. Journal of Textile Research, 2014,35(11):85-88.
[13] 李冬霞, 王越平, 莫茜婷. 羊毛与羊绒的天然染料染色性能比较[J]. 毛纺科技, 2016,44(1):37-42.
LI Dongxia, WANG Yueping, MO Xiting. Comparison of dyeing properties of cashmere and wool with natural dyes[J]. Wool Textile Journal, 2016,44(1):37-42.
[14] 张丽平, 曾丽娜. 4种天然染料对羊毛织物的染色性能比较[J]. 毛纺科技, 2006,34(7):17-22.
ZHANG Liping, ZENG Lina. Performance of four natural dyes on wool[J]. Wool Textile Journal, 2006,34(7):17-22.
[15] 陈秀芳, 郝文洁, 王晓. 真丝织物天然染料微波染色[J]. 丝绸, 2017,54(9):7-13.
CHEN Xiufang, HAO Wenjie, WANG Xiao. Microwave dyeing of silk fabric with natural dyes[J]. Journal of Silk, 2017,54(9):7-13.
[16] 宋慧君, 丁力志, 曹珂珂, 等. 蚕丝织物的紫胶色素染色研究[J]. 染整技术, 2017,39(12):18-22.
SONG Huijun, DING Lizhi, CAO Keke, et al. Study on dyeing silk fabric with lac pigment[J]. Textile Dyeing and Finishing Journal, 2017,39(12):18-22.
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