纺织学报 ›› 2020, Vol. 41 ›› Issue (05): 176-183.doi: 10.13475/j.fzxb.20190301208

• 综合述评 • 上一篇    下一篇

纤维基表面增强拉曼基底的研究进展

刘爱荣1, 陈艳敏1, 葛凤燕1(), 蔡再生1, 王娟2   

  1. 1.东华大学 生态纺织教育部重点实验室, 上海 201620
    2.石家庄市化学纤维技术创新中心, 河北 石家庄 050000
  • 收稿日期:2019-03-04 修回日期:2020-02-08 出版日期:2020-05-15 发布日期:2020-06-02
  • 通讯作者: 葛凤燕
  • 作者简介:刘爱荣(1996—),女,硕士生。主要研究方向为织物基表面增强拉曼基底。
  • 基金资助:
    国家重点研发计划资助项目(2017YFB0309400)

Progress on fiber-based surface-enhanced Raman scattering substrates

LIU Airong1, CHEN Yanmin1, GE Fengyan1(), CAI Zaisheng1, WANG Juan2   

  1. 1. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. Innovation Center of Shijiazhuang for Chemical Fiber Technology, Shijiazhuang, Hebei 050000, China
  • Received:2019-03-04 Revised:2020-02-08 Online:2020-05-15 Published:2020-06-02
  • Contact: GE Fengyan

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摘要：

为解决传统纤维表面拉曼增强(SERS)基底所存在的稳定性差、操作不便等问题。介绍了柔性SERS基底的优势,总结了目前各类纤维基SERS基底的研究进展及其在痕量检测领域的应用,简述了电磁增强和化学增强2种表面增强拉曼现象的基本原理。综述了纤维纸基SERS、织物基SERS、散纤维及纳米纤维膜SERS基底的制备方法及其应用,并着重介绍了织物基SERS材料的研究现状及其在在线检测应用方面的挑战与机遇。基于织物基SERS材料高度灵敏及灵活检测的特点,展望了其作为可穿戴传感器件用于即时检测和周身环境监测的前景,为拓展智能纺织品的应用领域开辟了新的思路。

关键词: 表面增强拉曼光谱, 柔性基底, 电磁增强, 化学增强, 在线监测, 可穿戴传感器

Abstract:

In view of the poor stability and inconvenient detection process of traditional urface-enhanced Raman scattering (SERS) substrates, the current research and application progress in fiber-based SERS substrates in the field of trace detection were reviewed in this and the advantages of flexible SERS substrates were summarized. The mechanisms of SERS were firstly introduced briefly, including electromagnetic enhancement and chemical enhancement. Secondly, the fabrication methods and practical application of fiber-based SERS, fabric-based SERS, and nanofibrous membranes SERS substrates were reviewed. Emphasis was placed on the research status of fabric-based SERS substrates and their challenges and opportunities in future detection applications. Based on the highly sensitive and flexible detection of fabric-based SERS materials, the potential application as a wearable sensor for instant detection and environmental monitoring was discussed, which leads to new ideas of creation of smart textiles.

Key words: surface-enhanced Raman spectrum, flexible substrate, electromagnetic enhancement, chemical enhancement, online detection, wearable sensor

中图分类号: 

  • O657

图1

原位法SERS-棉织物的制备及拉曼检测流程图"

图2

可循环使用SERS-棉织物的可循环使用性测试流程图"

图3

SERS活性纤维纳米粒子的制备原理及其探针分子检测中的应用"

图4

PmPD/PAN纳米纤维的合成和AgNCs的自组装过程及其检测4-MBA机制示意图"

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