水性聚丙烯酸酯对涂层商标织物图案打印效果的影响

doi:10.13475/j.fzxb.20190700608

纺织学报 ›› 2020, Vol. 41 ›› Issue (08): 55-62.doi: 10.13475/j.fzxb.20190700608

水性聚丙烯酸酯对涂层商标织物图案打印效果的影响

朱清¹^,², 徐丹丹¹, 潘园歌¹, 王成龙¹^,², 郑今欢¹^,³()

1.浙江理工大学先进纺织材料与制备技术教育部重点实验室, 浙江杭州 310018
2.浙江省清洁染整技术研究重点实验室, 浙江绍兴 312000
3.浙江理工大学生态染整技术教育部工程研究中心, 浙江杭州 310018

收稿日期:2019-07-01 修回日期:2020-03-23 出版日期:2020-08-15 发布日期:2020-08-21
通讯作者: 郑今欢
作者简介:朱清(1994—),女,硕士生。主要研究方向为绿色环保型涂层技术及其在纺织品上的应用。
基金资助:
浙江省清洁染整技术研究重点实验室开放基金项目(1810)

Influence of waterborne polyacrylate on printing effect of coated label fabrics

ZHU Qing¹^,², XU Dandan¹, PAN Yuange¹, WANG Chenglong¹^,², ZHENG Jinhuan¹^,³()

1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou,Zhejiang 310018, China
2. Zhejiang Key Laboratory of Clean Dyeing and Finishing Technology, Shaoxing,Zhejiang 312000, China
3. Engineering Research Center for Eco-Dyeing and Finishing of Textiles,Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China

Received:2019-07-01 Revised:2020-03-23 Online:2020-08-15 Published:2020-08-21
Contact: ZHENG Jinhuan

摘要/Abstract

摘要：

为解决涂层商标织物打印时吸墨速干性能差、打印图案不清晰等问题,通过对涂层剂粒径、涂层浆料流变性能,以及涂层商标织物的质量损失率、接触角和清晰度等性能进行测试,研究不同改性结构的涂层剂对涂层商标织物打印效果的影响,建立涂层表面结构与打印效果间的相关性。结果表明:涂层商标织物0.001~0.010 μm² 孔面积区间的孔隙率高于0.509%时,喷印图案易出现露白情况,且随着孔隙率的升高,露白现象加剧;当0.1~1.0 μm² 区间的孔隙率高于2.656%时,易出现墨水渗化现象;在1~100 μm²的孔面积区域中,微孔尺寸大都分布在1 μm² 左右,当该区域的孔隙率过高(超过9%以上)时,涂层商标织物表面大孔结构较多,打印文本图案的连续性较差。

关键词: 商标织物, 水性聚丙烯酸酯, 吸墨速干性能, 打印清晰度, 商标打印

Abstract:

In order to solve the problems of slow drying and low print resolution in coated label fabrics, this paper reported the influence of coating agents with different modified structures on the printing effect of coated label fabrics by testing the particle size of coating agent, rheological properties of coating slurry, weight loss rate, contact angle and printing resolution of coated label fabrics. The correlation between the coating surface structure and printing effect was established. The findings indicate that when the coated label fabrics have porosity higher than 0.509% for the pore areas ranging from 0.001 to 0.010 μm², the printed pattern tends to show bad coverage, and the phenomenon is exacerbated with the increase of porosity. When the porosity ranging from 0.1 to 1 μm² is higher than 2.656%, ink bleeding occurs. The micropore size is mostly distributed around 1 μm² in the interval of 1-100 μm². If the porosity in this interval is too high(more than 9%), there are more large pores on the surface of the coated label fabric, resulting in poor continuity of the printed patterns.

Key words: label fabric, waterborne polyacrylate, ink absorption and quick drying performance, print resolution, label printing

中图分类号:

TS195.5

朱清, 徐丹丹, 潘园歌, 王成龙, 郑今欢. 水性聚丙烯酸酯对涂层商标织物图案打印效果的影响[J]. 纺织学报, 2020, 41(08): 55-62.

ZHU Qing, XU Dandan, PAN Yuange, WANG Chenglong, ZHENG Jinhuan. Influence of waterborne polyacrylate on printing effect of coated label fabrics[J]. Journal of Textile Research, 2020, 41(08): 55-62.

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涂层剂名称	平均粒径/nm	方差/nm²
改性纯丙乳液	95	0.247
改性苯丙乳液	95	0.247
自交联醋丙乳液	133	5.830
环氧改性自交联丙烯酸乳液	104	0.459

涂层浆原料	平均宽度/mm	方差/nm²
改性纯丙乳液	1.49	0.000 25
改性苯丙乳液	1.49	0.000 22
自交联醋丙乳液	1.45	0.000 42
环氧改性自交联丙烯酸乳液	1.43	0.000 31

涂层浆原料	0.001~0.010 μm²			0.01~0.10 μm²			0.1~1.0 μm²			1~100 μm²
涂层浆原料	孔数	平均孔面积/μm²	孔隙率/%	孔数	平均孔面积/μm²	孔隙率/%	孔数	平均孔面积/μm²	孔隙率/%	孔数	平均孔面积/μm²	孔隙率/%
改性纯丙乳液	20 648	0.005	0.602	5 345	0.029	0.882	1 542	0.308	2.656	401	3.950	10.108
改性苯丙乳液	17 443	0.005	0.509	6 124	0.028	0.970	1 246	0.320	2.236	430	3.783	9.117
自交联醋丙乳液	21 041	0.005	0.615	5 825	0.029	0.960	1 782	0.328	3.280	515	4.666	13.500
环氧改性自交联丙烯酸乳液	30 347	0.005	0.889	7 255	0.026	1.042	1 650	0.335	3.101	531	4.398	13.100

涂层浆原料	耐干摩擦色牢度	耐湿摩擦色牢度
改性纯丙乳液	3	2~3
改性苯丙乳液	4	3~4
自交联醋丙乳液	3	2~3
环氧改性自交联丙烯酸乳液	2	2

水性聚丙烯酸酯对涂层商标织物图案打印效果的影响

Influence of waterborne polyacrylate on printing effect of coated label fabrics

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