纺织学报 ›› 2020, Vol. 41 ›› Issue (05): 94-98.doi: 10.13475/j.fzxb.20190704206

• 染整与化学品 • 上一篇    下一篇

小檗碱在聚丙烯腈/醋酸纤维素复合纤维染色中的应用

刘艳春1,2, 白刚1,2()   

  1. 1.绍兴文理学院 纺织服装学院, 浙江 绍兴 312000
    2.浙江省清洁染整技术研究重点实验室, 浙江 绍兴 312000
  • 收稿日期:2019-07-12 修回日期:2019-10-04 出版日期:2020-05-15 发布日期:2020-06-02
  • 通讯作者: 白刚
  • 作者简介:刘艳春(1971—),女,教授,博士。主要研究方向为功能纺织品开发。
  • 基金资助:
    浙江省基础公益研究计划项目(LCJ18E030002);浙江省基础公益研究计划项目(LCF18E090006)

Application of berberine in polyacrylonitrile/cellulose acetate composite fiber dyeing

LIU Yanchun1,2, BAI Gang1,2()   

  1. 1. School of Textile and Apparel, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
  • Received:2019-07-12 Revised:2019-10-04 Online:2020-05-15 Published:2020-06-02
  • Contact: BAI Gang

RichHTML

3

PDF (PC)

38

摘要：

为拓展小檗碱的应用领域,对小檗碱理化性能进行研究,并将小檗碱应用于聚丙烯腈/醋酸纤维素复合纤维染色。通过正交试验对聚丙烯腈/醋酸纤维素复合纤维小檗碱染色工艺进行优化,测定了上染速率曲线和吸附等温线,并测试了染色后聚丙烯腈/醋酸纤维素复合纤维对金黄色葡萄球菌和大肠杆菌的抗菌性能。结果表明:小檗碱能溶于水,在pH值3~11范围内耐酸碱稳定性好,在120 ℃以下热稳定性好;小檗碱对聚丙烯腈/醋酸纤维素复合纤维染色吸附等温线呈Langmuir型,小檗碱染色半染时间为15.5 min,平衡上染百分率为97%;最佳染色工艺为:染色温度为100 ℃,染色保温时间为40 min,染色pH值为8;染色后聚丙烯腈/醋酸纤维素复合纤维对金黄色葡萄球菌和大肠杆菌的抑菌率均可达到92%以上。

关键词: 小檗碱, 天然染料, 聚丙烯腈/醋酸纤维素复合纤维, 理化性能, 纤维染色, 抗菌性能

Abstract:

In order to widen the application domain of berberine, the physical and chemical properties of berberine were studied. Dyeing of polyacrylonitrile/cellulose acetate composite fibers with berberine was also investigated in this research. The dyeing process of polyacrylonitrile/cellulose acetate composite fiber with berberine was optimized through the use of orthogonal test. The dyeing rate curve and adsorption isotherm were determined, and the antimicrobial activity of dyed samples against Staphylococcus aureus and Escherichia coli was tested. The results indicate that berberine can be dissolved in water, and it has good acid and alkali resistance in the pH range of 3-11 and good thermal stability below 120 ℃. The dyeing adsorption isotherm of berberine on polyacrylonitrile/cellulose acetate composite fiber present Langmuir sorption model. The half dyeing time of berberine is 15.5 minutes, and the percentage of equilibrium dyeing is 97%. The best dyeing condition of berberine is found to be: dyeing temperature is 100 ℃, dyeing time is 40 min, dyeing pH value is 8. After dyeing, the bacteriostatic rate of polyacrylonitrile/cellulose acetate composite fiber to Staphylococcus aureus and Escherichia coli is over 92%.

Key words: berberine, natural dye, polyacrylonitrile/cellulose acetate composite fiber, physical and chemical properties, fiber dyeing, antimicrobial property

中图分类号: 

  • TS193.62

图1

小檗碱可见光谱图"

表1

pH值对小檗碱溶液稳定性的影响"

pH值 λmax/nm 吸光度A
3 420 0.270
5 419 0.271
7 421 0.266
9 420 0.268
11 420 0.263

表2

温度对小檗碱热稳定性的影响"

温度/℃ λmax/nm 吸光度A
40 419 0.272
60 421 0.269
80 421 0.274
100 419 0.274
120 420 0.272

图2

小檗碱的TG与DTA曲线"

表3

染色正交试验因素水平表"

水平 A B C
染色温度/℃ 保温时间/min pH值
1 40 10 5
2 60 20 7
3 80 30 8
4 100 40 9

表4

染色正交试验结果"

试验号 A B C K/S值
1 1 1 1 2.784 2
2 1 2 2 3.345 1
3 1 3 3 4.427 6
4 1 4 4 4.158 1
5 2 1 2 4.791 4
6 2 2 1 5.383 6
7 2 3 4 5.624 4
8 2 4 3 5.916 2
9 3 1 3 5.612 1
10 3 2 4 6.536 2
11 3 3 1 6.335 7
12 3 4 2 6.714 8
13 4 1 4 6.428 6
14 4 2 3 7.165 8
15 4 3 2 6.802 5
16 4 4 1 6.512 9
K1 3.679 4.904 5.254
K2 5.429 5.608 5.413
K3 6.300 5.798 5.780
K4 6.727 5.825 5.687
R 3.048 0.921 0.526

图3

小檗碱上染速率曲线"

图4

小檗碱吸附等温线"

图5

小檗碱染色提升性曲线"

[1] 陈荣圻. 天然染料及其染色[J]. 染整技术, 2018,40(8):1-7.
CHEN Rongqi. Natural dyes and the dyeing[J]. Textile Dyeing and Finishing Journal, 2018,40(8):1-7.
[2] 陆水峰. 天然染料茶色素对棉织物的染色性能研究[J]. 针织工业, 2018,359(12):49-51.
LU Shuifeng. Dyeing properties of tea natural dye on cotton fabric[J]. Knitting Industries, 2018,359(12):49-51.
[3] NIDHAL Salem, KAMEL Msaada, SALEM Elkahoui, et al. Evaluation of antibacterial, antifungal, and antioxidant activities of safflower natural dyes during flowering[J]. BioMed Research International, 2014,2014:1-10.
[4] ARPANA Kamboj. Consumer awareness for natural dyes[J]. Indian Journal of Health & Wellbeing, 2017,8(9):1012-1014.
[5] 刘艳春, 白刚. 蚕丝的红曲红素生态媒染染色[J]. 纺织学报, 2012,33(4):78-81.
LIU Yanchun, BAI Gang. Bioecological mordant dyeing of silk with monascorubrin[J]. Journal of Textile Research, 2012,33(4):78-81.
[6] SHALINI Chandravanshi. Effect of ionic surfactants on the adsorption of quercus infectoria natural dye on cotton fiber: a kinetic study[J]. Journal of Dispersion Science & Technology, 2014,35(10):1427-1433.
[7] PARISA Hasanein, MASUMEH Ghafari-Vahed, IRAJ Khodadadi. Effects of isoquinoline alkaloid berberine on lipid peroxidation, antioxidant defense system, and liver damage induced by lead acetate in rats[J]. Redox Report. 2017,22(1):42-50.
pmid: 26871196
[8] MISTRY Bhupendra, KEUM Young Soo, KIM Doo Hwan. Synjournal, antioxidant and anticancer screenings of berberine-indole conjugates[J]. Research on Chemical Intermediates, 2016,42(4):3241-3256.
[9] ZHOU Yan, LIU Shiqing. Sustained release effects of berberine-loaded chitosan microspheres on in vitro chondrocyte culture[J]. Drug Development & Industrial Pharmacy, 2017,43(10):1703-1714.
doi: 10.1080/03639045.2017.1339076 pmid: 28585864
[10] 严涌, 邓东海, 江大伦. 醋青/改性涤纶/棉织物染色及牢度提升[J]. 印染, 2018,44(18):29-32.
YAN Yong, DENG Donghai, JIANG Dalun. Dyeing and fastness improvement of acetate acrylic/modified polyester/cotton fabric[J]. China Dyeing & Finising, 2018,44(18):29-32.
[1] 黎俊妤, 蒋培清, 张文奇, 李文斌. 原子层沉积技术对纤维素膜功能化的影响[J]. 纺织学报, 2020, 41(12): 26-30.
[2] 姜兴茂, 刘奇, 郭琳. 二氧化硅包覆银铜纳米颗粒的结构及其抗菌性能[J]. 纺织学报, 2020, 41(11): 102-108.
[3] 张艳艳, 詹璐瑶, 王培, 耿俊昭, 付飞亚, 刘向东. 用无机纳米粒子制备耐久性抗菌棉织物的研究进展[J]. 纺织学报, 2020, 41(11): 174-180.
[4] 秦益民. 含银海藻酸盐医用敷料的临床应用[J]. 纺织学报, 2020, 41(09): 183-190.
[5] 占镠祥, 李婉, 王高军, 赵先丽, 王妮, 李毓陵. 微波处理在蛋白质纤维加工中的应用研究进展[J]. 纺织学报, 2020, 41(08): 128-134.
[6] 贾琳, 王西贤, 陶文娟, 张海霞, 覃小红. 聚丙烯腈抗菌复合纳米纤维膜的制备及其抗菌性能[J]. 纺织学报, 2020, 41(06): 14-20.
[7] 王婷婷, 刘梁, 曹秀明, 王清清. 竹红菌素-聚(甲基丙烯酸甲酯-co-甲基丙烯酸)纳米纤维的制备及其光敏抗菌性能[J]. 纺织学报, 2020, 41(05): 1-7.
[8] 王晓菲, 万爱兰. 紫外线辐照聚吡咯/银导电涤纶织物的制备[J]. 纺织学报, 2020, 41(04): 112-116.
[9] 吴倩倩, 李珂, 杨立双, 付译鋆, 张瑜, 张海峰. 载药聚偏氟乙烯伤口敷料的制备及其性能 [J]. 纺织学报, 2020, 41(01): 26-31.
[10] 张治斌, 李刚, 毛森贤, 厉巽巽, 陈玉霜, 毛青山, 李翼, 潘志娟, 王晓沁. 丝素蛋白/壳聚糖微球制备及其抗菌性能[J]. 纺织学报, 2019, 40(10): 7-12.
[11] 王文聪, 范静静, 丁超, 王鸿博. 多功能复合导电毛织物的制备及其性能[J]. 纺织学报, 2019, 40(08): 117-123.
[12] 吴娇, 于湖生, 万兴云, 田平, 李慧敏, 侯晓欣. 抗菌防螨防霉功能改性粘胶纤维的制备及其性能[J]. 纺织学报, 2019, 40(07): 19-23.
[13] 黄程博, 任学宏. 静电纺抗菌聚丙烯腈纳米纤维膜制备及其性能[J]. 纺织学报, 2019, 40(05): 7-11.
[14] 孙辉, 张恒源, 咸玉龙, 周传凯, 于斌. TiO2-Ag/聚乳酸纳米复合纤维的制备及其抗菌性能[J]. 纺织学报, 2019, 40(04): 1-6.
[15] 魏娜 康卫民 孙诚 程博闻. 静电纺核-壳纳米包装膜的制备及其抗菌性能[J]. 纺织学报, 2018, 39(12): 13-17.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发