纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 175-183.doi: 10.13475/j.fzxb.20200607109

• 综合述评 • 上一篇    下一篇

纤维素基有机-无机纳米光催化复合材料制备及其水处理应用的研究进展

张婷婷1,2,3, 许可欣1, 金梦甜2,3, 葛世洁2,3, 高国洪4, 蔡一啸1,2,3(), 王华平2,3   

  1. 1.东华大学 环境科学与工程学院, 上海 201620
    2.东华大学 材料科学与工程学院, 上海 201620
    3.东华大学 纤维材料改性国家重点实验室, 上海 201620
    4.江苏国望高科纤维有限公司, 江苏 苏州 215226
  • 收稿日期:2020-06-30 修回日期:2021-01-08 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 蔡一啸
  • 作者简介:张婷婷(1998—),女,硕士生。主要研究方向为纤维材料的环境水处理应用。
  • 基金资助:
    产业用纺织品教育部工程研究中心开放课题项目(274-10-0001)

Recent progress in preparation of cellulose-based organic-inorganic photocatalysts nanohybrids and it's application in water treatment

ZHANG Tingting1,2,3, XU Kexin1, JIN Mengtian2,3, GE Shijie2,3, GAO Guohong4, CAI Yixiao1,2,3(), WANG Huaping2,3   

  1. 1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
    4. Jiangsu Guowang High-Tech Fiber Co., Ltd., Suzhou, Jiangsu 215226, China
  • Received:2020-06-30 Revised:2021-01-08 Published:2021-07-15 Online:2021-07-22
  • Contact: CAI Yixiao

RichHTML

14

PDF (PC)

227

摘要：

为改善传统纳米粉体光催化剂易团聚导致催化活性降低,且难以重复利用等问题,针对性地开发具有高活性位点暴露、高分散性和稳定性的纤维素基光催化复合材料是推动光催化技术产业化应用的有效途径。综述了国内外纤维素基有机-无机纳米光催化复合材料的研究进展。首先从纤维素的不同制备形态角度出发,分析了纳米纤维素、纤维素膜材料、纤维素气凝胶材料与纳米光催化材料的设计合成与制备机制,重点阐述了其在环境领域的最新应用进展,最后提出纤维素基光催化材料的发展前景以及存在的问题与局限性,为纤维素基功能材料今后的规模化制备和在环境修复材料领域的广泛应用提供参考。

关键词: 纤维素功能材料, 环境修复, 有机-无机纳米复合材料, 高级氧化技术, 印染废水处理

Abstract:

With the aim of solving the agglomeration of traditional nano-sized photocatalysts particles that leads to low catalytic activity and recycling difficulty, it is imperative to promote the scalable application of advanced photocatalytic technology using cellulose based hybrid photocatalysts with high active site exposure, high dispersion and long-term stability. This review summarizes the recent progress in worldwide research on cellulose-based organic-inorganic photocatalysts nanohybrids. In terms of different cellulose forms, the fabrication and preparation principle of nanocellulose, cellulose-based membrane, cellulose-based aerogel and their application in the fields of water treatment are discussed. The prospect of cellulose based photocatalytic materials and the existing scientific questions and limitations are proposed. It is anticipated that this review can be used as a reference for preparation and industrialization of cellulose-based functional materials, especially in areas of environmental remediation.

Key words: cellulose-based functional material, environmental remediation, organic-inorganic nanohybrid, advanced oxidation technology, dyeing and printing wastewater treatment

中图分类号: 

  • TS102.5

表1

纳米纤维素的分类与制备方法"

名称 制备方法 直径/nm 长度/nm 聚合度
CNF 机械法、
TEMPO氧化法 		5~60 1 000~10 000 ≥500
CNC 酸水解法 5~70 100~250 500~15 000
BC 细菌合成法 20~100 呈纤维网络结构 4 000~10 000

表2

半导体/纤维素复合材料用于纺织印染废水的净化"

光催化材料 制备形态 污染物 光源(波长) 降解率/% 时间/min 参考文献
TiO2/C/棉纤维素 纳米纤维 X-BR 紫外光 90.0 15 [31]
GO@TiO2/纤维素 纳米纤维 IC
MB 		40 W紫外光 (320~400 nm) 99.8
98.3 		150
250 		[32]
C掺杂 ZnO/纤维素 纳米颗粒 MO 6 W (200~400 nm) 95.4 120 [33]
ZIF-8/CNC 纳米颗粒 MB 太阳光 99.8 300 [34]
ZnO/CuO/CNC 纳米颗粒 RB 20 W 紫外光 99.7 40 [35]
BiOBr/纤维素微晶 纳米颗粒 RhB 300 W氙灯(>420 nm) 90.0 70 [36]
g-C3N4/CA 膜 RhB 太阳光 99.0 150 [37]
TiO2-Au/纤维素 膜 RhB 500 W氙灯(>400 nm) 94.99 300 [38]
H4SiW12O40/CA 膜 MO 300 W 汞灯 94.6 120 [39]
TiO2/PDA/BC 膜 MO
RhB
MB 		500 W汞灯(>320 nm) 95.1
100.0
99.5 		30
60
20 		[40]
g-C3N4/纤维素 气凝胶 MB 350 W氙灯(>400 nm) 99.8 80 [41]
TiO2/ CNF 气凝胶 MB 汞灯(365 nm) 98.1 20 [42]
Cu2O/CBA 气凝胶 MB 350 W氙灯(>400 nm) 95.79 60 [43]
CuS/CBA 气凝胶 MB 500 W氙灯(>400 nm) 94.1 60 [44]
SiO2-WxTiO2/纤维素 气凝胶 RhB 125 W汞灯(>400 nm) 95.0 120 [45]
β-FeOOH/纤维素 水凝胶 MB 300 W氙灯(>420 nm) 99.89 30 [46]

表3

半导体/纤维素复合材料用于重金属离子的去除"

光催化材料 制备形态 污染物 光源 去除率/% 时间/min 参考文献
P25/CAM 一体式 Cr6+ 1700 W氙弧灯(280~400 nm) 100 90 [49]
TiO2/CNC 纳米颗粒 Cr6+ 300 W氙弧灯(420 nm) 96 80 [50]
N掺杂C/纤维素 纳米颗粒 Cr6+ 500 W氙灯(>420 nm) 80 300 [51]
ZnIn2S4/CNF 纳米颗粒 Cr6+ 300 W氙灯(>420 nm) 100 90 [12]
BiOBr/CCNF 纳米颗粒 Cr6+ 200 W LED灯 100 60 [52]
SWCNT/Fe3O4/TiO2/壳聚糖/CA 纳米纤维 As5+和Cr6+ 30 W UV灯(365 nm) >95 60 [53]
g-C3N4/CA 薄膜 Cr6+ 300 W氙灯(380~750 nm) 95 100 [37]
[1] CAREY J H, LAWRENCE J, TOSINE H M. Photodechlorination of PCB's in the presence of titanium dioxide in aqueous suspensions[J]. Bulletin of Environmental Contamination and Toxicology, 1976, 16(6):697-701.
doi: 10.1007/BF01685575
[2] JIANG Y F, LAWAN I, ZHOU W M, et al. Synjournal, properties and photocatalytic activity of a semiconductor/cellulose composite for dye degradation: a review[J]. Cellulose, 2019, 27(2):595-609.
doi: 10.1007/s10570-019-02851-w
[3] WANG S, LU A, ZHANG L N. Recent advances in regenerated cellulose materials[J]. Progress in Polymer Science, 2016, 53:169-206.
doi: 10.1016/j.progpolymsci.2015.07.003
[4] MOHAMED M A, MUTALIB M A, HIR Z, et al. An overview on cellulose-based material in tailoring bio-hybrid nanostructured photocatalysts for water treatment and renewable energy applications[J]. International Journal of Biological Macromolecules, 2017, 103:1232-1256.
doi: 10.1016/j.ijbiomac.2017.05.181
[5] MOHAMED M A, SALLEH W N W, JAAFAR J, et al. Incorporation of N-doped TiO2 nanorods in regenerated cellulose thin films fabricated from recycled newspaper as a green portable photocatalyst[J]. Carbohydrate Polymers, 2015, 133:429-437.
doi: 10.1016/j.carbpol.2015.07.057
[6] TAN K, HEO S, FOO M, et al. An insight into nanocellulose as soft condensed matter: challenge and future prospective toward environmental sustainability[J]. Science of the Total Environment, 2019, 650:1309-1326.
doi: 10.1016/j.scitotenv.2018.08.402
[7] 付时雨. 纤维素的研究进展[J]. 中国造纸, 2019, 38(6):54-64.
FU Shiyu. Progress in cellulose research[J]. China Pulp & Paper, 2019, 38(6):54-64.
[8] MOON R J, MARTINI A, NAIRN J, et al. Cellulose nanomaterials review: structure, properties and nanocomposites[J]. Chemical Society Reviews, 2011, 40(7):3941-94.
doi: 10.1039/c0cs00108b
[9] 张思航, 付润芳, 董立琴, 等. 纳米纤维素的制备及其复合材料的应用研究进展[J]. 中国造纸, 2017, 36(1):67-74.
ZHANG Sihang, FU Runfang, DONG Liqin, et al. Research progress on preparation of nano cellulose and its application in composites[J]. China Pulp & Paper, 2017, 36(1):67-74.
[10] 姚一军, 王鸿儒. 纤维素化学改性的研究进展[J]. 材料导报, 2018, 32(19):3478-3488.
YAO Yijun, WANG Hongru. An overview on chemical modification of cellulose[J]. Materials Reports, 2018, 32(19):3478-3488.
[11] TIAN C H, TAO X, LUO S, et al. Cellulose nanofibrils anchored Ag on graphitic carbon nitride for efficient photocatalysis under visible light[J]. Environmental Science: Nano, 2018, 5(9):2129-2143.
doi: 10.1039/C8EN00570B
[12] QIU J H, LI M, YANG L Y, et al. Facile construction of three-dimensional netted ZnIn2S4 by cellulose nanofibrils for efficiently photocatalytic reduction of Cr(VI)[J]. Chemical Engineering Journal, 2019, 375:121990.
doi: 10.1016/j.cej.2019.121990
[13] 朱亚崇, 吴朝军, 于冬梅, 等. 纳米纤维素制备方法的研究现状[J]. 中国造纸, 2020, 39(9):1-10.
ZHU Yachong, WU Chaojun, YU Dongmei, et al. Research status of nanocellulose preparation methods[J]. China Pulp & Paper, 2020, 39(9):1-10.
[14] XUE J, SONG F, DONG X, et al. Controlling self-assembly of cellulose nanocrystal to synergistically regulate (001) reactive facets and hierarchical pore structure of anatase nano-TiO2 for high photocatalytic activity[J]. ACS Sustainable Chemistry & Engineering, 2018, 7(2):1973-1979.
[15] LIU F, SUN Y B, GU J Y, et al. Highly efficient photodegradation of various organic pollutants in water: rational structural design of photocatalyst via thiol-ene click reaction[J]. Chemical Engineering Journal, 2020, 381:122631.
doi: 10.1016/j.cej.2019.122631
[16] 张金明, 张军. 基于纤维素的先进功能材料[J]. 高分子学报, 2010(12):1376-1398.
ZHNAG Jinming, ZHANG Jun. Advanced functional materials based on cellulose[J]. Acta Polymerica Sinica, 2010(12):1376-1398.
[17] WU Y L, YAN Y S, PAN J M, et al. Fabrication and evaluation of molecularly imprinted regenerated cellulose composite membranes via atom transfer radical polymerization[J]. Chinese Chemical Letters, 2014, 25(2):273-278.
doi: 10.1016/j.cclet.2013.11.019
[18] MOHAMED M A, SALLEH W N W, JAAFAR J, et al. Physicochemical characteristic of regenerated cellulose/N-doped TiO2 nanocomposite membrane fabricated from recycled newspaper with photocatalytic activity under UV and visible light irradiation[J]. Chemical Engineering Journal, 2016, 284:202-215.
doi: 10.1016/j.cej.2015.08.128
[19] 钱怡帆, 周堂, 张礼颖, 等. 聚丙烯腈/醋酸纤维素/TiO2复合纳米纤维膜的制备及其光催化降解性能[J]. 纺织学报, 2020, 41(5):8-14.
QIAN Yifan, ZHOU Tang, ZHANG Liying, et al. Preparation of polyacrylonitrile/cellulose acetate/TiO2 composite nanofiber membrane and its photocatalytic degradation performance [J]. Journal of Textile Research, 2020, 41(5):8-14.
[20] ZHANG C, FU Z H, DAI B H, et al. Biochar sulfonic acid immobilized chlorozincate ionic liquid: an efficiently biomimetic and reusable catalyst for hydrolysis of cellulose and bamboo under microwave irradiation[J]. Cellulose, 2014, 21(3):1227-1237.
doi: 10.1007/s10570-014-0167-9
[21] FU F Y, GU J Y, XU X Y, et al. Interfacial assembly of ZnO-cellulose nanocomposite films via a solution process: a one-step biomimetic approach and excellent photocatalytic properties[J]. Cellulose, 2016, 24(1):147-162.
doi: 10.1007/s10570-016-1087-7
[22] FU F Y, LI L Y, LIU L J, et al. Construction of cellulose based ZnO nanocomposite films with antibacterial properties through one-step coagulation[J]. ACS Applied Materials Interfaces, 2015, 7(4):2597-606.
doi: 10.1021/am507639b
[23] ZHAO H X, CHEN S, QUAN X, et al. Integration of microfiltration and visible-light-driven photocatalysis on g-C3N4 nanosheet/reduced graphene oxide membrane for enhanced water treatment[J]. Applied Catalysis B: Environmental, 2016, 194:134-140.
doi: 10.1016/j.apcatb.2016.04.042
[24] GAO Z, YANG H P, LI J W, et al. Simultaneous evaporation and decontamination of water on a novel membrane under simulated solar light irradiation[J]. Applied Catalysis B: Environmental, 2020, 267:118695.
doi: 10.1016/j.apcatb.2020.118695
[25] 王世贤, 降帅, 李萌萌, 等. 硅烷偶联剂改性纳米纤维素气凝胶的制备及其表征[J]. 纺织学报, 2020, 41(3):33-38.
WANG Shixian, JIANG Shuai, LI Mengmeng, et al. Preparation and characterization of nanocellulose aerogel modified by silane coupling agent[J]. Journal of Textile Research, 2020, 41(3):33-38.
[26] SHI F, YU T, HU S C, et al. Synjournal of highly porous SiO2-(WO3)x·TiO2 composite aerogels using bacterial cellulose as template with solvothermal assisted crystallization[J]. Chemical Engineering Journal, 2016, 292:105-112.
doi: 10.1016/j.cej.2016.02.022
[27] ZHANG J, CAO Y W, FENG J C, et al. Graphene-oxide-sheet-induced gelation of cellulose and promoted mechanical properties of composite aerogels[J]. The Journal of Physical Chemistry C, 2012, 116(14):8063-8068.
doi: 10.1021/jp2109237
[28] WEI J, JIAO X L, WANG T, et al. Fast, simultaneous metal reduction/deposition on electrospun a-WO3/PAN nanofiber membranes and their potential applications for water purification and noble metal recovery[J]. Journal of Materials Chemistry A, 2018, 6(30):14577-14586.
doi: 10.1039/C8TA03686A
[29] QIU J L, FAN P, YUE C L, et al. Multi-networked nanofibrous aerogel supported by heterojunction photocatalysts with excellent dispersion and stability for photocatalysis[J]. Journal of Materials Chemistry A, 2019, 7(12):7053-7064.
doi: 10.1039/C9TA00388F
[30] RAJAGOPAL S, PARAMASIVAM B, MUNIYASAMY K J S, et al. Photocatalytic removal of cationic and anionic dyes in the textile wastewater by H2O2 assisted TiO2 and micro-cellulose composites[J]. Separation Purification Technology, 2020, 252:117444.
doi: 10.1016/j.seppur.2020.117444
[31] 吉强, 王晓, 戚俊然, 等. 光接枝丙烯酸棉纤维素基 TiO2/C光催化剂的制备与光催化性[J]. 纺织学报, 2017, 38(10):75-80.
JI Qiang, WANG Xiao, QI Junran, et al. Preparation and photocatalysis of acrylic acid grafted cotton cellulose-based TiO2/C photocatalyst [J]. Journal of Textile Research, 2017, 38(10):75-80.
[32] ABOAMERA N M, MOHAMED A, SALAMA A, et al. An effective removal of organic dyes using surface functionalized cellulose acetate/graphene oxide composite nanofibers[J]. Cellulose, 2018, 25(7):4155-4166.
doi: 10.1007/s10570-018-1870-8
[33] XIAO H, SHAN Y W, ZHANG W Y, et al. C-nanocoated ZnO by TEMPO-oxidized cellulose templating for improved photocatalytic performance[J]. Carbohydrate Polymers, 2020, 235:115958.
doi: 10.1016/j.carbpol.2020.115958
[34] MA J, HU J, TANG Y, et al. In-situ preparation of hollow cellulose nanocrystals/zeolitic imidazolate framework hybrid microspheres derived from Pickering emulsion[J]. Journal of Colloid and Interface Science, 2020, 572:160-169.
doi: 10.1016/j.jcis.2020.03.076
[35] ELFEKY A S, SALEM S S, ELZAREF A S, et al. Multifunctional cellulose nanocrystal /metal oxide hybrid, photo-degradation, antibacterial and larvicidal activities[J]. Carbohydrate Polymers, 2020, 230:115711.
doi: 10.1016/j.carbpol.2019.115711
[36] ZHOU W M, SUN S C, JIANG Y F, et al. Template in situ synjournal of flower-like BiOBr/microcrystalline cellulose composites with highly visible-light photocatalytic activity[J]. Cellulose, 2019, 26(18):9529-9541.
doi: 10.1007/s10570-019-02722-4
[37] WANG S Y, LI F, DAI X H, et al. Highly flexible and stable carbon nitride/cellulose acetate porous films with enhanced photocatalytic activity for contaminants removal from wastewater[J]. Journal of Hazardous Materials, 2020, 384:121417.
doi: 10.1016/j.jhazmat.2019.121417
[38] YU Y Q, ZHU X R, WANG L R, et al. A simple strategy to design 3-layered Au-TiO2 dual nanoparticles immobilized cellulose membranes with enhanced photocatalytic activity[J]. Carbohydrate Polymers, 2020, 231:115694.
doi: 10.1016/j.carbpol.2019.115694
[39] LI W, LI T T, LI G T, et al. Electrospun H4SiW12O40/cellulose acetate composite nanofibrous membrane for photocatalytic degradation of tetracycline and methyl orange with different mechanism[J]. Carbohydrate Polymers, 2017, 168:153-162.
doi: 10.1016/j.carbpol.2017.03.079
[40] YANG L Y, CHEN C T, HU Y, et al. Three-dimensional bacterial cellulose/polydopamine/TiO2 nanocomposite membrane with enhanced adsorption and photocatalytic degradation for dyes under ultraviolet-visible irradiation[J]. Journal of Colloid and Interface Science, 2020, 562:21-28.
doi: 10.1016/j.jcis.2019.12.013
[41] BAI W D, YANG X G, DU X L, et al. Robust and recyclable macroscopic g-C3N4/cellulose hybrid photocatalysts with enhanced visible light photocatalytic activity[J]. Applied Surface Science, 2020, 504:144179.
doi: 10.1016/j.apsusc.2019.144179
[42] LI S, HAO X F, DAI X D, et al. Rapid photocatalytic degradation of pollutant from water under UV and sunlight via cellulose nanofiber aerogel wrapped by TiO2[J]. Journal of Nanomaterials, 2018. DOI: 10.1155/2018/8752015.
[43] SU X P, LIAO Q, LIU L, et al. Cu2O nanoparticle-functionalized cellulose-based aerogel as high-performance visible-light photocatalyst[J]. Cellulose, 2016, 24(2):1017-1029.
doi: 10.1007/s10570-016-1154-0
[44] SAEED R M Y, BANO Z, SUN J Z, et al. CuS-functionalized cellulose based aerogel as biocatalyst for removal of organic dye[J]. Journal of Applied Polymer Science, 2019, 136(15):47404.
doi: 10.1002/app.47404
[45] LIU D Y, SHI F, LIU J X, et al. Synjournal of SiO2-WxTiO2 composite aerogels via solvothermal crystallization under the guidance of bacterial cellulose followed by freeze drying method[J]. Journal of Sol-Gel Science and Technology, 2017, 84(1):42-50.
doi: 10.1007/s10971-017-4463-3
[46] WANG J M, LI X X, CHENG Q Y, et al. Construction of beta-FeOOH@tunicate cellulose nanocomposite hydrogels and their highly efficient photocatalytic properties[J]. Carbohydr Polym, 2020, 229:115470.
doi: 10.1016/j.carbpol.2019.115470
[47] 覃发梅, 邱学青, 孙川, 等. 纳米纤维素去除水体系重金属离子的研究进展[J]. 化工进展, 2019, 38(7):3390-3401.
QIN Famei, QIU Xueqing, SUN Chuan, et al. Research progress in nanocellulose for the removal of heavy metal ions in water[J]. Chemical Industry and Engineering Progess, 2019, 38(7):3390-3401.
[48] LU M, GUAN X H, XU X H, et al. Characteristic and mechanism of Cr(VI) adsorption by ammonium sulfamate-bacterial cellulose in aqueous solutions[J]. Chinese Chemical Letters, 2013, 24(3):253-256.
doi: 10.1016/j.cclet.2013.01.034
[49] MARINHO B A, CRISTÓVÃO R O, DJELLABI R, et al. Photocatalytic reduction of Cr(VI) over TiO2-coated cellulose acetate monolithic structures using solar light[J]. Applied Catalysis B: Environmental, 2017, 203:18-30.
doi: 10.1016/j.apcatb.2016.09.061
[50] LI Y X, ZHANG J J, ZHAN C B, et al. Facile synjournal of TiO2/CNC nanocomposites for enhanced Cr(VI) photoreduction:synergistic roles of cellulose nanocrystals[J]. Carbohydrate Polymers, 2020, 233:115853.
doi: 10.1016/j.carbpol.2020.115853
[51] LI R Q, HU D, HU K, et al. Coupling adsorption-photocatalytic reduction of Cr(VI) by metal-free N-doped carbon[J]. Science of the Total Environment, 2020, 704:135284.
doi: 10.1016/j.scitotenv.2019.135284
[52] GAN L, GENG A B, SONG C, et al. Simultaneous removal of rhodamine B and Cr(VI) from water using cellulose carbon nanofiber incorporated with bismuth oxybromide: the effect of cellulose pyrolysis temperature on photocatalytic performance[J]. Environmental Research, 2020, 185:109414.
doi: 10.1016/j.envres.2020.109414
[53] ZABIHISAHEBI A, KOUSHKBAGHI S, PISHNAMAZI M, et al. Synjournal of cellulose acetate/chitosan/SWCNT/Fe3O4/TiO2 composite nanofibers for the removal of Cr(VI), As(V), methylene blue and congo red from aqueous solutions[J]. International Journal of Biological Macromolecules, 2019, 140:1296-1304.
doi: 10.1016/j.ijbiomac.2019.08.214
[54] XUE Z X, CAO Y Z, LIU N, et al. Special wettable materials for oil/water separation[J]. Journal of Materials Chemistry A, 2014, 2(8):2445-2460.
doi: 10.1039/C3TA13397D
[55] NASEEM S, WU C M, XU T Z, et al. Oil-water separation of electrospun cellulose triacetate nanofiber membranes modified by electrophoretically deposited TiO2/graphene oxide[J]. Polymers (Basel), 2018, 10(7):746.
doi: 10.3390/polym10070746
[56] YANG X, MA J J, LING J, et al. Cellulose acetate-based SiO2/TiO2 hybrid microsphere composite aerogel films for water-in-oil emulsion separation[J]. Applied Surface Science, 2018, 435:609-616.
doi: 10.1016/j.apsusc.2017.11.123
[57] ZHAO J, CHEN X Y, ZHOU Y H, et al. Efficient removal of oil pollutant via simultaneous adsorption and photocatalysis using La-N-TiO2-cellulose/SiO2 difunctional aerogel composite[J]. Research on Chemical Intermediates, 2020, 46(3):1805-1822.
doi: 10.1007/s11164-019-04064-z
[1] 蒋文雯, 莫慧琳, 樊婷玥, 赵紫瑶, 任煜, 王春霞, 张伟, 臧传锋. Ag6Si2O7/TiO2 复合光催化剂的制备及其对亚甲基蓝的降解性能[J]. 纺织学报, 2021, 42(04): 107-113.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发