纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 175-183.doi: 10.13475/j.fzxb.20200607109

• 综合述评 • 上一篇    下一篇

纤维素基有机-无机纳米光催化复合材料制备及其水处理应用的研究进展

张婷婷1,2,3, 许可欣1, 金梦甜2,3, 葛世洁2,3, 高国洪4, 蔡一啸1,2,3(), 王华平2,3   

  1. 1.东华大学 环境科学与工程学院, 上海 201620
    2.东华大学 材料科学与工程学院, 上海 201620
    3.东华大学 纤维材料改性国家重点实验室, 上海 201620
    4.江苏国望高科纤维有限公司, 江苏 苏州 215226
  • 收稿日期:2020-06-30 修回日期:2021-01-08 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 蔡一啸
  • 作者简介:张婷婷(1998—),女,硕士生。主要研究方向为纤维材料的环境水处理应用。
  • 基金资助:
    产业用纺织品教育部工程研究中心开放课题项目(274-10-0001)

Recent progress in preparation of cellulose-based organic-inorganic photocatalysts nanohybrids and it's application in water treatment

ZHANG Tingting1,2,3, XU Kexin1, JIN Mengtian2,3, GE Shijie2,3, GAO Guohong4, CAI Yixiao1,2,3(), WANG Huaping2,3   

  1. 1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
    4. Jiangsu Guowang High-Tech Fiber Co., Ltd., Suzhou, Jiangsu 215226, China
  • Received:2020-06-30 Revised:2021-01-08 Published:2021-07-15 Online:2021-07-22
  • Contact: CAI Yixiao

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摘要：

为改善传统纳米粉体光催化剂易团聚导致催化活性降低,且难以重复利用等问题,针对性地开发具有高活性位点暴露、高分散性和稳定性的纤维素基光催化复合材料是推动光催化技术产业化应用的有效途径。综述了国内外纤维素基有机-无机纳米光催化复合材料的研究进展。首先从纤维素的不同制备形态角度出发,分析了纳米纤维素、纤维素膜材料、纤维素气凝胶材料与纳米光催化材料的设计合成与制备机制,重点阐述了其在环境领域的最新应用进展,最后提出纤维素基光催化材料的发展前景以及存在的问题与局限性,为纤维素基功能材料今后的规模化制备和在环境修复材料领域的广泛应用提供参考。

关键词: 纤维素功能材料, 环境修复, 有机-无机纳米复合材料, 高级氧化技术, 印染废水处理

Abstract:

With the aim of solving the agglomeration of traditional nano-sized photocatalysts particles that leads to low catalytic activity and recycling difficulty, it is imperative to promote the scalable application of advanced photocatalytic technology using cellulose based hybrid photocatalysts with high active site exposure, high dispersion and long-term stability. This review summarizes the recent progress in worldwide research on cellulose-based organic-inorganic photocatalysts nanohybrids. In terms of different cellulose forms, the fabrication and preparation principle of nanocellulose, cellulose-based membrane, cellulose-based aerogel and their application in the fields of water treatment are discussed. The prospect of cellulose based photocatalytic materials and the existing scientific questions and limitations are proposed. It is anticipated that this review can be used as a reference for preparation and industrialization of cellulose-based functional materials, especially in areas of environmental remediation.

Key words: cellulose-based functional material, environmental remediation, organic-inorganic nanohybrid, advanced oxidation technology, dyeing and printing wastewater treatment

中图分类号: 

  • TS102.5

表1

纳米纤维素的分类与制备方法"

名称 制备方法 直径/nm 长度/nm 聚合度
CNF 机械法、
TEMPO氧化法 		5~60 1 000~10 000 ≥500
CNC 酸水解法 5~70 100~250 500~15 000
BC 细菌合成法 20~100 呈纤维网络结构 4 000~10 000

表2

半导体/纤维素复合材料用于纺织印染废水的净化"

光催化材料 制备形态 污染物 光源(波长) 降解率/% 时间/min 参考文献
TiO2/C/棉纤维素 纳米纤维 X-BR 紫外光 90.0 15 [31]
GO@TiO2/纤维素 纳米纤维 IC
MB 		40 W紫外光 (320~400 nm) 99.8
98.3 		150
250 		[32]
C掺杂 ZnO/纤维素 纳米颗粒 MO 6 W (200~400 nm) 95.4 120 [33]
ZIF-8/CNC 纳米颗粒 MB 太阳光 99.8 300 [34]
ZnO/CuO/CNC 纳米颗粒 RB 20 W 紫外光 99.7 40 [35]
BiOBr/纤维素微晶 纳米颗粒 RhB 300 W氙灯(>420 nm) 90.0 70 [36]
g-C3N4/CA 膜 RhB 太阳光 99.0 150 [37]
TiO2-Au/纤维素 膜 RhB 500 W氙灯(>400 nm) 94.99 300 [38]
H4SiW12O40/CA 膜 MO 300 W 汞灯 94.6 120 [39]
TiO2/PDA/BC 膜 MO
RhB
MB 		500 W汞灯(>320 nm) 95.1
100.0
99.5 		30
60
20 		[40]
g-C3N4/纤维素 气凝胶 MB 350 W氙灯(>400 nm) 99.8 80 [41]
TiO2/ CNF 气凝胶 MB 汞灯(365 nm) 98.1 20 [42]
Cu2O/CBA 气凝胶 MB 350 W氙灯(>400 nm) 95.79 60 [43]
CuS/CBA 气凝胶 MB 500 W氙灯(>400 nm) 94.1 60 [44]
SiO2-WxTiO2/纤维素 气凝胶 RhB 125 W汞灯(>400 nm) 95.0 120 [45]
β-FeOOH/纤维素 水凝胶 MB 300 W氙灯(>420 nm) 99.89 30 [46]

表3

半导体/纤维素复合材料用于重金属离子的去除"

光催化材料 制备形态 污染物 光源 去除率/% 时间/min 参考文献
P25/CAM 一体式 Cr6+ 1700 W氙弧灯(280~400 nm) 100 90 [49]
TiO2/CNC 纳米颗粒 Cr6+ 300 W氙弧灯(420 nm) 96 80 [50]
N掺杂C/纤维素 纳米颗粒 Cr6+ 500 W氙灯(>420 nm) 80 300 [51]
ZnIn2S4/CNF 纳米颗粒 Cr6+ 300 W氙灯(>420 nm) 100 90 [12]
BiOBr/CCNF 纳米颗粒 Cr6+ 200 W LED灯 100 60 [52]
SWCNT/Fe3O4/TiO2/壳聚糖/CA 纳米纤维 As5+和Cr6+ 30 W UV灯(365 nm) >95 60 [53]
g-C3N4/CA 薄膜 Cr6+ 300 W氙灯(380~750 nm) 95 100 [37]
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