聚酯/二氧化硅/橙活性成分改性纤维的制备及其性能

doi:10.13475/j.fzxb.20210201908

纺织学报 ›› 2021, Vol. 42 ›› Issue (12): 21-27.doi: 10.13475/j.fzxb.20210201908

聚酯/二氧化硅/橙活性成分改性纤维的制备及其性能

黄效华¹, 周家良²(), 池姗¹, 刘彦明¹, 伏广伟³, 胡泽旭², 相恒学², 朱美芳²

1.百事基材料(青岛)股份有限公司, 山东青岛 266001
2.东华大学材料科学与工程学院, 上海 201620
3.中国纺织工程学会, 北京 100025

收稿日期:2021-02-07 修回日期:2021-09-02 出版日期:2021-12-15 发布日期:2021-12-29
通讯作者: 周家良
作者简介:黄效华(1967—),男,高级工程师,硕士。主要研究方向为生物功能纤维。
基金资助:
教育部“创新团队发展计划”滚动支持项目(IRT16R13);上海市优秀学术/技术带头人计划项目(20XD1433700);上海市“一带一路”国际合作项目(20520740800);中国博士后科学基金项目(2019M661323);中国博士后科学基金项目(2020TQ0062)

Preparation and properties of polyester/silica/orange active ingredient fiber

HUANG Xiaohua¹, ZHOU Jialiang²(), CHI Shan¹, LIU Yanming¹, FU Guangwei³, HU Zexu², XIANG Hengxue², ZHU Meifang²

1. Bestee Material (Qingdao) Co., Ltd., Qingdao, Shandong 266001, China
2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
3. China Textile Engineering Society, Beijing 100025, China

Received:2021-02-07 Revised:2021-09-02 Published:2021-12-15 Online:2021-12-29
Contact: ZHOU Jialiang

摘要/Abstract

摘要：

为解决天然活性成分改性聚酯纤维生产过程中,天然成分不耐高温易损失导致功能下降的问题,通过分子巢技术将超临界CO₂萃取获得的橙活性成分装载入介孔SiO₂载体中,进而制备具有良好抑菌、抗病毒效果的聚酯/二氧化硅/橙活性成分改性纤维。对改性纤维的形貌结构、化学结构、力学性能、活性成分含量、抗菌性能和抗病毒性能等进行测试与分析。结果表明:制备的介孔SiO₂的尺寸为(100±5) nm,比表面积为729.7 m²/g,平均孔径为 2.55 nm;聚酯/二氧化硅/橙活性成分改性纤维的断裂强度为3.22 cN/dtex,纤维中橙活性成分柚皮甙含量为(0.41±0.05) mg/kg,抑菌率大于或等于91%,抗病毒率大于或等于99%,均显著优于普通聚酯纤维(p<0.01)。

关键词: 聚酯, 二氧化硅, 橙活性成分, 分子巢技术, 超临界CO₂萃取, 抗菌纤维, 抗病毒性能

Abstract:

In order to solve the problem of functional degradation caused by the loss of natural active ingredients in the production process of polyester fibers, the molecular-nesting technology was independently developed. The orange active ingredients obtained by supercritical CO₂ extraction was loaded into mesoporous silica nanoparticles (MSNs) carrier to obtain the polyester/silica/orange active ingre-dient (PET/SiO₂/O) fiber with good antibacterial and antiviral effects. The morphology, chemical structure, mechanical properties, active ingredient content, antibacterial and antiviral properties of the modified fiber were characterized and analyzed. The results show that the size, specific surface area and average pore diameter of the achieved MSNs are (100±5) nm, 729.7 m²/g and 2.55 nm, respectively, and the fracture strength of PET/SiO₂/O fiber is 3.22 cN/dtex. The content of orange active ingredient naringin in PET/SiO₂/O fiber is (0.41±0.05) mg/kg, the antibacterial rate is above 91%, and the antiviral rate is above 99%, which are significantly better than that of the common polyester fibers (p<0.01).

Key words: polyester, silica, orange active ingredient, molecular-nesting technology, supercritical fluent CO₂ extraction, antibacterial fiber, antiviral property

中图分类号:

TQ342.8

黄效华, 周家良, 池姗, 刘彦明, 伏广伟, 胡泽旭, 相恒学, 朱美芳. 聚酯/二氧化硅/橙活性成分改性纤维的制备及其性能[J]. 纺织学报, 2021, 42(12): 21-27.

HUANG Xiaohua, ZHOU Jialiang, CHI Shan, LIU Yanming, FU Guangwei, HU Zexu, XIANG Hengxue, ZHU Meifang. Preparation and properties of polyester/silica/orange active ingredient fiber[J]. Journal of Textile Research, 2021, 42(12): 21-27.

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参考文献 21

[1]	宋登鹏, 周佳艳, 朱坤坤, 等. 纺织用抗菌整理剂的研究进展[J]. 西安工程大学学报, 2020, 34(2):26-36.
	SONG Dengpeng, ZHOU Jiayan, ZHU Kunkun, et al. Research progress in antibacterial agents for textiles[J]. Journal of Xi'an Polytechnic University, 2020, 34(2):26-36.
[2]	王凤, 胡力主. 抗病毒纺织品现状及展望[J]. 纺织科技进展, 2020(7):5-7.
	WANG Feng, HU Lizhu. Status and prospect of antiviral textiles[J]. Progress in Textile Science & Technology, 2020(7):5-7.
[3]	ZHOU Jialiang, HU Zexu, ZABIHI Fatemeh, et al. Progress and perspective of antiviral protective mate-rial[J]. Advanced Fiber Materials, 2020(2):123-139.
[4]	吴均, 杨德莹, 李抒桐, 等. 甜橙精油的化学成分、抑菌和抗氧化活性研究[J]. 食品工业科技, 2016(14):148-153.
	WU Jun, YANG Deying, LI Shutong, et al. Study on chemical components, antimicrobial and antioxidant activity of essential oil from Citrus sinensis[J]. Science and Technology of Food Industry, 2016(14):148-153.
[5]	赵鑫, 张宝月, 黄蓉, 等. 甜橙精油的挥发性成分分析及抗氧化和抑菌活性研究[J]. 应用化学, 2013, 42(3):575-577.
	ZHAO Xin, ZHANG Baoyue, HUANG Rong, et al. Analysis of essential oil of Citrus sinensis and its antioxidative and antimicrobial effectiveness[J]. Chinese Journal of Applied Chemistry, 2013, 42(3):575-577.
[6]	杨宏亮, 田珩, 李沛波, 等. 柚皮苷及柚皮素的生物活性研究[J]. 中药材, 2007, 30(6):752-754.
	YANG Hongliang, TIAN Heng, LI Peibo, et al. Study on the biological activity of naringin and naringenin[J]. Journal of Chinese Madicinal Materials, 2007, 30(6):752-754.
[7]	TUTUNCHI H, NAEINI F, OSTADRAHIMI A, et al. Naringenin, a flavanone with antiviral and anti-inflammatory effects: a promising treatment strategy against COVID-19[J]. Phytotherapy Research, 2020, 73:1-11.
[8]	JO S, KIM S, SHIN D H, et al. Inhibition of SARS-CoV 3CL protease by flavonoids[J]. Journal of Enzyme Inhibition and Medicinal Chemistry, 2020, 35(1):145-151. doi: 10.1080/14756366.2019.1690480
[9]	CHENG L, ZHENG W, LI M, et al. Citrus fruits are rich in flavonoids for immunoregulation and potential targeting ACE2[J]. Preprint, 2020(2):2020020313.
[10]	ALI R, SHAHID A, ALI N, et al. Amelioration of Benzo[a]pyrene-induced oxidative stress and pulmonary toxicity by naringenin in wistar rats: a plausible role of COX-2 and NF-κB[J]. Human & Experimental Toxicology, 2017, 36(4):349-364.
[11]	杨频, 韩玲军, 张立伟. 超临界流体萃取技术在中草药有效成份提取中的应用[J]. 化学研究与应用, 2001, 13(2):128-132.
	YANG Pin, HAN Lingjun, ZHANG Liwei. The principle of the technology of super critical fluid extraction and its application of extraction to effective components of Chinese herbal medicines[J]. Chemical Research and Application, 2001, 13(2):128-132.
[12]	KRESGE C T, LEONOWICZ M E, ROTH W J, et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J]. Nature, 1992, 359(6397):710-712. doi: 10.1038/359710a0
[13]	ALFREDSSON V, ANDERSON M W. Structure of MCM-48 revealed by transmission electron micro-scopy[J]. Chem Mater, 1996, 8(5):1141-1146. doi: 10.1021/cm950568k
[14]	KRUK M, JARONIEC M. Characterization of the porous structure of SBA-15[J]. Chem Mater, 2000, 12(7):1961-1968. doi: 10.1021/cm000164e
[15]	王中平, 孙荣龙, 周龙, 等. 溶胶凝胶法室温合成介孔二氧化硅[J]. 材料导报, 2015(S1):62-65.
	WANG Zhongping, SUN Ronglong, ZHOU Long, et al. Synjournal of mesoporous silicas by sol-gel method at room temperature[J]. Materials Reports, 2015(S1):62-65.
[16]	许磊, 王公慰, 魏迎旭, 等. MCM-41介孔分子筛合成研究: Ⅰ: 水热合成法[J]. 催化学报, 1999, 20(3):247-250.
	XU Lei, WANG Gongwei, WEI Yingxu, et al. Study on synjournal of mesoporous molecular sieve MCM-41: Ⅰ: hydrothermal synjournal method[J]. Chinese Journal of Catalysis, 1999, 20(3):247-250.
[17]	张青山, 张辉森, 郭炳南. 以双子表面活性剂为模板全微波辐射合成介孔分子筛MCM-48[J]. 北京理工大学学报, 2003, 3:394-396.
	ZHANG Qingshan, ZHANG Huisen, GUO Bingnan. Synjournal of mesoporous molecular sieve MCM-48 using surfactant gemini as a template and applying the microwave radiation method[J]. Transactions of Beijing Institute of Technology, 2003, 3:394-396.
[18]	林杰, 廖金华, 蔡基智. 超临界二氧化碳萃取柚皮甙的研究[J]. 中国食品添加剂, 2011, 1:72-76.
	LIN Jie, LIAO Jinhua, CAI Jizhi. Extraction of naringin from shaddock by supercritical CO₂[J]. China Food Additives, 2011, 1:72-76.
[19]	段红梅, 汪希铭, 黄子欣, 等. 纤维基介孔SiO₂药物载体的构建及其释药性能[J]. 纺织学报, 2020, 41(7):15-22.
	DUAN Hongmei, WANG Ximing, HUANG Zixin, et al. Construction and drug release properties of fiber-based mesoporous SiO₂ drug carrier[J]. Journal of Textile Research, 2020, 41(7):15-22.
[20]	YU Senlong, XIANG Hengxue, ZHOU Jialiang, et al. Preparation and characterization of fire resistant PLA fibers with phosphorus flame retardant[J]. Fibers and Polymers, 2017, 18(6):1098-1105. doi: 10.1007/s12221-017-6877-5
[21]	YU Senlong, XIANG Hengxue, ZHOU Jialiang, et al. The synergistic effect of organic phosphorous/α-zirconium phosphate on flame-retardant poly(lactic acid) fiber[J]. Fibers and Polymers, 2018, 19:812-820. doi: 10.1007/s12221-018-7828-5

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样品名称	断裂伸长率/%	线密度/ dtex	断裂强度/ (cN·dtex^-1)
PET纤维	10.21±0.51	144.00	4.15±0.06
PET/SiO₂/O纤维	8.43±0.83	144.00	3.22±0.05
PET/O纤维	8.32±0.62	144.00	2.71±0.04

菌种名称	PET纤维活菌浓度平均值/ (CFU·mL^-1)	PET/SiO₂/O纤维		PET/O纤维		PET/SiO₂纤维
菌种名称	PET纤维活菌浓度平均值/ (CFU·mL^-1)	活菌浓度平均值/(CFU·mL^-1)	平均抑菌率/%	活菌浓度平均值/(CFU·mL^-1)	平均抑菌率/%	活菌浓度平均值/(CFU·mL^-1)	平均抑菌率/%
金黄色葡萄球菌	(1.56±0.07)×10⁷	(1.53±0.09)×10⁵	99.01±0.06	(2.01±0.07)×10⁶	87.12±0.46	(1.53±0.06)×10⁷	—
大肠杆菌	(1.81±0.08)×10⁶	(1.44±0.05)×10⁴	99.02±0.26	(3.07±0.11)×10⁵	83.04±0.63	(1.80±0.12)×10⁶	—
白色念珠菌	(2.51±0.05)×10⁵	(2.07±0.09)×10⁴	91.86±0.45	(4.67±0.09)×10⁴	81.41±0.34	(2.46±0.12)×10⁵	—

纤维名称	病毒滴度的对数平均值 lgTCID₅₀/(20 mL)	TCID₅₀/(20 mL)	抗病毒活性值	抗病毒率/%
PET纤维	7.45±0.05	(2.81±0.31)×10⁷	—	—
PET/SiO₂/O纤维	5.08±0.03	(1.21±0.08)×10⁵	2.37±0.03	99.57±0.04
PET/O纤维	5.41±0.05	(2.57±0.33)×10⁵	2.04±0.05	99.09±0.19
PET/SiO₂纤维	5.80±0.03	(6.27±0.44)×10⁵	1.65±0.03	—

纤维名称	病毒滴度的对数平均值 lgTCID₅₀/(20 mL)	TCID₅₀/(20 mL)	抗病毒活性值	抗病毒率/%
PET纤维	6.54	(3.49±0.21)×10⁶	—	—
PET/SiO₂/O纤维	4.37	(2.36±0.06)×10⁴	2.17±0.01	99.32±0.06

聚酯/二氧化硅/橙活性成分改性纤维的制备及其性能

Preparation and properties of polyester/silica/orange active ingredient fiber

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