纺织学报 ›› 2022, Vol. 43 ›› Issue (12): 181-189.doi: 10.13475/j.fzxb.20210501210

• 综合述评 • 上一篇    下一篇

气凝胶材料在纺织品上的应用研究进展

赵伦玉1,2, 隋晓锋1,2, 毛志平1,2, 李卫东3, 冯雪凌1,2()   

  1. 1.东华大学 化学与化工学院, 上海 201620
    2.东华大学 生态纺织教育部重点实验室, 上海 201620
    3.东华大学 纺织学院, 上海 201620
  • 收稿日期:2021-05-07 修回日期:2021-11-29 出版日期:2022-12-15 发布日期:2023-01-06
  • 通讯作者: 冯雪凌
  • 作者简介:赵伦玉(1995—),女,博士生。主要研究方向为离子凝胶纤维的制备与应用。
  • 基金资助:
    中央高校基本科研业务费专项资金资助项目(2232019A3-03)

Research progress in aerogel materials application for textiles

ZHAO Lunyu1,2, SUI Xiaofeng1,2, MAO Zhiping1,2, LI Weidong3, FENG Xueling1,2()   

  1. 1. College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China
    2. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    3. College of Textiles, Donghua University, Shanghai 201620, China
  • Received:2021-05-07 Revised:2021-11-29 Published:2022-12-15 Online:2023-01-06
  • Contact: FENG Xueling

RichHTML

52

PDF (PC)

289

摘要：

为明晰气凝胶的定义并挖掘其在纺织品上的应用价值,综述了气凝胶材料的定义演变历程以及目前国内外在气凝胶基纺织品上的研究现状。具体分析了气凝胶在纺织品上的3种主要应用方法,即凝胶整体成型法、热黏合法和涂层法的工艺流程及其优缺点;围绕气凝胶基纺织品的4种应用形式,包括热防护纺织品、保暖防寒纺织品、超疏水纺织品和消声隔声纺织品,阐明了气凝胶的作用机制并提出该类应用形式目前面临的问题。最后指出,增强力学性能、优化材料配伍、降低制备成本以及推动智能化转型是气凝胶材料未来的重要发展方向。

关键词: 气凝胶, 成型方法, 功能纺织品, 热防护纺织品, 防寒纺织品, 超疏水, 消声隔声

Abstract:

In order to clarify the definition of aerogel and explore its application value in textiles, the evolution of the definition and the domestic and international research status of aerogel-based textiles were reviewed and summarized. The preparation processes of three main application methods of aerogel in textiles, i.e., gel integral molding method, thermal bonding method and coating method, as well as their advantages and disadvantages were analyzed in detail. Focusing on the four application forms of aerogel-based textiles, including thermal protection textiles, warm and cold-proof textiles, super-hydrophobic textiles and noise and sound insulation textiles, this paper expounded the action mechanism of aerogel and pointed out the problems currently in these application forms. Finally, the review concluded that enhancing mechanical properties, optimizing material compatibility, reducing preparation cost and promoting intelligent transformation would be the significant development directions of aerogel materials for the textile field in the future.

Key words: aerogel, preparation method, functional textile, thermal protection textile, cold-proof textile, super hydrophobic, acoustic insulation

中图分类号: 

  • TS941.73

图1

气凝胶材料"

图2

整体成型法工艺流程图"

图3

热黏合法工艺流程图"

图4

涂层法工艺流程图"

[1] DU A, ZHOU B, ZHANG Z, et al. A special material or a new state of matter: a review and reconsideration of the aerogel[J]. Materials, 2013, 6(3): 941-968.
doi: 10.3390/ma6030941 pmid: 28809350
[2] KISTLER S S. Coherent expanded-aerogels[J]. The Journal of Physical Chemistry, 1932, 36(1): 52-64.
doi: 10.1021/j150331a003
[3] KISTLER S S. Method of producing aerogels:US2093454A[P]. 1937-09-21.
[4] HÜSING N, SCHUBERT U. Aerogels: airy materials: chemistry, structure, and properties[J]. Angewandte Chemie International Edition, 1998, 37(1/2): 22-45.
doi: 10.1002/(SICI)1521-3773(19980202)37:1/2<22::AID-ANIE22>3.0.CO;2-I
[5] 施瓦特福格 F, 鲍姆勒 U. 在水不溶性甲硅烷基化剂中基本上呈球形液凝胶的生产方法: 99802075.3[P]. 2001-03-21.
SHIWATEFUGE F, BAOMULE U. Method of producing substantially spherical lyogels in water insoluble silylating agents: 99802075.3[P]. 2001-03-21.
[6] ALEMÁN J, CHADWICK A V, HE J, et al. Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)[J]. Pure and Applied Chemistry, 2007, 79(10): 1801-1829.
doi: 10.1351/pac200779101801
[7] AEGERTER M A, LEVENTIS N, KOEBEL M M. Aerogels handbook[M]. New York: Springer, 2011: 3.
[8] ALIEV A E, OH J, KOZLOV M E, et al. Giant-stroke, superelastic carbon nanotube aerogel muscles[J]. Science, 2009, 323(5921): 1575-1578.
doi: 10.1126/science.1168312 pmid: 19299612
[9] JIN H, NISHIYAMA Y, WADA M, et al. Nanofibrillar cellulose aerogels[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 240(1): 63-67.
doi: 10.1016/j.colsurfa.2004.03.007
[10] ZIEGLER C, WOLF A, LIU W, et al. Modern inorganic aerogels[J]. Angewandte Chemie International Edition, 2017, 56(43): 13200-13221.
doi: 10.1002/anie.201611552
[11] 孔勇, 沈晓冬, 崔升. 气凝胶纳米材料[J]. 中国材料进展, 2016, 35(8): 569-576.
KONG Yong, SHEN Xiaodong, CUI Sheng. Nano materials of aerogels[J]. Materials China, 2016, 35(8): 569-576.
[12] 魏鹏湾, 闫共芹, 赵冠林, 等. 二氧化硅气凝胶复合隔热材料研究进展[J]. 无机盐工业, 2016, 48(10): 1-6.
WEI Pengwan, YAN Gongqin, ZHAO Guanlin, et al. Research progress of silica aerogel composites for thermal insulation[J]. Inorganic Chemicals Industry, 2016, 48(10): 1-6.
[13] 梁腾隆, 赵晓明. SiO2气凝胶绝热复合材料的研究现状[J]. 成都纺织高等专科学校学报, 2017, 34(2): 238-243.
LIANG Tenglong, ZHAO Xiaoming. Research status of SiO2 aerogel composite with thermal insulation[J]. Journal of Chengdu Textile College, 2017, 34(2): 238-243.
[14] 赵国樑, 李光武, 薛蓉, 等. 气凝胶在纺织服装领域的应用技术现状[J]. 新材料产业, 2021(2): 48-53.
ZHAO Guoliang, LI Guangwu, XUE Rong, et al. Present situation of application technology of aerogel in textile and garment field[J]. Advanced Materials Industry, 2021(2): 48-53.
[15] OH K W, KIM D K, KIM S H. Ultra-porous flexible PET/aerogel blanket for sound absorption and thermal insulation[J]. Fibers and Polymers, 2009, 10(5): 731-737.
doi: 10.1007/s12221-010-0731-3
[16] LI Z, GONG L L, CHENG X D, et al. Flexible silica aerogel composites strengthened with aramid fibers and their thermal behavior[J]. Materials & Design, 2016, 99: 349-355.
[17] XU L, JIANG Y, FENG J, et al. Infrared-opacified Al2O3-SiO2 aerogel composites reinforced by SiC-coated mullite fibers for thermal insulations[J]. Ceramics International, 2015, 41(1): 437-442.
doi: 10.1016/j.ceramint.2014.08.088
[18] 罗佳妮, 吴瑾, 王浣雨, 等. PP/SiO2和PET/SiO2复合气凝胶的制备及性能研究[J]. 产业用纺织品, 2021, 39(2): 41-47,58.
LUO Jiani, WU Jin, WANG Huanyu, et al. Study on preparation and properties of PP/SiO2 and PET/SiO2 composite aerogels[J]. Technical Textiles, 2021, 39(2): 41-47,58.
[19] 吴会军, 梁雄龙, 陈奇良, 等. 整体成型法制备气凝胶隔热保温复合材料[J]. 广州大学学报(自然科学版), 2015, 14(6): 36-40.
WU Huijun, LIANG Xionglong, CHEN Qiliang, et al. Preparation of aerogel composites by monolithic forming method for thermal insulation[J]. Journal of Guangzhou University (Natural Science Edition), 2015, 14(6): 36-40.
[20] 岳晓华. 一种复合SiO2气凝胶隔热毡垫及其制备方法:201410091609.4[P]. 2014-07-16.
YUE Xiaohua. A composite SiO2 aerogel insulation felt and its preparation method: 201410091609.4[P]. 2014-07-16.
[21] XIONG X, YANG T, MISHRA R, et al. Transport properties of aerogel-based nanofibrous nonwoven fabrics[J]. Fibers and Polymers, 2016, 17(10): 1709-1714.
doi: 10.1007/s12221-016-6745-8
[22] BHUIYAN M A R, WANG L, SHAID A, et al. Silica aerogel-integrated nonwoven protective fabrics for chemical and thermal protection and thermophysiological wear comfort[J]. Journal of Materials Science, 2020, 55(6): 2405-2418.
doi: 10.1007/s10853-019-04203-2
[23] 贺香梅. SiO2气凝胶的常压干燥制备及在隔热纺织品中的应用[D]. 上海: 东华大学, 2014: 31-35.
HE Xiangmei. The synthesis of silica aerogel via atmospheric pressure drying and its application in thermal insulation textiles[D]. Shanghai: Donghua University, 2014: 31-35.
[24] 张明明, 刘晓林, 马天, 等. SiO2气凝胶制备及其在织物保温涂层中的应用[J]. 稀有金属材料与工程, 2015, 44(S1): 421-425.
ZHANG Mingming, LIU Xiaolin, MA Tian, et al. Preparation of silica aerogels and application in thermal insulation coating of fabric[J]. Rare Metal Materials and Engineering, 2015, 44(S1): 421-425.
[25] JABBARI M, ÅKESSON D, SKRIFVARS M, et al. Novel lightweight and highly thermally insulative silica aerogel-doped poly (vinyl chloride)-coated fabric composite[J]. Journal of Reinforced Plastics and Composites, 2015, 34(19): 1581-1592.
doi: 10.1177/0731684415578306
[26] BHUIYAN M R, WANG L, SHAID A, et al. Polyurethane-aerogel incorporated coating on cotton fabric for chemical protection[J]. Progress in Organic Coatings, 2019, 131:100-110.
doi: 10.1016/j.porgcoat.2019.01.041
[27] 何飞, 赫晓东, 李垚. 气凝胶热特性的研究现状[J]. 材料导报, 2005, 12: 20-22.
HE Fei, HE Xiaodong, LI Yao. Study on thermal properties of aerogels[J]. Materials Reports, 2005, 12: 20-22.
[28] 何飞. SiO2和 SiO2-Al2O3复合干凝胶超级隔热材料的制备与表征[D]. 哈尔滨: 哈尔滨工业大学, 2006:128-129.
HE Fei. Synthesis and characterization of SiO2 and SiO2-Al2O3 xerogels super insulation materials[D]. Harbin: Harbin Institute of Technology, 2006:128-129.
[29] 张兴娟, 吴洪飞, 孔祥明. 新型组合式消防服热防护性能分析[J]. 中国个体防护装备, 2013 (6): 20-24.
ZHANG Xingjuan, WU Hongfei, KONG Xiangming. Analysis of thermal protective performance of aerogel-based new combined firefighters' clothing[J]. China Personal Protective Equipment, 2013(6): 20-24.
[30] UDAYRAJ, TALUKDAR P, DAS A, et al. Heat and mass transfer through thermal protective clothing:a review[J]. International Journal of Thermal Sciences, 2016, 106: 32-56.
doi: 10.1016/j.ijthermalsci.2016.03.006
[31] JIN L, HONG K, YOON K. Effect of aerogel on thermal protective performance of firefighter clothing[J]. Journal of Fiber Bioengineering and Informatics, 2013, 6(3): 315-324.
doi: 10.3993/jfbi09201309
[32] QI Z, HUANG D, HE S, et al. Thermal protective performance of aerogel embedded firefighter's protective clothing[J]. Journal of Engineered Fibers and Fabrics, 2013, 8(2): 134-139.
[33] 高珊, 卢业虎, 张德锁, 等. 石墨烯气凝胶复合防火织物的热防护性能[J]. 纺织学报, 2020, 41(4): 117-122.
GAO Shan, LU Yehu, ZHANG Desuo, et al. Thermal protective performance of composite flame retardant fabrics treated by graphene aerogel[J]. Journal of Textile Research, 2020, 41(4): 117-122.
[34] SHAID A, FERGUSSON M, WANG L. Thermophysiological comfort analysis of aerogel nanoparticle incorporated fabric for fire fighter's protective clothing[J]. Chemical and Materials Engineering, 2014, 2(2): 37-43.
doi: 10.13189/cme.2014.020203
[35] SHAID A, WANG L, PADHYE R, et al. Aerogel nonwoven as reinforcement and batting material for firefighter's protective clothing: a comparative study[J]. Journal of Sol-Gel Science and Technology, 2018, 87(1): 95-104.
doi: 10.1007/s10971-018-4689-8
[36] SHAID A, WANG L, PADHYE R. The thermal protection and comfort properties of aerogel and PCM-coated fabric for firefighter garment[J]. Journal of Industrial Textiles, 2016, 45(4): 611-625.
doi: 10.1177/1528083715610296
[37] ZHANG H, SONG G, SU H, et al. An exploration of enhancing thermal protective clothing performance by incorporating aerogel and phase change materials[J]. Fire and Materials, 2017, 41(8): 953-963.
doi: 10.1002/fam.2435
[38] 张慧. 基于气凝胶的高性能热防护纺织新材料的研究[D]. 天津: 天津工业大学, 2017: 27-46.
ZHANG Hui. Research on high performance thermal protection textile materials based on aerogel[D]. Tianjin:Tiangong University, 2017: 27-46.
[39] 王昕, 黄胶, 郑振荣. TiO2/SiO2气凝胶隔热涂层帐篷材料的制备[J]. 印染, 2020, 46(1): 52-55,59.
WANG Xin, HANG Jiao, ZHENG Zhenrong. Preparation of TiO2/SiO2 aerogel thermal insulation coating tent material[J]. China Dyeing & Finishing, 2020, 46(1): 52-55,59.
[40] 崔海云, 何婷婷. 气凝胶在服饰鞋被纺织品中的应用[J]. 新材料产业, 2021(2): 54-56.
CUI Haiyun, HE Tingting. Application of aerogel in clothing and footwear textiles[J]. Advanced Materials Industry, 2021(2): 54-56.
[41] TREVINO L A, ORNDOFF E S, TANG H H, et al. Aerogel-based insulation for advanced space suit[J]. SAE Technical Paper, 2002.DOI:10.4271/2002-01-2316.
doi: 10.4271/2002-01-2316
[42] TANG H H, ORNDOFF E S, TREVINO L A. Thermal performance of space suit elements with aerogel insulation for moon and mars exploration[J]. SAE Technical Paper, 2006. DOI:10.4271/2006-01-2235.
doi: 10.4271/2006-01-2235
[43] 刘茜, 吴磊. 固体空气: 气凝胶在服装和建筑中的应用[J]. 国外纺织技术, 2004, 5: 13-16.
LIU Qian, WU Lei. Application of solid air: aerogel in clothing and architecture[J]. Textile Technology Overseas, 2004, 5: 13-16.
[44] 高珊, 卢业虎, 王来力, 等. 气凝胶在防护服中的应用进展[J]. 丝绸, 2019, 56(4): 44-49.
GAO Shan, LU Yehu, WANG Laili, et al. Application progress of aerogel in protective clothing[J]. Journal of Silk, 2019, 56(4): 44-49.
[45] 赵石楠. 气凝胶型隔热层消防服概念及应用的可行性研究[J]. 消防技术与产品信息, 2018, 31(1): 67-69.
ZHAO Shinan. Conception and application feasibility of aerogel thermal insulating fire protective clothing[J]. Fire Technique and Products Information, 2018, 31(1): 67-69.
[46] 严杰, 赵林, 张雪. 一种气凝胶保暖服装: 201821691075.9[P]. 2019-08-30.
YAN Jie, ZHAO Lin, ZHANG Xue. An aerogel thermal clothing: 201821691075.9[P]. 2019-08-30.
[47] 苏文桢, 卢业虎. 气凝胶防寒服的研制与性能评价[J]. 丝绸, 2020, 57(9): 58-62.
SU Wenzhen, LU Yehu. Development and performance evaluation of aerogel-based cold protective clothing[J]. Journal of Silk, 2020, 57(9): 58-62.
[48] 曹明贵, 彭兵. 一种二氧化硅气凝胶衣服: 201821294696.3[P]. 2019-03-15.
CAO Minggui, PENG Bing. A silica aerogel garment: 201821294696.3[P]. 2019-03-15.
[49] SHI S, HAN Y, HU J. Robust waterproof and self-adaptive breathable membrane with heat retention property for intelligent protective cloth[J]. Progress in Organic Coatings, 2019. DOI:10.1016/j.porgcoat.2019.105303.
doi: 10.1016/j.porgcoat.2019.105303
[50] 韩健健, 胡勇杰, 刘谷. 服装用气凝胶材料的贴合结构设计[J]. 染整技术, 2021, 43(6): 34-37.
HAN Jianjian, HU Yongjie, LIU Gu. Fitting structure design of aerogel material for clothing[J]. Textile Dyeing and Finishing Journal, 2021, 43(6): 34-37.
[51] 张旋宇. 基于多孔材料制备超疏水防紫外多功能纺织品[D]. 上海: 东华大学, 2017:48-68.
ZHANG Xuanyu. Preparation of super-hydrophobic and UV-blocking multifunctional textiles based on porous materials[D]. Shanghai: Donghua University, 2017:48-68.
[52] 盛宇, 徐丽慧, 孟云, 等. 用SiO2/TiO2复合气凝胶制备超疏水光催化防紫外线织物[J]. 纺织学报, 2019, 40(7): 90-96.
SHENG Yu, XU Lihui, MENG Yun, et al. Preparation of superhydrophobic,photocatalytic and UV-blocking textiles based on SiO2/TiO2 composite aerogels[J]. Journal of Textile Research, 2019, 40(7): 90-96.
[53] LANG X H, ZHU T Y, ZOU L, et al. Fabrication and characterization of polypropylene aerogel material and aerogel coated hybrid materials for oil-water separation applications[J]. Progress in Organic Coatings, 2019. DOI:10.1016/j.porgcoat.2019.105370.
doi: 10.1016/j.porgcoat.2019.105370
[54] 靳懿, 徐丽慧, 曲珍, 等. 氟硅烷改性 CuS/SiO2 复合气凝胶的超双疏防紫外线纺织品[J]. 印染, 2020, 46(2): 1-6.
JIN Yi, XU Lihui, QU Zhen, et al. Preparation of superamphiphobic and anti-UV fabrics based on the CuS/SiO2 aerogel modified by fluorosilane[J]. China Dying & Finishing, 2020, 46(2): 1-6.
[55] 丁娇娥. 基于 SiO2气凝胶的自清洁材料的制备和表征[D]. 上海: 东华大学, 2015:17-29.
DING Jiaoe. Preparation and characterization of self-cleaning materials based on SiO2 aerogel[D]. Shanghai: Donghua University: 2015, 17-29.
[56] YANG T, XIONG X, VENKATARAMAN M, et al. Investi-gation on sound absorption properties of aerogel/polymer nonwovens[J]. Journal of The Textile Institute, 2019, 110(2): 196-201.
doi: 10.1080/00405000.2018.1472540
[57] RAMAMOORTHY M, PISAL A A, RENGASAMY R S, et al. In-situ synthesis of silica aerogel in polyethylene terephthalate fibre nonwovens and their composite properties on acoustical absorption behavior[J]. Journal of Porous Materials, 2018, 25(1): 179-187.
doi: 10.1007/s10934-017-0431-0
[58] TALEBI Z, SOLTANI P, HABIBI N, et al. Silica aerogel/polyester blankets for efficient sound absorption in buildings[J]. Construction and Building Materials, 2019, 220:76-89.
doi: 10.1016/j.conbuildmat.2019.06.031
[59] 向文艺. 一种纳米气凝胶隔音隔热毡: 201921543045.8[P]. 2019-09-17.
XIANG Wenyi. A sound and heat insulation felt based on nano aerogel: 201921543045.8[P]. 2019-09-17.
[1] 张楚丹, 王锐, 王文庆, 刘燕燕, 陈睿. 阳离子改性阻燃涤纶织物的制备及其性能[J]. 纺织学报, 2022, 43(12): 109-117.
[2] 楚艳艳, 李施辰, 陈超, 刘莹莹, 黄伟韩, 张越, 陈晓钢. 柔性抗冲击纺织材料及其结构的研究进展[J]. 纺织学报, 2022, 43(12): 203-212.
[3] 乔路阳, 吕巧莉, 胡乾恒, 王成龙, 郑今欢. 改性羰基铁粉制备及其在蓝光固化磁控超疏水薄膜中的应用[J]. 纺织学报, 2022, 43(12): 88-95.
[4] 方寅春, 陈吕鑫, 李俊伟. 阻燃超疏水涤/棉混纺织物的制备及其性能[J]. 纺织学报, 2022, 43(11): 113-118.
[5] 高强, 范浩军, 颜俊, 陈玉国, 郑萍. 三维超疏水超细纤维绒面革的仿生构建[J]. 纺织学报, 2022, 43(10): 126-132.
[6] 陈珺娴, 李伟萍, 付琪轩, 冯新星, 张华. 芳纶/阻燃粘胶/阻燃锦纶混纺织物制备及其性能[J]. 纺织学报, 2022, 43(09): 107-114.
[7] 宫学斌, 刘元军, 赵晓明. 热防护用气凝胶材料的研究进展[J]. 纺织学报, 2022, 43(06): 187-196.
[8] 南清清, 曾庆红, 袁竟轩, 王晓沁, 郑兆柱, 李刚. 抗菌功能纺织品的研究进展[J]. 纺织学报, 2022, 43(06): 197-205.
[9] 魏娜娜, 刘碟, 马政, 焦晨璐. 纤维素/壳聚糖磁性气凝胶的冻融法制备及其对染料吸附性能[J]. 纺织学报, 2022, 43(02): 53-60.
[10] 林美霞, 王嘉雯, 肖爽, 王晓云, 刘皓, 何崟. 高灵敏超压缩生物基炭化材料柔性压力传感器的制备及其性能[J]. 纺织学报, 2022, 43(02): 61-68.
[11] 谢爱玲, 乐昱含, 艾馨, 王亚辉, 王义容, 陈新彭, 陈国强, 邢铁玲. 茶多酚改性超疏水涤纶织物制备及其在油水分离中的应用[J]. 纺织学报, 2022, 43(02): 162-170.
[12] 李珍珍, 支超, 余灵婕, 朱海, 杜明娟. 废棉再生气凝胶/经编间隔织物复合材料的制备及其性能[J]. 纺织学报, 2022, 43(01): 167-171.
[13] 骆晓蕾, 刘琳, 姚菊明. 纯生物质纤维素气凝胶的制备及其阻燃性能[J]. 纺织学报, 2022, 43(01): 1-8.
[14] 方寅春, 孙卫昊. 阻燃纤维素气凝胶研究进展[J]. 纺织学报, 2022, 43(01): 43-48.
[15] 许仕林, 杨世玉, 张亚茹, 胡柳, 胡毅. 热塑性聚氨酯/特氟龙无定形氟聚物超疏水纳米纤维膜制备及其性能[J]. 纺织学报, 2021, 42(12): 42-42.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发