纺织学报 ›› 2022, Vol. 43 ›› Issue (01): 141-146.doi: 10.13475/j.fzxb.20210909406

• 染整与化学品 • 上一篇    下一篇

双亲两嵌段接枝淀粉浆料的制备及其上浆性能

李伟(), 张正桥, 徐珍珍, 张朝辉   

  1. 安徽工程大学 纺织服装学院, 安徽 芜湖 241000
  • 收稿日期:2021-09-26 修回日期:2021-10-12 出版日期:2022-01-15 发布日期:2022-01-28
  • 作者简介:李伟(1986—),男,副教授,博士。主要研究方向为纺织浆料的开发与研究。E-mail: fangzhiliweiwu@sina.com。
  • 基金资助:
    安徽省自然科学基金面上项目(1908085ME124);安徽省重点研发计划项目(201904a06020001);安徽省纺织工程技术研究中心、安徽省高等学校纺织面料重点实验室开放基金项目(2021AETKL17)

Preparation and sizing properties of amphiphilic diblock grafted starch sizing agent

LI Wei(), ZHANG Zhengqiao, XU Zhenzhen, ZHANG Chaohui   

  1. College of Textiles and Garments, Anhui Polytechnic University, Wuhu, Anhui 241000, China
  • Received:2021-09-26 Revised:2021-10-12 Published:2022-01-15 Online:2022-01-28

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摘要：

为提高淀粉浆料的使用性能,为纺织经纱上浆提供新型接枝淀粉浆料品种,以丙烯酸(AA)和丙烯酸丁酯(BA)为接枝单体,2-溴异丁酯化淀粉(BBES)为大分子引发剂,利用电子转移活化再生催化剂原子转移自由基聚合技术成功制备了双亲两嵌段接枝淀粉[BBES-g-(PAA-b-PBA)]。以酸解淀粉、BBES为对比样,探讨了双亲两嵌段接枝支链的引入对淀粉浆液性能、浆膜力学性能的影响。结果表明:接枝支链的引入能够进一步增加淀粉浆液的黏度热稳定性、黏附性及其浆膜的断裂伸长率;随着AA接枝率的降低及同时BA接枝率的增加,淀粉浆液的黏度热稳定性变化不大,对涤纶的黏附力和浆膜的断裂伸长率逐渐增加,浆膜的断裂强度逐渐降低。

关键词: 淀粉浆料, 接枝变性, 接枝率, 上浆性能, 双亲两嵌段接枝淀粉

Abstract:

In order to provide a new grafted starch for enhancing usability of starch sizing agent in warp sizing, amphiphilic diblock grafted starch [BBES-g-(PAA-b-PBA)] was prepared by activators regenerated by electron transfer for atom transfer radical polymerization with acrylic acid (AA) and butyl acrylate (BA) as monomers and 2-bromoisobutyl esterified starch (BBES) as macromolecular initiator. Taking acid-hydrolyzed starch and BBES as contrast samples, effects of the amphiphilic diblock grafted branches on the properties of starch paste and tensile property of starch film were discussed. The results showed that the paste properties and film elongation are demonstrated in the order of BBES-g-(PAA-b-PBA)>BBES>acid-hydrolyzed starch, indicating that introduction of the grafted branches can further improve the viscosity stability of starch paste, adhesion to polyester fibers and breaking elongation of starch film. With the decrease in the grafting ratio of AA while the increase in the grafting ratio of BA, viscosity stability exhibited a slight difference, the adhesion and film elongation demonstrated a gradual increase, whereas tensile strength of the film decreased monotonically.

Key words: starch sizing agent, graft polymerization, grafting ratio, sizing property, amphiphilic diblock grafted starch

中图分类号: 

  • TS103.846

图1

两步接枝反应合成BBES-g-(PAA-b-PBA)的反应方程"

图2

AHS、BBES和BBES-g-(PAA-b-PBA)的红外光谱图"

图3

淀粉颗粒样品的扫描电镜照片(×2 000)"

表1

BBES-g-(PAA-b-PBA)样品的接枝率"

结构单元 接枝率/%
III IV V
AA 8.53 7.73 4.98
BA 4.54 7.62 9.82

图4

双亲两嵌段接枝变性对淀粉浆液黏度热稳定性的影响"

图5

双亲两嵌段接枝变性对淀粉与涤纶间黏附性的影响"

图6

双亲两嵌段接枝变性对淀粉浆液表面张力的影响"

图7

双亲两嵌段接枝变性对淀粉浆膜力学性能的影响"

[1] DAI L, WANG Y, ZOU X J, et al. Ultrasensitive physical, bio, and chemical sensors derived from 1-, 2-, and 3-D nanocellulosic materials[J]. Small, 2020, 16(13): 1906567.
doi: 10.1002/smll.v16.13
[2] RAMARAJ B. Crosslinked poly(vinyl alcohol) and starch composite films: II: physicomechanical, thermal properties and swelling studies[J]. Journal of Applied Polymer Science, 2007, 103(2): 909-916.
doi: 10.1002/(ISSN)1097-4628
[3] WANG L L, ZHANG X, XU J, et al. How starch-g-poly(acrylamide) molecular structure effect sizing properties[J]. International Journal of Biological Macromolecules, 2020, 144:403-409.
doi: 10.1016/j.ijbiomac.2019.12.143
[4] WANG Y T, MENG Y, JI Z, et al. Bioinspired colored degradable starch-based films with excellent tensile strength[J]. Industrial Crops and Products, 2021, 167:113525.
doi: 10.1016/j.indcrop.2021.113525
[5] BHATTACHARYYA R, KUMAR R, BANDYOPADHYAY K K, et al. Preparation of novel biodegradable starch/poly(vinyl alcohol)/bentonite grafted polymeric films for fertilizer encapsulation[J]. Carbohydrate Polymers, 2021, 259:117679.
doi: 10.1016/j.carbpol.2021.117679
[6] ZHU Z F, SONG Y Z, XU Z Z, et al. Introduction of octenylsuccinate and carboxymethyl onto starch for strong bonding to fiber and easy removal from sized yarn[J]. Carbohydrate Polymers, 2021, 269:118249.
doi: 10.1016/j.carbpol.2021.118249
[7] 李伟, 祝志峰, 徐珍珍, 等. 淀粉浆料用极性增塑剂及其增塑作用的研究进展[J]. 纺织学报, 2017, 38(4): 176-181.
LI Wei, ZHU Zhifeng, XU Zhenzhen, et al. Research progress and plasticization effect of polar plasticizers for starch sizing agents[J]. Journal of Textile Research, 2017, 38(4): 176-181.
doi: 10.1177/004051756803800209
[8] ZHU Z F, LEI Y. Effect of chain length of the alkyl in quaternary ammonium substituents on the adhesion-to-fiber, aerobic biodegradation, and desizability of quaternized cornstarch[J]. Journal of Adhesion Science and Technology, 2015, 29(2): 116-132.
doi: 10.1080/01694243.2014.976515
[9] KOVACEVIC S, SCHWARZ I, DORDEVIC S, et al. Synthetized potato starch:a new eco sizing agent for cotton yarns[J]. Polymers, 2019, 11(5): 908.
doi: 10.3390/polym11050908
[10] LIU F D, ZHU Z F, XU Z Z, et al. Desizability of the grafted starches used as warp sizing agents[J]. Starch-Stärke, 2017, 70:1700149.
doi: 10.1002/star.v70.3-4
[11] 李伟, 吴杰, 吴兰娟, 等. ARGET-ATRP技术的应用研究进展[J]. 高分子通报, 2020(7): 18-25.
LI Wei, WU Jie, WU Lanjuan, et al. Research progress on application of ARGET-ATRP technology[J]. Polymer Bulletin, 2020 (7): 18-25.
[12] ZHU Z F, CHEN P H. Carbamoyl ethylation of starch for enhancing the adhesion capacity to fibers[J]. Journal of Applied Polymer Science, 2007, 106(4): 2763-2768.
doi: 10.1002/(ISSN)1097-4628
[13] LI W, WU J, ZHANG Z Q, et al. Investigation on the synjournal process of bromoisobutyryl esterified starch and its sizing properties: viscosity stability, adhesion and film properties[J]. Polymers, 2019, 11(12): 1936.
doi: 10.3390/polym11121936
[14] VARAVINIT S, CHAOKASEM N, SHOBSNGOB S. Studies of flavor encapsulation by agents produced from modified sago and tapioca starches[J]. Starch-Stärke, 2001, 53(6): 281-287.
doi: 10.1002/(ISSN)1521-379X
[15] 李伟, 张正桥, 吴兰娟, 等. 亚甲基丁二酸交联变性对淀粉浆料性能的影响[J]. 纺织学报, 2021, 42(3): 113-118.
LI Wei, ZHANG Zhengqiao, WU Lanjuan, et al. Influence of methylene succinic acid cross-linking on properties of starch sizing agents[J]. Journal of Textile Research, 2021, 42(3): 113-118.
[16] ZHU Z F, XU D S, GUO J S, et al. Comparative study on sizing properties of amphoteric starch and phosphorylated starch for warp sizing[J]. Fibers and Polymers, 2012, 13(2): 177-184.
doi: 10.1007/s12221-012-0177-x
[17] ALTUNA L, HERRERA M L, FORESTI M L. Synjournal and characterization of octenyl succinic anhydride modified starches for food applications: a review of recent literature[J]. Food Hydrocolloids, 2018, 80:97-110.
doi: 10.1016/j.foodhyd.2018.01.032
[18] SHEN S Q, ZHU Z F, LIU F D. Introduction of poly[(2-acryloyloxyethyl trimethyl ammoniumchloride)-co-(acrylic acid)]branches onto starch for cotton warp sizing[J]. Carbohydrate Polymers, 2016, 138:280-289.
doi: 10.1016/j.carbpol.2015.11.058
[19] LI W, ZHANG Z Q, WU L J, et al. Improving the adhesion-to-fibers and film properties of corn starch by starch sulfo-itaconation for a better application in warp sizing[J]. Polymer Testing, 2021, 98:107194.
doi: 10.1016/j.polymertesting.2021.107194
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