纺织学报 ›› 2022, Vol. 43 ›› Issue (01): 49-57.doi: 10.13475/j.fzxb.20210910009
朱斐超1, 张宇静1, 张强2, 叶翔宇3, 张恒4, 汪伦合5, 黄瑞杰6, 刘国金1, 于斌1()
ZHU Feichao1, ZHANG Yujing1, ZHANG Qiang2, YE Xiangyu3, ZHANG Heng4, WANG Lunhe5, HUANG Ruijie6, LIU Guojin1, YU Bin1()
摘要:
聚乳酸(PLA)基熔喷非织造材料存在柔韧性不足、驻极耐久性差、功能性单一等问题,限制了其作为高性能吸附与过滤材料的应用和发展,本文全面总结了PLA基熔喷材料在原料设计、加工成形及应用方面的研究进展。介绍了PLA基熔喷材料的加工成形方法及其改性,主要包括母粒改性(共聚/嵌段、增强增韧、功能性改性等)和后整理改性(静电驻极整理和功能整理);阐述了PLA基熔喷材料在空气过滤、医疗防护、卫生保健、组织工程、清洁擦拭、吸油、保暖领域的典型应用。最后,对PLA基熔喷材料的纤维微纳化、多组分化、复合化、耐静电驻极化、功能和智能化发展方向进行了展望,为PLA基熔喷材料的高质化和高值化发展提供理论和技术参考。
中图分类号:
[1] |
CAMPOS R K, JIN J, RAFAEL G H, et al. Decontamination of SARS-CoV-2 and other RNA viruses from N95 level meltblown poly propylene fabric using heat under different humidities[J]. ACS Nano, 2020.DOI: 10.1101/2020.08.10.20171728.
doi: 10.1101/2020.08.10.20171728 |
[2] | 张星, 张海峰, 靳向煜, 等. 防护口罩用非织造滤料的制备技术与研究现状[J]. 纺织学报, 2020, 41(3): 168-174. |
ZHANG Xing, ZHANG Haifeng, JIN Xiangyu, et al. Preparation technology and research status of nonwoven filtration materials for individual protective masks[J]. Journal of Textile Research, 2020, 41(3): 168-174. | |
[3] | HIREMATH N, BHAT G. Melt blown polymeric nanofibers for medical applications: an overview[J]. Nano Science and Technology, 2015, 2(1): 1-9. |
[4] |
MOHAMMAD A H, BONG Y Y, ARNOLD W, et al. Fabrication of nanofiber meltblown membranes and their filtration properties[J]. Journal of Membrane Science, 2013, 427:336-344.
doi: 10.1016/j.memsci.2012.09.050 |
[5] | 谷英姝, 汪滨, 张秀芹, 等. 聚乳酸熔喷非织造材料用于空气过滤领域的研究进展[J]. 化工新型材料, 2021, 49(1): 214-217. |
GU Yingshu, WANG Bin, ZHANG Xiuqin, et al. Research progress on PLA melt-blown nonwoven applied in air filtration[J]. New Chemical Materials, 2021, 49(1): 214-217. | |
[6] | DIETER H M, ANDREAS K. Meltblown fabrics from biodegradable polymers[J]. Inrernational Nonwovens Journal, 2001, 10(1): 11-13. |
[7] | 刘亚. 熔喷/静电纺复合法聚乳酸非织造布的制备及过滤性能研究[D]. 天津: 天津大学, 2009: 63. |
LIU Ya. Study on preparation and filrearion property of PLA nonwovens via meltblown/electro-spinning[D]. Tianjin: Tiangong University, 2009: 63. | |
[8] |
LIU Y, CHENG B W, NA W, et al. Development and filtration performance of polylactic acid meltblowns[J]. Textile Research Journal, 2010, 79(9): 771-779.
doi: 10.1177/0040517509102797 |
[9] | 李玉梅. 聚乳酸熔喷非织造布的纺制及其结构与性能的研究[D]. 天津: 天津工业大学, 2008: 32. |
LI Yumei. Study on spinning, structure and properties of polylactic acid melt blown nonwovens[D]. Tianjin: Tiangong University, 2008: 32. | |
[10] | YU B, ZHANG X, KONG J, et al. Influence of die-to-collector distance on structure and property of the PLA meltblowing web[J]. Rare Metal Materials and Engineering, 2016, 45(S1): 345-349. |
[11] | 张琦. 驻极体聚乳酸熔喷非织造材料的制备及性能研究[D]. 杭州: 浙江理工大学, 2012: 49. |
ZHANG Qi. The preparation and study on properties of electret polylactic acid meltblown nonwovens [D]. Hangzhou: Zhejiang Sci-Tech University, 2012: 49. | |
[12] |
EWA D, ANNA S, MARCIN K, et al. Effects of process parameters on structure and properties of melt-blown poly (lactic acid) nonwovens for skin regeneration[J]. Journal of Functional Biomaterials, 2021, 12(16): 1-17.
doi: 10.3390/jfb12010001 |
[13] | HAMMONDS R L, GAZZOLA W H, BENSON R S. Physical and thermal characterization of polylactic acid meltblown nonwovens[J]. Journal of Applied Polymer Science, 2014, 131(15): 117-125. |
[14] | 渠叶红, 柯勤飞. 熔喷聚乳酸非织造材料的研究进展[J]. 产业用纺织品, 2003(12): 1-5. |
QU Yehong, KE Qinfei. The investigation progress on melt-blown polylactic acid nonwovens[J]. Technical Textiles, 2003(12): 1-5. | |
[15] | 渠叶红, 柯勤飞, 靳向煜, 等. 熔喷聚乳酸非织造材料工艺与过滤性能研究[J]. 产业用纺织品, 2005(5): 19-22. |
QU Yehong, KE Qinfei, JIN Xiangyu, et al. Study on the meltblown PLA nonwoven process and filtration property[J]. Technical Textiles, 2005(5): 19-22. | |
[16] | 曹勇民, 于斌, 韩建, 等. PDLLA-PCL-PDLLA的添加对PLA/PCL共混材料力学性能的影响[J]. 浙江理工大学学报(自然科学版), 2016, 35/36(4): 538-542. |
CAO Yongmin, YU Bin, HAN Jian, et al. Effect of PDLLA-PCL-PDLLA on mechanical property of PLA/PCL blending matrtial [J]. Journal of Zhejiang Sci-Tech University (Natural Sciences Edition), 2016, 35/36(4): 538-542. | |
[17] |
ZHU F, SU J, WANG M, et al. Study on dual-monomer melt-grafted poly (lactic acid) compatibilized poly (lactic acid)/polyamide 11 blends and toughened melt-blown nonwovens[J]. Journal of Industrial Textiles, 2018, 49(6): 748-772.
doi: 10.1177/1528083718795913 |
[18] |
ZHU F, YU B, SU J, et al. Study on PLA/PA11 bio-based toughening melt-blown nonwovens[J]. Autex Research Journal, 2020, 20(1): 24-31.
doi: 10.2478/aut-2019-0002 |
[19] | ZHU F, SU J, ZHAO Y, et al. Influence of halloysite nanotubes on poly (lactic acid) melt-blown nonwovens compatibilized by dual-monomer melt-grafted poly (lactic acid)[J]. Textile Research Journal, 2019: 4173-4185. |
[20] |
YU B, WANG M, SUN H, et al. Preparation and properties of poly (lactic acid)/magnetic Fe3O4 composites and nonwovens[J]. RSC Advances, 2017, 7(66): 41929-41935.
doi: 10.1039/C7RA06427F |
[21] | 彭鹏. PLA增韧增强改性及其熔喷超细复合纤维材料的制备[D]. 南通: 南通大学, 2015: 60-61. |
PENG Peng. Study on toughening and reinforcing modification of PLA and the preparation of superfine composite fiber by melt blowing[J]. Nantong: Nantong University, 2015: 60-61. | |
[22] |
CUI L, ZHU C L, ZHU P, et al. Preparation and physical properties of melt-blown nonwovens of biodegradable PLA/acetyl tributyl citrate/FePol copolyester blends[J]. Journal of Applied Polymer Science, 2012, 125(S2): 158-167.
doi: 10.1002/app.v125.1 |
[23] | 张琦, 于斌, 韩建, 等. 电气石改性聚乳酸切片的制备及分析[J]. 浙江理工大学学报(自然科学版), 2012, 29(4): 480-483. |
ZHANG Qi, YU Bin, HAN Jian, et al. Preparation and analysis of polylactic acid resin containing tourmaline[J]. Journal of Zhejiang Sci-Tech Univer-sity(Natural Sciences Edition), 2012, 29(4): 480-483. | |
[24] |
YU B, HAN J, SUN H, et al. The Preparation and property of poly (lactic acid)/tourmaline blends and melt-blown nonwoven[J]. Polymer Composites, 2015, 36(2): 264-271.
doi: 10.1002/pc.v36.2 |
[25] | 蔡诚, 唐国翌, 宋国林, 等. 纳米SiO2驻极体/聚乳酸复合熔喷非织造材料的制备及性能[J]. 复合材料学报, 2017, 34(3): 486-493. |
CAI Cheng, TANG Guoyi, SONG Guolin, et al. Preparation and properties of nano-SiO2 electret/PLA composite meltblown nonwovens[J]. Acta Materiae Compositae Sinica, 2017, 34(3): 486-493. | |
[26] | 黄海超, 宋国林, 唐国翌, 等. 驻极体增塑剂复合改性聚乳酸熔喷非织造材料的制备及性能[J]. 复合材料学报, 2019, 36(3): 563-571. |
HUANG Haichao, SONG Guolin, TANG Guoyi, et al. Preparation and characterization of poly (lactic acid) meltblown nonwovens modified by electrets and co-plasticizers[J]. Acta Materiae Compositae Sinica, 2019, 36(3): 563-571. | |
[27] | MAJCHRZYCKA K, BROCHOCKA A, BRYCKI B. Biocidal agent for modification of poly (lactic acid) high-efficiency filtering nonwovens[J]. Fibres & Textiles in Eastern Europe, 2015, 23(4): 88-95. |
[28] | LATWINSKA M, JADWIGA S, JERZY C, et al. PLA and PP composite nonwoven with antimicrobial activity for filtration applications[J]. International Journal of Polymer Science, 2016(119): 1-9. |
[29] |
YU B, WANG M, SUN H, et al. Preparation and properties of poly (lactic acid)/magnetic Fe3O4 composites and nonwovens[J]. RSC Advances, 2017, 7(66): 41929-41935.
doi: 10.1039/C7RA06427F |
[30] | SUN H, PENG S W, WANG M J, et al. Preparation and characterization of magnetic PLA/Fe3O4-g-PLLA composite melt blown nonwoven fabric for air filtration[J]. Journal of Engineered Fibers and Fabrics, 2020, 15(1): 1-13. |
[31] |
NAKAGAWA T, NAKIRI T, HOSOYA R, et al. Electrical properities of biodegradable polylactic acid film[J]. IEEE Transactions on Industry Applications, 2004, 40(4): 1020-1024.
doi: 10.1109/TIA.2004.830751 |
[32] | TSAI P, YAN Y, BROWN D, et al. Electrostatic charging of biodegradable MB PLA and its use for air filter media [R]. Beijing: American Filtration and Separations Society, 2009. |
[33] | 任煜, 李猛, 尤祥银. 驻极处理对聚乳酸熔喷材料性能的影响[J]. 纺织学报, 2015, 36(9): 13-17. |
REN Yu, LI Meng, YOU Xiangyin. Influence of corona electret treatment on melt-blow PLA nonwovens material[J]. Journal of Textile Research, 2015, 36(9): 13-17. | |
[34] | ZHANG J, CHEN G, BHAT G S, et al. Electret characteristics of melt-blown polylactic acid fabrics for air filtration application[J]. Journal of Applied Polymer, 2020: 48309. |
[35] | 马金亮, 麻文效, 温开琦. 壳聚糖接枝改性PLA非织造布的制备及性能研究[J]. 合成纤维工业, 2020, 43(4): 45-48. |
MA Jinliang, MA Wenxiao, WEN Kaiqi. Preparation and properties of chitosan-graft modified PLA non-woven fabric[J]. China Synthetic Fiber Industry, 2020, 43(4): 45-48. | |
[36] | 任煜, 王晓娜, 徐林, 等. 常压等离子体辅助PLA表面接枝壳聚糖及抗菌性[J]. 上海纺织科技, 2017(8): 40-43. |
REN Yu, WANG Xiaona, XU Lin, et al. Plasma-chitosan combined treatment for surface modification of polylactic acid spunbond nonwovens[J] Shanghai Textile Science & Technology, 2017(8): 40-43. | |
[37] | 孙欣悦, 薛亚玲, 逯向阳, 等. 溶菌酶在等离子体改性PLA纤维上的固定[J]. 山东化工, 2020, 49(7): 6-8. |
SUN Xinyue, XUE Yaling, LU Xiangyang, et al. Fixation of lysozyme on plasma-modified PLA fiber[J]. Shandong Chemical Industry, 2020, 49(7): 6-8. | |
[38] | 史韩萍, 李旭明. 脂肪酶处理对聚乳酸非织造布亲水性的影响[J]. 上海纺织科技, 2016, 44(6): 26-27, 36. |
SHI Hanpin, LI Xuming. Effect of lipase treatment on the hydrophilicity of PLA nonwovens[J]. Shanghai Textile Science & Technology, 2016, 44(6): 26-27,36. | |
[39] |
LI T T, WANG Z, REN H T, et al. Recyclable and degradable nonwoven-based double-network composite hydrogel adsorbent for efficient removal of Pb (II) and Ni (II) from aqueous solution[J]. Science of the Total Environment, 2020, 758(3): 143640.
doi: 10.1016/j.scitotenv.2020.143640 |
[40] | 彭鹏, 张瑜, 张伟, 等. 聚乳酸超细纤维医用抗菌敷料的制备[J]. 上海纺织科技, 2014, 42(12): 18-20. |
PENG Peng, ZHANG Yu, ZHANG Wei, et al. Preparation of polylactic acid superfine fiber anti-becterial medical dressings[J]. Shanghai Textile Science & Technology, 2014, 42(12): 18-20. | |
[41] | 仙桃市非织造布产业协会. 恒天纤维:生物基可降解聚乳酸非织造医用防护材料[EB/OL]. (2020-09-08) https://www.sohu.com/a/417134038_120065055. |
Xiantao Nonwoven Fabric Industry Association. Hengtian fiber: bio-based biodegradable polylactic acid nonwoven medical protective material[EB/OL].(2020-09-08) https://www.sohu.com/a/417134038_120065055. | |
[42] | 张恒, 甄琪, 柳洋, 等. 一种水平分支结构的熔喷非织造复合材料及其制备方法: 201810530117.0[P]. 2020-06-26. |
ZHANG Heng, ZHEN Qi, LIU Yang, et al. Melt-blown non-woven composite material with horizontal branch structure and preparation method thereof: 201810530117.0[P]. 2020-06-26. | |
[43] | 崔景强, 张恒, 甄琪, 等. 一种聚乳酸弹性超细纤维非织造材料及其制备方法和应用:202110606498.6[P]. 2021-08-24. |
CUI Jingqiang, ZHANG Heng, ZHEN Qi, et al. Polylactic acid elastic superfine fiber non-woven material and preparation method and application thereof: 202110606498.6[P]. 2021-08-24. | |
[44] | 聚乳酸O2O平台. 丰原聚乳酸PLA基材面膜,让你的皮肤更光泽[EB/OL]. (2020-11-17). https://www.163.com/dy/article/FRLGJHOL0538PX6U.html. |
Polylactic acid O2O platform. Fengyuan polylactic acid PLA base mask to make your skin more shiny[EB/OL].(2020-11-17). https://www.163.com/dy/article/FRLGJHOL0538PX6U.html. | |
[45] |
GAZZOLA W H, BENSON R S, CARVER W. Meltblown polylactic acid nanowebs as a tissue engineering scaffold[J]. Annals of Plastic Surgery, 2019, 83(6): 716-721.
doi: 10.1097/SAP.0000000000002036 |
[46] | MONIKA R, JOANNA G, JANUSZ F, et al. PLA melt-blown fibrous structures for potential biomedical applications[J]. Engineering of Biomaterials, 2011, 14(104): 5-7. |
[47] | CAI S, POURDEYHIMI B, LOBOA E G. Industrial-scale fabrication of an osteogenic and antibacterial PLA/silver-loaded calcium phosphate composite with significantly reduced cytotoxicity[J]. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 2019, 107B:900-910. |
[48] |
JENKINS T L, MEEHAN S, POURDEYHIMI B, et al. Meltblown polymer fabrics as candidate scaffolds for rotator cuff tendon tissue engineering[J]. Tissue Engineering Part A, 2017, 23(17/18): 958.
doi: 10.1089/ten.tea.2016.0470 |
[49] | 山东希瑞新材料有限公司. 希瑞新材料双拳出击上海国际非织造材料展览会[EB/OL]. (2021-08-03). https://www.unikorn-nonwoven.com/newsinfo/1767769.html. |
Unicorn Nonwovens Co., Ltd.. Unicorn Nonwovens Co., Ltd., double fist attack Shanghai International Nonwovens Exhibition[EB/OL]. (2021-08-03). https://www.unikorn-nonwoven.com/newsinfo/1767769.html. | |
[50] | 郭永诗, 骆旭晖, 张齐婷, 等. 熔喷吸油材料的研究进展及现状[J]. 轻工科技, 2017, 33(8): 114-115. |
GUO Yongshi, LUO Xuhui, ZHANG Qiting, et al. Research progress and status of melt blown oil absorbing materials[J]. Light Industry Science and Technology, 2017, 33(8): 114-115. | |
[51] | 黄婷婷, 仇何, 张瑜, 等. 可降解聚乳酸熔喷吸油材料的研发及性能测试[J]. 上海纺织科技, 2015, 43(12): 24-27. |
HUANG Tingting, QIU He, ZHANG Yu, et al. The research and performance testing on the biodegradable polylactic acid melt-blown oil absorption materials[J]. Shanghai Textile Science & Technology, 2015, 43(12): 24-27. | |
[52] | 仇何, 路绮雯, 张伟, 等. PLA/PAE仿鹅绒高效保暖材料的制备与工艺研究[J]. 南通大学学报(自然科学版), 2016, 15(1): 34-38. |
QIU He, LU Qiwen, ZHANG Wei, et al. Preparation and process of PLA/PAE imitate down feather effective warm materials[J]. Jounal of Nantong Univer-sity (Natural Science Edition), 2016, 15(1): 34-38. | |
[53] | 林玲, 周兆懿, 何海华. 聚乳酸絮片的制备,性能及展望[J]. 合成纤维, 50(2): 25-27. |
LIN Ling, ZHOU Zhaoyi, HE Haihua. Preparation, performance and prospect of polylactic acid flakes[J]. Synthetic Fiber in China, 50(2): 25-27. | |
[54] | MAGDI E, Gajanan B, AFFAF E, et al. Acoustical absorptive properties of meltblown nonwovens for textile machinery[J]. Textile Research Journal, 2020, 91(11/12): 1-13. |
[55] | 俞琳英. 功能性纺织品检测现状及发展趋势[J]. 纺织报告, 2021, 40(6): 40-41. |
YU Linying. Current status and development trend of functional textiles testing[J]. Textile Reports, 2021, 40(6): 40-41. | |
[56] | GROUP F. NTI advances meltblown nanofibre technology[J]. Filtration & Separation, 2005, 42(4): 12. |
[57] | BENSON R S. Physical and thermal characterization of polylactic acid meltblown nonwovens[J]. Journal of Applied Polymer Science, 2014, 131(15): 117-125. |
[58] |
WANG Z, LIU X, MACOSKO C W, et al. Nanofibers from water-extractable melt-blown immiscible polymer blends[J]. Polymer, 2016, 101:269-273.
doi: 10.1016/j.polymer.2016.08.058 |
[59] | RUNGIAH S, RUAMSUK R, VROMAN P, et al. Structural characterization of polypropylene/poly (lactic acid) bicomponent meltblown[J]. Journal of Applied Polymer Science, 2016, 134(14): 44540-44548. |
[60] | 朱斐超. 尼龙11/埃洛石纳米管复合聚乳酸材料及其增强增韧熔喷非织造材料的研究[D]. 杭州: 浙江理工大学, 2019: 107-108. |
ZHU Feichao. Study on polyamide 11/halloysite nanotubes hybrid poly (lactic acid) composites and reinforced and toughened melt-blown nonwovens [D]. Hangzhou: Zhejiang Sci-Tech University, 2019: 107-108. |
[1] | 丁倩, 邓炳耀, 李昊轩. 全纤维光驱动界面蒸发系统在海水淡化工程中的应用研究进展[J]. 纺织学报, 2022, 43(01): 36-42. |
[2] | 许仕林, 杨世玉, 张亚茹, 胡柳, 胡毅. 热塑性聚氨酯/特氟龙无定形氟聚物超疏水纳米纤维膜制备及其性能[J]. 纺织学报, 2021, 42(12): 42-42. |
[3] | 贾琳, 王西贤, 李环宇, 张海霞, 覃小红. 聚丙烯腈/BaTiO3复合纳米纤维过滤膜的制备及其性能[J]. 纺织学报, 2021, 42(12): 34-41. |
[4] | 王曙东, 董青, 王可, 马倩. 还原氧化石墨烯增强聚乳酸纳米纤维膜的制备及其性能[J]. 纺织学报, 2021, 42(12): 28-33. |
[5] | 宋雪旸, 张岩, 徐成功, 王萍, 阮芳涛. 碳纤维/聚丙烯/聚乳酸增强复合材料的力学性能[J]. 纺织学报, 2021, 42(11): 84-88. |
[6] | 赖星, 王纯, 肖长发, 王黎明, 辛斌杰. 芳香族聚酰胺分离膜制备方法及应用进展[J]. 纺织学报, 2021, 42(10): 172-179. |
[7] | 刘强飞, 吴韶华, 杨吉震, 周蓉, 董湘琳, 宋传波, 沈照旭. 芳纶纳米纤维改性聚四氟乙烯/聚苯硫醚针刺毡的制备及其性能[J]. 纺织学报, 2021, 42(10): 47-52. |
[8] | 柳洋, 夏兆鹏, 王亮, 范杰, 曾强, 刘雍. 医用防护服的发展现状及趋势[J]. 纺织学报, 2021, 42(09): 195-202. |
[9] | 权震震, 王亦涵, 祖遥, 覃小红. 多曲面喷头静电纺射流形成机制与成膜特性[J]. 纺织学报, 2021, 42(09): 39-45. |
[10] | 高猛, 王增元, 漏琦伟, 陈钢进. 电晕驻极熔喷聚丙烯驻极体非织造布的电荷捕获特性[J]. 纺织学报, 2021, 42(09): 52-58. |
[11] | 王亚宁, 周楚帆, 乌婧, 王华平. 生物基异己糖醇聚酯的制备及其构效关系研究进展[J]. 纺织学报, 2021, 42(08): 8-16. |
[12] | 王玉栋, 姬长春, 王新厚, 高晓平. 新型熔喷气流模头的设计与数值分析[J]. 纺织学报, 2021, 42(07): 95-100. |
[13] | 文玉峰, 马晓谱, 盛方园, 朱志国. 微胶囊化膨胀型阻燃剂的制备及其在聚乳酸中的应用[J]. 纺织学报, 2021, 42(06): 71-77. |
[14] | 潘宏杰, 杨小兵, 周川, 张守鑫, 常素芹, 罗宏森. 新型冠状病毒防护口罩过滤效率测试标准比对[J]. 纺织学报, 2021, 42(06): 97-105. |
[15] | 苏梦茹, 邹婷, 陈颀超, 李超婧, 王富军, 王璐. 医用倒刺缝合线的研究进展[J]. 纺织学报, 2021, 42(05): 178-184. |
|