涤/棉交织物一浴法轧染工艺

doi:10.13475/j.fzxb.20211109108

纺织学报 ›› 2022, Vol. 43 ›› Issue (05): 18-25.doi: 10.13475/j.fzxb.20211109108

• 特约专栏:第十一届中国纺织学术年会专家观点 • 上一篇下一篇

涤/棉交织物一浴法轧染工艺

刘宇¹^,²^,³^,⁴, 谢汝义¹^,²^,³^,⁴, 宋亚伟¹^,²^,³^,⁴, 齐元章⁵, 王辉⁵, 房宽峻¹^,²^,³^,⁴()

1.青岛大学纺织服装学院, 山东青岛 266071
2.生态纺织省部共建协同创新中心, 山东青岛 266071
3.生物多糖纤维成形与生态纺织省部共建国家重点实验室, 山东青岛 266071
4.山东省生态纺织协同创新中心, 山东青岛 266071
5.鲁丰织染有限公司, 山东淄博 255100

收稿日期:2021-11-22 修回日期:2022-02-23 出版日期:2022-05-15 发布日期:2022-05-30
通讯作者: 房宽峻
作者简介:刘宇(1998—),男,硕士生。主要研究方向为涤/棉交织物清洁染整。
基金资助:
国家重点研发计划项目(2017YFB0309800);山东省重大科技创新工程项目(2019TSLH0108);生物多糖纤维成形与生态纺织省部共建国家重点实验室资助项目(ZDKT202008)

One-bath pad dyeing technology for polyester/cotton fabric

LIU Yu¹^,²^,³^,⁴, XIE Ruyi¹^,²^,³^,⁴, SONG Yawei¹^,²^,³^,⁴, QI Yuanzhang⁵, WANG Hui⁵, FANG Kuanjun¹^,²^,³^,⁴()

1. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
2. Collaborative Innovation Center for Eco-Textiles of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
3. State Key Laboratory for Biofibers and Eco-Textiles, Qingdao, Shandong 266071, China
4. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, Shandong 266071, China
5. Lufeng Weaving and Dyeing Co., Ltd., Zibo, Shandong 255100, China

Received:2021-11-22 Revised:2022-02-23 Published:2022-05-15 Online:2022-05-30
Contact: FANG Kuanjun

摘要/Abstract

摘要：

针对涤/棉交织物染色工艺流程长,耗水耗能大,碳排放量和废水排放量高等问题,研究了涤/棉交织物分散/活性染料一浴两步法轧染工艺。通过分析分散/活性混合染液在不同pH值条件下的稳定性,探讨了焙烘温度、焙烘时间、染浴pH值、固色碱种类与质量浓度、汽蒸时间等对分散蓝79以及K型、KN型、M型活性染料染色效果的影响,并对一浴两步法轧染工艺和两浴两步法工艺产生的能耗进行计算和比较。结果表明:一浴两步法染色织物可以获得与传统染色工艺相同的颜色深度,耐摩擦色牢度以及耐皂洗色牢度可以达到4~5级;以分散蓝79和活性蓝19为例,相比于传统两浴两步法轧染,每染色1万m涤/棉交织物,一浴两步法轧染工艺可减少45.5%的水耗、20.9%的电能消耗、41.7%的热能消耗、40.6%的CO₂排放。

关键词: 涤/棉交织物, 一浴两步法, 轧染, 分散染料, 活性染料, 低碳排放, 表观色深

Abstract:

To solve the problems of process complexity, high water and energy consumption, high carbon and waste water emissions in dyeing process of polyester/cotton fabric, a disperse/reactive dye one-bath two-step pad dyeing method of polyester/cotton was investigated. The stability of disperse/reactive mixed dye solution in different pH conditions was analyzed. The effects of baking temperature, baking time, pH, type and concentration of alkali, steaming time on fabric dyeing were discussed using Disperse Blue 79 and K, KN and M Reactive Dyes. The energy consumption of the one-bath pad dyeing process and traditional process were evaluated and compared. The results show that fabrics dyed using the one-bath two-step method achieve the same color depth compared with the traditional dyeing process. The rubbing fastness and washing fastness reach grade 4-5. Take Disperse Blue 79 and Reactive Blue 19 for example, compared with the traditional two-bath pad dyeing process, the one-bath pad dyeing process reduces water consumption by 45.5%, electricity consumption by 20.9%, heat consumption by 41.7% and CO₂ emission by 40.6% per 10 000 m of polyester/cotton fabric.

Key words: polyester/cotton fabric, one-bath two-step method, pad dyeing, disperse dye, reactive dye, low carbon emission, color strength

中图分类号:

TS193.6

刘宇, 谢汝义, 宋亚伟, 齐元章, 王辉, 房宽峻. 涤/棉交织物一浴法轧染工艺[J]. 纺织学报, 2022, 43(05): 18-25.

LIU Yu, XIE Ruyi, SONG Yawei, QI Yuanzhang, WANG Hui, FANG Kuanjun. One-bath pad dyeing technology for polyester/cotton fabric[J]. Journal of Textile Research, 2022, 43(05): 18-25.

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参考文献 21

[1]	赵欣, 高淑珍. 涤/棉交织物分散/活性碱性一浴一步法染色工艺探讨[J]. 纺织学报, 2003, 24(2):60-62.
	ZHAO Xin, GAO Shuzhen. Alkali one-bath one-step dyeing of polyester/cotton fabric with disperse/reactive dyes[J]. Journal of Textile Research, 2003, 24(2):60-62. doi: 10.1177/004051755402400111
[2]	HAJI A, MALEK R. MAZAHERI F. Comparative study of exhaustion and pad-steam methods for improvement of handle, dye uptake and water absorption of polyester/cotton fabric[J]. Chemical Industry & Chemical Engineering Quarterly, 2011, 17(3):359-365.
[3]	YANG L L, XU Z X, LI H Q, et al. Synthesis, characterization, and dyeing assessment of reactive dyes containing a benzsulfonamide moiety[J]. Fibers and Polymers, 2021, 22(4):1000-1008. doi: 10.1007/s12221-021-0179-7
[4]	ZHANG W, WU C W. Dyeing of multiple types of fabrics with a single reactive azo disperse dye[J]. Chemical Papers, 2013, 68(3):330-335.
[5]	纪柏林, 王碧佳, 毛志平. 纺织染整领域支撑低碳排放的关键技术[J]. 纺织学报, 2022, 43(1):113-121.
	JI Bolin, WANG Bijia, MAO Zhiping. Key technologies supporting low-carbon emissions in dyeing and finishing of textiles[J]. Journal of Textile Research, 2022, 43(1):113-121.
[6]	王小艳, 杜金梅, 彭铃淇, 等. 涤纶针织物碱减量和染色一浴一步法工艺[J]. 纺织学报, 2020, 41(1): 80-87.
	WANG Xiaoyan, DU Jinmei, PENG Lingqi, et al. Alkali reduction and one-bath-one-step process for dyeing polyester knitted fabric[J]. Journal of Textile Research, 2020, 41(1):80-87.
[7]	李纪蓁, 房宽峻, 陈为超, 等. 涤/棉混纺织物的阳离子纳米球改性及染色[J]. 纺织科学与工程学报, 2017, 34(2):66-69.
	LI Jizhen, FANG Kuanjun, CHEN Weichao, et al. Modification and dyeing of polyester/cotton blended fabric with cationic nanospheres[J]. Journal of Textile Science and Engineering, 2017, 34(2):66-69.
[8]	ZHANG W, JI X Q, WANG C X. One-bath one-step low-temperature dyeing of polyester/cotton blended fabric with cationic dyes via β-cyclodextrin modification[J]. Textile Research Journal, 2019, 89(9):1699-1711. doi: 10.1177/0040517518779249
[9]	王建庆, 吴婵娟, 刘海林. 涤/棉交织物分散/活性染料染色的免还原净洗技术[J]. 纺织学报, 2013, 34(4):70-74.
	WANG Jianqing, WU Chanjuan, LIU Hailin. Reduction clearing-free dyeing of polyester/cotton fabrics with disperse/reactive dyes[J]. Journal of Textile Research, 2013, 34(4):70-74.
[10]	宋心远. 多组分纺织品活性染料生态染色技术[J]. 印染, 2009, 35(13):44-47.
	SONG Xinyuan. Ecological dyeing techniques of multicomponent textiles with reactive dye[J]. China Dyeing & Finishing, 2009, 35(13):44-47.
[11]	何瑾馨, 姚翔, 任绳武. 分散深蓝HGL(C.I.分散蓝79)染料在高温染色过程中化学稳定性的研究[J]. 华东理工大学学报(自然科学版), 1986, 12(1):61-68.
	HE Jinxin, YAO Xiang, REN Shengwu. Study on the chemical stability of disperse dark blue HGL(C.I. Disperse Blue 79) dye during high temperature dyeing[J]. Journal of East China University of Science and Technology(Natural Science Edition), 1986, 12(1):61-68.
[12]	王平三, 范桂生, 程敏, 等. 涤/棉色布分散/活性同浴轧焙法中性固色工艺探讨[J]. 印染, 1995, 21(11):10-12.
	WANG Pingsan, FAN Guisheng, CHENG Min, et al. Study on neutral color fixing process of dispersed/reactive one-bath rolling calcination of polyester cotton color cloth[J]. China Dyeing & Finishing, 1995, 21(11):10-12.
[13]	BURDETT B C, 沈煜如. pH实际意义和控制方法:上[J]. 国外纺织技术, 1985(2):38-42.
	BURDETT B C, SHEN Yuru. Practical significance and Control method of pH: part 1[J]. Textile Technology Overseas, 1985(2):38-42.
[14]	周乃锋, 傅伟松, 唐智勇, 等. 基于粒径分析的分散染料黑浆聚集沉淀[J]. 纺织学报, 2016, 37(4):80-85.
	ZHOU Naifeng, FU Weisong, TANG Zhiyong, et al. Precipitation of disperse dye black slurry based on diameter analysis[J]. Journal of Textile Research, 2016, 37(4):80-85.
[15]	KIM T K, SON Y A, LIM Y J. Thermodynamic parameters of disperse dyeing on several polyester fibers having different molecular structures[J]. Dyes and Pigments, 2005, 67(3):229-234. doi: 10.1016/j.dyepig.2004.12.005
[16]	王菊生. 染整工艺原理:第3册[M]. 北京: 纺织工业出版社, 1984:209.
	WANG Jusheng. Dyeing and finishing process principle:Ⅲ[M]. Beijing: Textile Industry Press, 1984:209.
[17]	陈维国, 戴瑾瑾, 王俊苏, 等. 高耐光色牢度还原染料对涤纶织物的热熔法染色[J]. 纺织学报, 2008, 29(9):82-86.
	CHEN Weiguo, DAI Jinjin, WANG Junsu, et al. Thermosol dyeing of polyester fabrics with high light fastness vat dyes[J]. Journal of Textile Research, 2008, 29(9):82-86.
[18]	薛迪庚. 涤/棉混纺织物的染整[M]. 北京: 纺织工业出版社, 1982:405.
	XUE Digeng. Dyeing and finishing of polyester cotton blended fabric[M]. Beijing: Textile Industry Press, 1982:405.
[19]	张鑫卿, 张健飞, 房宽峻, 等. 应用活性蓝19的棉织物低含水率-湿蒸染色工艺[J]. 纺织学报, 2017, 38(2):129-133.
	ZHANG Xinqing, ZHANG Jianfei, FANG Kuanjun, et al. Low-water content wet-steaming fixation of cotton fabric padded with Reactive Blue 19[J]. Journal of Textile Research, 2017, 38(2):129-133.
[20]	张蓉, 沈一峰, 林素玲, 等. C.I.活性蓝19在低温下的水解性能研究[J]. 浙江理工大学学报, 2008, 25(2):132-136.
	ZHANG Rong, SHEN Yifeng, LIN Suling, et al. Study on the hydrolysis kinetics of C. I. Reactice Blue 19 at low-temperature with HPLC analysis[J]. Journal of Zhejiang Sci-Tech University, 2008, 25(2):132-136.
[21]	张英菊, 宋东明. 分散染料在涤/棉混纺织物热熔固色中的转移机理[J]. 染料与染色, 1983(4):43-49.
	ZHANG Yingju, SONG Dongming. Transfer mechanism of disperse dyes in hot melting of polyester/cotton blended fabric[J]. Dyestuffs and Coloration, 1983(4):43-49.

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活性染料类型	染浴pH值	L^*	a^*	b^*	K/S值
K型	4	38.9	-1.4	-31.2	7.8
	5	39.5	-1.5	-31.4	7.6
	6	39.3	-1.0	-31.9	7.6
KN型	4	36.9	-0.7	-33.3	9.5
	5	37.5	-0.9	-33.4	9.2
	6	36.7	-0.7	-32.9	9.5
M型	4	36.0	-0.5	-31.4	9.5
	5	36.5	-1.1	-32.1	9.5
	6	36.4	-0.4	-31.9	9.3

Na₂CO₃质量浓度/(g·L^-1)	L^*	a^*	b^*	K/S值
10	26.9	-1.4	-26.2	19.8
20	26.0	-1.1	-25.4	20.5
30	26.5	-1.5	-25.7	20.3
40	26.9	-1.5	-26.2	20.0
50	26.9	-1.5	-26.3	20.0

活性染料	工艺方法	K/S值	耐摩擦色牢度/级		耐皂洗色牢度/级
活性染料	工艺方法	K/S值	干	湿	棉沾	变色
K型	两浴轧染	4.0	5	5	4~5	5
K型	一浴轧染	4.0	5	4~5	4~5	5
KN型	两浴轧染	9.6	5	5	4~5	5
KN型	一浴轧染	9.5	5	4~5	4~5	5
M型	两浴轧染	8.1	5	5	4~5	5
M型	一浴轧染	7.9	5	4~5	4~5	5

工艺	水耗/t	电能消耗/ (kW·h)	热能消耗/ GJ	CO₂排放量/ t
两浴轧染	399.3	408.3	63.8	7.4
一浴轧染	217.8	322.9	37.2	4.4
节省比例/%	45.5	20.9	41.7	40.6

涤/棉交织物一浴法轧染工艺

One-bath pad dyeing technology for polyester/cotton fabric

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