纺织学报 ›› 2023, Vol. 44 ›› Issue (10): 53-59.doi: 10.13475/j.fzxb.20220506101

• 纺织工程 • 上一篇    下一篇

形状记忆氨纶/锦纶包覆纱的制备及其压力袜性能

王雅倩1, 万爱兰1(), 曾登2, 吴光军1, 祁倩2   

  1. 1.江南大学 针织技术教育部工程研究中心, 江苏 无锡 214122
    2.连云港杜钟新奥神氨纶有限公司, 江苏 连云港 222069
  • 收稿日期:2022-05-19 修回日期:2022-08-22 出版日期:2023-10-15 发布日期:2023-12-07
  • 通讯作者: 万爱兰(1976—),女,副教授,博士。主要研究方向为纺织材料与智能纺织品。E-mail:ailan.wan@jiangnan.edu.cn
  • 作者简介:王雅倩(1996—),女,硕士生。主要研究方向为智能纺织品。
  • 基金资助:
    国家自然科学基金项目(61902150);中央高校基本科研业务费专项资金资助项目(JUSRP122003)

Preparation of shape memory polyurethane/polyamide covered yarn and properties of compression socks

WANG Yaqian1, WAN Ailan1(), ZENG Deng2, WU Guangjun1, QI Qian2   

  1. 1. Engineering Research Center for Knitting Technology, Ministry of Education, Wuxi, Jiangsu 214122, China
    2. Lianyungang LDZ New Ao Shen Spandex Co., Ltd., Lianyungang, Jiangsu 222069, China
  • Received:2022-05-19 Revised:2022-08-22 Published:2023-10-15 Online:2023-12-07

摘要:

为改善常规压力袜因压力过高而易给人体带来穿脱困难的问题,采用玻璃化转变温度接近人体体表温度的形状记忆氨纶(SMPU)与锦纶编织并设计3种平纹衬垫组织衬垫比的形状记忆氨纶压力袜。分别对SMPU的玻璃化转变温度和形状记忆性能,以及形状记忆氨纶/锦纶(SMPU/PA)包覆纱的形状记忆性能、拉伸强力、弹性回复性能进行评价。探究形状记忆氨纶压力袜袜筒部位平纹衬垫组织的衬垫比以及衬垫纱的送纱张力对人体脚踝最细处压力的影响。结果表明:人体体表温度即可触发SMPU的形状记忆性能,SMPU和SMPU/PA 包覆纱均具有良好的形状记忆性能;SMPU/PA包覆纱在玻璃化转变温度以上时的弹性回复率和断裂强力比玻璃化转变温度以下时分别提高24.76%、降低18.56%;以SMPU/PA包覆纱为衬垫纱制得的SMPU压力袜,其袜筒部位的压力在温度达到玻璃化转变温度以上与玻璃化转变温度以下时相比最大可提高16.26%;且衬垫比为1∶3,送纱张力为8 cN时,SMPU压力袜的压力最大可达到2 841 Pa。

关键词: 氨纶/锦纶包覆纱, 压力袜, 玻璃化转变温度, 平纹衬垫组织, 衬垫比, 送纱张力

Abstract:

Objective As a new functional knitted product, compression socks exert pressure on human legs through deformation, which can help lower limb vascular reflux and reduce tissue edema, thus improving lower limb venous pressure and promoting blood circulation. In order to improve the comfort of conventional compression socks, shape memory polyurethane filament (SMPU), whose glass transition temperature is close to the surface temperature of human body, was used to prepare and design SMPU compression socks with three fleecy ratios.

Method In this paper, SMPU/polyamide(SMPU/PA) covered yarn and cotton yarn were used to knit the stocking part of the compression sock by a two-thread fleecy stitch. The glass transition temperature, shape memory properties, tensile strength and elastic recovery properties of SMPU and SMPU/PA covered yarn were evaluated. The influence of the fleecy ratio and the feeding tension of the fleecy yarn of SMPU compression socks on the pressure at the thinnest pressure test point B of human ankle was investigated.

Results The DSC curves showed that the transition temperature of SMPU was 32.15 ℃(Fig. 5), which was close to the human body surface temperature of 34 ℃. While the shape fixity ratio and shape recovery ratio of SMPU were 90% and 91%, the shape fixity ratio and shape recovery ratio of SMPU/PA covered yarn were 85% and 89%, respectively. The elastic recovery rate and breaking strength of SMPU/PA covered yarn were increased by 24.76% and decreased by 18.56% while the pressure of the stocking part of the SMPU compression sock increased by 16.26% when the test temperature was above glass transition temperature compared with that below glass transition temperature. The pressure test data showed that at a feeding tension of 6 cN, the compression sock with a fleecy ratio of 1∶3 had a maximum pressure increase of 11% compared to that with a fleecy ratio of 1∶1(Fig. 6). A long float stitch allowed more room for the internal stresses stored in the SMPU to be released, and the SMPU could reach the maximum variation in length, resulting in the largest pressure. At a fleecy ratio of 1∶3, the pressure of the SMPU compression sock with a feeding tension of 8 cN was increased by 30% compared to that of 4 cN. When the feeding tension was increased, the content of SMPU/PA covered yarn fed into the sock was risen, and thus the pressure of the compression sock increased. When the fleecy ratio was 1∶3 and the yarn feeding tension was 8 cN, the maximum pressure of SMPU compression socks reached 2 841 Pa.

Conclusion The shape memory performance of SMPU can be triggered by body surface temperature. Both SMPU and SMPU/PA covered yarn have good shape memory performance that are suitable for fabrics and clothing. The SMPU compression socks are easier to wear because SMPU can fix large deformation and the deformation can recover by internal stress release after the temperature rise. When the fleecy ratio of the two-thread fleecy in the stocking part is 1∶3 and the feeding tension of the fleecy yarn is 8 cN, the SMPU/PA content is the highest, and the float length is the longest, and the pressure of the socks knitting parameter will be the highest. The pressure of the SMPU compression socks in this study meets the requirements of FZ/T 73031—2009 for the thinnest pressure test point B of the ankle circumference.

Key words: polyurethane/polyamide covered yarn, compression sock, glass transition temperature, plain backing structure, fleecy ratio, yarn feeding tension

中图分类号: 

  • TS182.5

图1

平纹衬垫组织"

表1

压力袜工艺参数"

样品名称 衬垫纱 送纱张力/cN 衬垫比
PU压力袜 PU包覆纱 4、5、6、7、8 1∶1、1∶2、1∶3
SMPU压力袜 SMPU包覆纱 4、5、6、7、8 1∶1、1∶2、1∶3

图2

压力袜实物图"

图3

压力测试装置"

图4

压力测试点"

图5

SMPU的差示扫描量热曲线"

表2

包覆纱弹性回复性能测试结果"

包覆纱 弹性回复率 塑性变形率
20 ℃ 34 ℃ 20 ℃ 34 ℃
PU/PA 62.31 63.22 37.69 36.78
SMPU/PA 46.40 57.89 53.60 42.11

表3

包覆纱拉伸性能测试结果"

包覆纱 断裂强力/cN 断裂伸长率/%
20 ℃ 34 ℃ 20 ℃ 34 ℃
PU/PA 309.20 304.10 32.68 32.04
SMPU/PA 407.70 332.00 42.85 36.20

图6

PU压力袜的压力测试结果"

图7

SMPU压力袜的压力测试结果"

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