聚乙烯亚胺/聚丙烯腈复合纤维薄膜的制备及其功能化应用

doi:10.13475/j.fzxb.20230600801

纺织学报 ›› 2024, Vol. 45 ›› Issue (09): 26-32.doi: 10.13475/j.fzxb.20230600801

聚乙烯亚胺/聚丙烯腈复合纤维薄膜的制备及其功能化应用

王浩然¹, 于影²(), 左雨欣³, 顾志清², 卢海龙¹, 陈洪立¹, 柯俊¹

1.浙江理工大学机械工程学院, 浙江杭州 310018
2.嘉兴学院信息科学与工程学院, 浙江嘉兴 314001
3.嘉兴南湖学院, 浙江嘉兴 314001

收稿日期:2023-06-05 修回日期:2024-03-22 出版日期:2024-09-15 发布日期:2024-09-15
通讯作者: 于影(1988—),女,副教授,博士。研究方向为功能化纤维材料制备与柔性电子器件。E-mail: yingyu@zjxu.edu.cn。
作者简介:王浩然(1999—),男,硕士生。主要研究方向为功能纤维。
基金资助:
国家自然科学基金项目(52305059);浙江省自然科学基金项目(LGG21E050021);嘉兴市应用性基础研究专项资助项目(2020AY10015);嘉兴市应用性基础研究专项资助项目(2020AD10015);嘉兴市应用性基础研究专项资助项目(2021AY30020)

Preparation and functional application of polyethyleneimine/polyacrylonitrile composite fiber membrane

WANG Haoran¹, YU Ying²(), ZUO Yuxin³, GU Zhiqing², LU Hailong¹, CHEN Hongli¹, KE Jun¹

1. School of Mechanical Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
2. College of Information Science and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
3. Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China

Received:2023-06-05 Revised:2024-03-22 Published:2024-09-15 Online:2024-09-15

摘要/Abstract

摘要：

针对金属-空气电池阴极易腐蚀的问题,将聚乙烯亚胺(PEI)和聚丙烯腈(PAN)共混,基于静电纺丝方法制备PEI/PAN复合纤维薄膜,抑制CO₂对空气阴极的侵蚀。借助计算机模拟方法计算PEI/PAN复合纤维薄膜的最佳成分配比,采用扫描电子显微镜、傅里叶变换红外吸收光谱仪、同步热分析仪等对PEI/PAN复合纤维薄膜的物理特性、CO₂吸附性能进行表征和分析。以铝-空气电池为例,通过电池测试系统分析了PEI/PAN复合纤维薄膜对电池电化学性能的影响情况。结果表明:基于静电纺丝技术可成功将PEI嵌入PAN纤维中,所制备的PEI/PAN复合纤维薄膜纤维直径均一且表面光滑;当PEI/PAN复合纤维薄膜中的PEI质量分数为50%时,在100 kPa条件下其CO₂吸附量可达1.86 mmol/g;在金属-空气电池阴极添加PEI/PAN复合纤维薄膜,相较于传统铝-空气电池,其比容量提升19.5%,放电时间延长20.4%。

关键词: 复合纤维薄膜, CO₂吸附, 聚乙烯亚胺, 聚丙烯腈, 空气阴极腐蚀, 金属-空气电池, 静电纺丝

Abstract:

Objective The CO₂ corrosion of metal-air batteries is extremely serious, which greatly limits the service life of the metal-air batteries. Existing researches generally add CO₂ absorbers or O₂ selective membranes to the cathodes, which indeed inhibit the CO₂ corrosion to a certain extent, but have a negative impact on the electrochemical performance of the batteries. Therefore, there is an urgent need to explore a new method to inhibit cathode corrosion in metal-air batteries, which would not sacrifice the electrochemical performance of the battery and can effectively inhibit CO₂ corrosion.

Method Polyethyleneimine/polyacrylonitrile (PEI/PAN) precursor solutions with different PEI contents were prepared, and PEI/PAN composite fiber membranes were fabricated by electrospinning. The microstructure of the composite fiber membrane was characterized by scanning electron microscope and infrared spectrometer. The influences of different PEI contents on the CO₂ adsorption performance of PEI/PAN composite fiber membranes were studied combining computer simulation and CO₂ adsorption-desorption experiments. An aluminum-air battery with a PEI/PAN composite fiber membrane was prepared to verify the optimization effect of the composite fiber membrane on the discharge performance of the battery.

Results PEI was successfully embedded into PAN fibers through electrospinning, and the surface was smooth and the layered fiber structure was evenly distributed. The computer simulation results showed that the PEI/PAN composite fiber membrane of system II (50% PEI) illustrated excellent adsorption performance, and the CO₂ adsorption-desorption experiment further confirmed the simulation results. When the pressure was 100 kPa, the adsorption capacity of PEI/PAN composite fiber membrane was 1.86 mmol/g. The experimental and simulation results agreed well to each other. Taking aluminum-air batteries as an example, aluminum-air batteries with PEI/PAN composite fiber membranes were assembled. Electrochemical test results showed that compared with conventional aluminum-air batteries, the cathode corrosion of aluminum-air batteries with PEI/PAN composite fiber membrane was significantly inhibited. The discharge time of the aluminum battery with PEI/PAN composite fiber membrane was 548 min, while the conventional aluminum-air battery was only 455 min. The discharge time of the battery with the composite fiber film was prolonged by 20.4%, and the specific capacity was increased by 19.5%, proving that the PEI/PAN composite fiber film could effectively inhibit the corrosion of the positive electrode and improve the electrochemical performance of the battery.

Conclusion The PEI/PAN composite fiber membrane prepared has excellent adsorption properties, and its application in metal-air batteries can effectively inhibit the corrosion of CO₂ on the air cathode. Adding PEI/PAN composite fiber membrane to the cathode of aluminum-air battery can significantly increase the specific capacity and prolong the discharge time of the battery.

Key words: composite fiber membrane, CO₂ adsorption, polyethyleneimine, polyacrylonitrile, air cathode corrosion, metal-air battery, electrostatic spinning

中图分类号:

TQ152

王浩然, 于影, 左雨欣, 顾志清, 卢海龙, 陈洪立, 柯俊. 聚乙烯亚胺/聚丙烯腈复合纤维薄膜的制备及其功能化应用[J]. 纺织学报, 2024, 45(09): 26-32.

WANG Haoran, YU Ying, ZUO Yuxin, GU Zhiqing, LU Hailong, CHEN Hongli, KE Jun. Preparation and functional application of polyethyleneimine/polyacrylonitrile composite fiber membrane[J]. Journal of Textile Research, 2024, 45(09): 26-32.

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链接本文: http://www.fzxb.org.cn/CN/10.13475/j.fzxb.20230600801

http://www.fzxb.org.cn/CN/Y2024/V45/I09/26

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参考文献 22

[1]	于小燕, 李萌, 魏磊, 等. 聚丙烯腈在锂金属电池电解质中的应用[J]. 化学进展, 2023, 35(3): 390-406. doi: 10.7536/PC220913
	YU Xiaoyan, LI Meng, WEI Lei, et al. Application of polyacrylonitrile in electrolytes of lithium metal battery[J]. Progress in Chemistry, 2023, 35(3): 390-406. doi: 10.7536/PC220913
[2]	BUCKINGHAM R, ASSET T, ATANASSOV P. Aluminum-air batteries: a review of alloys, electrolytes and design[J]. Journal of Power Sources, 2021. DOI: 10.1016/j.jpowsour.2021.229762.
[3]	唐丽琴, 李彦, 毛吉富, 等. 检测汗液用可穿戴电化学传感器的研究进展[J]. 纺织学报, 2023, 44(3): 221-230.
	TANG Liqin, LI Yan, MAO Jifu, et al. Research progress in wearable electrochemical sensors for sweat detecting[J]. Journal of Textile Research, 2023, 44(3): 221-230.
[4]	MACDONALD D D, ENGLISH C. Development of anodes for aluminium/air batteries-solution phase inhibition of corrosion[J]. Journal of Applied Electrochemistry, 1990, 20: 405-417.
[5]	ZHAO D, ZHANG Z, REN J, et al. Fe₂VO₄ nanoparticles on rGO as anode material for high-rate and durable lithium and sodium ion batteries[J]. Chemical Engineering Journal, 2023. DOI: 10.1016/j.cej.2022.138882.
[6]	ZHANG Q, WANG C, XIE Z, et al. Defective/doped graphene‐based materials as cathodes for metal-air batteries[J]. Energy & Environmental Materials, 2022, 5(4): 1103-1116.
[7]	LIU X, ZHANG G, WANG L, et al. Structural design strategy and active site regulation of high‐efficient bifunctional oxygen reaction electrocatalysts for Zn-air battery[J]. Small, 2021. DOI: 10.1002/smll.202006766.
[8]	ZHENG R, SHU C, LI J, et al. Oxygen vacancy engineering of vertically aligned NiO nanosheets for effective CO₂ reduction and capture in Li-CO₂ battery[J]. Electrochimica Acta, 2021. DOI: 10.1016/j.electacta.2021.138359.
[9]	ZHANG P F, SHENG T, ZHOU Y, et al. Li-CO₂/O₂ battery operating at ultra-low overpotential and low O₂ content on Pt/CNT catalyst[J]. Chemical Engineering Journal, 2022. DOI: 10.1016/j.cej.2022.137541.
[10]	NAJAM T, SHAH S S A, IBRAHEEM S, et al. Single-atom catalysis for zinc-air/O₂ batteries, water electrolyzers and fuel cells applications[J]. Energy Storage Materials, 2022, 45: 504-540.
[11]	王焕君, 靳归, 李野, 等. 基于不同粒径ZIF-8多孔液体的二氧化碳捕集性能[J]. 精细化工, 2023, 40(3): 572-583.
	WANG Huanjun, JIN Gui, LI Ye, et al. Carbon dioxide capture performance of porous liquids based on ZIF-8 with different particle sizes[J]. Fine Chemicals, 2023, 40(3): 572-583.
[12]	IGLINA T, IGLIN P, PASHCHENKO D. Industrial CO₂ capture by algae: a review and recent advances[J]. Sustainability, 2022. DOI: 10.3390/su14073801.
[13]	ZHAO J, YING Y, WANG G, et al. Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries[J]. Energy Storage Materials, 2022, 48: 82-89.
[14]	沈雪华, 颜枫, 谢丰, 等. 固废源固态胺吸附剂用于CO₂捕集研究进展[J]. 硅酸盐学报, 2023, 51(9): 2411-2422.
	SHEN Xuehua, YAN Feng, XIE Feng, et al. Research progress of solid amine adsorbents from solid waste for CO₂ capture[J]. Journal of the Chinese Ceramic Society, 2023, 51(9): 2411-2422.
[15]	陈明星, 张威, 王新亚, 等. 纳米纤维基催化材料的制备及其在环境领域中的应用研究进展[J]. 纺织学报, 2023, 44(1): 209-218.
	CHEN Mingxing, ZHANG Wei, WANG Xinya, et al. Research progress of preparation of nanofiber-supported catalysts and application thereof in environmental protection[J]. Journal of Textile Research, 2023, 44(1): 209-218.
[16]	王纯怡, 吴伟, 王健, 等. C.I分散棕19在超临界CO₂及水中溶解性的分子动力学模拟[J]. 纺织学报, 2020, 41(9): 95-101.
	WANG Chunyi, WU Wei, WANG Jian, et al. Molecular dynamics simulation of solubility of C.I. Dispersed Brown 19 in supercritical CO₂ and water[J]. Journal of Textile Research, 2020, 41(9): 95-101.
[17]	王嘉乐, 王越锋, 左雨欣, 等. 静电纺丝制备铝-空气电池阳极防腐薄膜[J]. 表面技术, 2021, 50(12): 364-71.
	WANG Jiale, WANG Yuefeng, ZUO Yuxin, et al. Preparation of anti-corrosive film for Al-air battery anode by electrospinning[J]. Surface Technology, 2021, 50(12): 364-371.
[18]	DANWITTAYAKUL S, MUENSRI P. Polyethyleneimine coated polyacrylonitrile cellulose membrane for colorimetric copper (II) determina-tion[J]. Journal of Water Chemistry and Technology, 2020, 42: 22-29.
[19]	LIU M, ZHANG X, HAN R, et al. Crosslinked polyethylenimine/polyacrylonitrile blend membrane for multifunctional adsorption of heavy metals and endocrine disrupting chemicals in solution[J]. Journal of Molecular Liquids, 2022. DOI: 10.1016/j.molliq.2022.120124.
[20]	ZENG K, LU T, JIANG P, et al. Methane adsorption capacity measurement in shale matrix nanopores at high pressure by low-field NMR and molecular simula-tion[J]. Chemical Engineering Journal, 2022. DOI: 10.1016/j.cej.2021.133151.
[21]	LIU X, WANG S, SHI W, et al. Thermo-/pH-dual-sensitive PEG/PAMAM nanogel: reaction dynamics and plugging application of CO₂ channeling[J]. Gels, 2022. DOI: 10.3390/gels8100683.
[22]	张靖超, 郭百合, 张佳栋, 等. SO₂对掺杂KMnO₄的K₂CO₃/Al₂O₃吸附剂脱碳性能影响[J]. 环境科学与技术, 2023, 46(3): 230-236.
	ZHANG Jingchao, GUO Baihe, ZHANG Jiadong, et al. Effect of SO₂ on decarbonization performance of K₂CO₃/Al₂O₃ adsorbent doped with KMnO₄[J] Environmental Science and Technology, 2023, 46(3): 230-236.

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体系	PEI		PAN
体系	分子数	质量分数/%	分子数	质量分数/%
Ⅰ	575	33	970	67
Ⅱ	885	50	740	50
Ⅲ	1 050	60	565	40

压强/ kPa	吸附量/(mmol·g^-1)
压强/ kPa	体系Ⅰ	体系Ⅱ	体系Ⅲ
40	1.34	1.65	1.01
65	1.55	1.95	1.05
100	1.82	2.05	1.26

压强/ kPa	吸附量/(mmol·g^-1)
压强/ kPa	体系Ⅰ	体系Ⅱ	体系Ⅲ
40	1.18	1.66	0.88
65	1.29	1.73	1.00
100	1.54	1.86	1.12

体系	压强/ kPa	q_m/ (mmol·g^-1)	k_a/ min^-1	n
Ⅰ	40	1.34	0.016	1.121
	65	1.55	0.016	1.121
	100	1.82	0.016	1.121
Ⅱ	40	1.65	0.018	1.131
	65	1.95	0.018	1.131
	100	2.05	0.018	1.131
Ⅲ	40	1.01	0.034	1.117
	65	1.05	0.034	1.117
	100	1.26	0.034	1.117

聚乙烯亚胺/聚丙烯腈复合纤维薄膜的制备及其功能化应用

Preparation and functional application of polyethyleneimine/polyacrylonitrile composite fiber membrane

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