蒙脱土协同TiO2整理棉织物的功能性

doi:10.13475/j.fzxb.20230904801

纺织学报 ›› 2024, Vol. 45 ›› Issue (09): 121-128.doi: 10.13475/j.fzxb.20230904801

蒙脱土协同TiO₂整理棉织物的功能性

赵强¹^,², 刘正江¹(), 高晓平¹, 张云婷¹, 张宏²

1.内蒙古工业大学轻工与纺织学院, 内蒙古呼和浩特 010080
2.塔里木大学机械电气化工程学院, 新疆阿拉尔 843300

收稿日期:2023-09-19 修回日期:2024-05-21 出版日期:2024-09-15 发布日期:2024-09-15
通讯作者: 刘正江(1988—),男,副教授,博士。研究方向为纺织品功能整理与印染污水处理。E-mail: zhengjliu@imut.edu.cn。
作者简介:赵强(1993—),男,硕士生。主要研究方向为纺织品功能整理。
基金资助:
内蒙古自治区自然科学基金项目(2021BS02017);内蒙古自治区直属高校基本科研业务费资金资助项目(JY20220308)

Functionality of cotton fabrics finished by montmorillonite combined with TiO₂

ZHAO Qiang¹^,², LIU Zhengjiang¹(), GAO Xiaoping¹, ZHANG Yunting¹, ZHANG Hong²

1. College of Light Industry and Textile, Inner Mongolia University of Technology, Hohhot, Inner Mongolia 010080, China
2. College of Mechanical and Electrical Engineering, Tarim University, Aral, Xinjiang 843300, China

Received:2023-09-19 Revised:2024-05-21 Published:2024-09-15 Online:2024-09-15

摘要/Abstract

摘要：

为解决TiO₂在棉织物表面易团聚而导致光能利用率低的问题,采用蒙脱土与TiO₂二者协同对棉织物进行整理,以轧—烘—焙的方式将TiO₂和蒙脱土整理到棉织物上,制备了具有紫外线防护、抗老化和自清洁能力的棉织物。借助扫描电子显微镜、傅里叶变换红外光谱仪和紫外可见漫反射光谱仪对整理前后的棉织物进行分析,并通过纺织品紫外线测试仪、白度测试仪及织物风格仪等测试其紫外线防护性能、白度和风格变化。结果表明:整理后棉织物的长波黑斑效应紫外线(UVA)透过率为1.81%,中波红斑效应紫外线(UVB)透过率为0.87%,紫外线防护因子(UPF)为100+,且经50次皂洗后UPF值仍能维持在50+;整理后棉织物的抗老化性能提高了16.7%,具有较好的自清洁性能,其白度、透气性能、断裂强力和风格等有一定程度的损失,但损失不大。

关键词: 二氧化钛, 蒙脱土, 棉织物, 紫外线防护, 自清洁, 功能性纺织品, 功能整理

Abstract:

Objective In order to enable multifunctions of cotton fabrics and reduce agglomeration of TiO₂ on cotton fabric surface, TiO₂/montmorillonite finishing agent was prepared by sol-gel method at lower temperature using tetrabutyl titanate and montmorillonite as the precursor, aiming to reduce agglomeration of TiO₂. At the same time, the reduction of TiO₂ consumption was fargetted to increase the added value of montmorillonite products.

Method TiO₂/montmorillonite was firstly synthesized using ultrasound-sol-gel method and then deposited onto the surface of cotton fabrics by two-dipping and two-rolling processes. The properties of the cotton fabric before and after treatment were analyzed using Fourier transform infrared (FT-IR) spectrometer and energy dispersive spectrometer, while the surface morphologies of the cotton fabrics were analyzed by scanning electron microscopy. The whiteness, air permeability, breaking strength and elongation of TiO₂/montmorillonite-finished cotton fabrics were measured, respectively. In addition, the performance such as hand feel attributes, softness, smoothness and stiffness were measured. Rhodamine B was used as a test contaminant to qualitatively assess the self-cleaning performance of the TiO₂/montmorillonite finished cotton fabric.

Results The SEM and EDS results indicated that TiO₂/montmorillonite was uniformly distributed on cotton fibers surface. UV-visible diffuse reflectance spectrum result showed that TiO₂/montmorillonite finished cotton fabric demonstrated excellent absorption capability to UV light, while the FT-IR result showed that the bonding mode between TiO₂/montmorillonite and cotton fiber was formed through covalent bonding. The anti-aging performance test showed that after 96 h UV irradiation, the strength loss of TiO₂ finished cotton fabric was 22.9%, while the strength loss of TiO₂/montmorillonite finished cotton fabric was 15.4%, indicating that the montmorillonite compound could improve the anti-aging performance of TiO₂. The self-cleaning performance test showed that TiO₂/montmorillonite finished cotton fabric had satisfactory self-cleaning capability. Nevertheless, compared with raw cotton fabric, the whiteness of TiO₂/montmorillonite finished cotton fabric was decreased by 25.8%, the breaking strength decreased by 10.2%, and the air permeability decreased by 5.7%, respectively.

Conclusion A cotton fabric with UV protection, anti-aging, and self-cleaning performances was prepared by applying TiO₂ and montmorillonite onto the fabric surface using the rolling-baking-baking process. The result indicated that the UVA transmittance, UVB transmittance, and UPF value of TiO₂/montmorillonite finished cotton fabric were 1.81%, 0.87%, and 100+, respectively. Moreover, the UPF value of the treated cotton fabric was still maintained at 50+ after 50 cycles of soap washing, and the fabric's anti-aging performances were increased by 16.7% after post-treatment. Also, the Ti—O—Si bond was formed between TiO₂ and montmorillonite, which reduces recombination of electron-hole pairs of TiO₂, and effectively controls the TiO₂ particle size, thus improving the properties of TiO₂ finished cotton fabrics.

Key words: titanium dioxide, montmorillonite, cotton fabric, ultraviolet resistance, self-cleaning, functional textile, functional finishing

中图分类号:

TS195.5

赵强, 刘正江, 高晓平, 张云婷, 张宏. 蒙脱土协同TiO₂整理棉织物的功能性[J]. 纺织学报, 2024, 45(09): 121-128.

ZHAO Qiang, LIU Zhengjiang, GAO Xiaoping, ZHANG Yunting, ZHANG Hong. Functionality of cotton fabrics finished by montmorillonite combined with TiO₂[J]. Journal of Textile Research, 2024, 45(09): 121-128.

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链接本文: http://www.fzxb.org.cn/CN/10.13475/j.fzxb.20230904801

http://www.fzxb.org.cn/CN/Y2024/V45/I09/121

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参考文献 21

[1]	FERNANDES M, PADRÃO J, RIBEIRO A I, et al. Polysaccharides and metal nanoparticles for functional textiles: a review[J]. Nanomaterials, 2022.DOI:10.3390/nano12061006.
[2]	帅旗, 孙硕, 成世杰, 等. 氮硼掺杂碳量子点/异氰酸酯型微胶囊复合整理棉织物及其防紫外线性能[J]. 纺织学报, 2023, 44(8): 126-132.
	SHUAI Qi, SUN Shuo, CHENG Shijie, et al. Effect of isocyanate microcapsules on UV protection of carbon quantum dot finished cotton fabrics[J]. Journal of Textile Research, 2023, 44(8): 126-132.
[3]	HUANG J Y, LI S H, GE M Z, et al. Robust superhydrophobic TiO₂@fabrics for UV shielding, self-cleaning and oil-water separation[J]. Journal of Materials Chemistry A, 2015, 3(6): 2825-2832.
[4]	WORSLEY D A, SEARLE J R. Photoactivity test for TiO₂ pigment photocatalysed polymer degradation[J]. Materials Science and Technology, 2013, 18(6): 681-684.
[5]	KUBACKA A, M FERNÁNDEZ-GARCÍA, COLÓN G. Advanced nanoarchitectures for solar photocatalytic applications[J]. Chemical Reviews, 2012, 112(3): 1555-1564. doi: 10.1021/cr100454n pmid: 22107071
[6]	BI Z, PARANTHAMAN M P, MENCHHOFER P A, et al. Self-organized amorphous TiO₂ nanotube arrays on porous Ti foam for rechargeable lithium and sodium ion batteries[J]. Journal of Power Sources, 2013, 222: 461-466.
[7]	HENYCH J R, STENGL V. Feasible synthesis of TiO₂ deposited on kaolin for photocatalytic applications[J]. Clays and Clay Minerals, 2013, 61(3/4): 165-176.
[8]	KIL H S, RHEE S W. Synthesis and infrared light reflecting characteristics of TiO₂/mica hybrid comp-osites[J]. Journal of the Korean Industrial & Engineering Chemistry, 2016, 27(1): 16-20.
[9]	GERASIMOVA LG, MASLOVA M V, SHCHUKINA E S, et al. Mineral layer fillers for the production of functional materials[J]. Materials, 2021. DOI:10.3390/ma14123369.
[10]	DE LEÓN M A, RODRÍGUEZ M, MARCHETTI S G, et al. Raw montmorillonite modified with iron for photo-Fenton processes: influence of iron content on textural, structural and catalytic properties[J]. Journal of Environmental Chemical Engineering, 2017, 5(5): 4742-4750.
[11]	DAO T B T, HA T T L, NGUYEN T D, et al. Effectiveness of photocatalysis of montmorillonite-supported TiO₂ and TiO₂ nanotubes for rhodamine B degradation[J]. Chemosphere, 2021. DOI:10.1016/j.chemosphere.2021.130802.
[12]	杜姗, 魏云航, 谭宇浩, 等. 棉织物的硅溶胶/短链含氟聚丙烯酸酯复合拒水整理[J]. 纺织学报, 2023, 44(9): 153-160.
	DU Shan, WEI Yunhang, TAN Yuhao, et al. Water-repellent finishing of cotton fabrics with silica sol and short-chain fluorinated polyacrylic ester[J]. Journal of Textile Research, 2023, 44(9): 153-160.
[13]	CHAO H X, SHUN T J, JING Z, et al. Superhydrophobic surfaces on cotton textiles by complex coating of silica nanoparticles and hydro-phobization[J]. Thin Solid Films, 2009, 517(16): 4593-4598.
[14]	余炼钢, 刘衔宇, 陈全莉. “缅绿料”石英质玉的宝石矿物学及谱学表征[J]. 光谱学与光谱分析, 2023, 43(8):2543-2549.
	YU Liangang, LIU Xianyu, CHEN Quanli. Gemstone mineralogical and spectroscopic characteristics of quartzose jade ('Mianlü Yu')[J]. Spectroscopy and Spectral Analysis, 2023, 43(8): 2543-2549.
[15]	RAJAN M S, YOON M, THOMAS J. Kaolin-graphene carboxyl incorporated TiO₂ as efficient visible light active photocatalyst for the degradation of cefuroxime sodium[J]. Photochemical & Photobiological Sciences, 2022, 21(4): 509-528.
[16]	NIE W, RUAN M, GUO D, et al. Design of flexible hydrophobic photocatalytic sheets on polydimethylsiloxane substrates based on carrier migration of Si—O—Ti hybrid bonds for photodegradation of dye molecules[J]. Applied Surface Science, 2023. DOI:10.1016/j.apsusc.2023.156415.
[17]	SALEEM M, NAZ M Y, SHUKRULLAH S, et al. Experimental and statistical analysis of dielectric barrier discharge plasma effect on sonochemically TiO₂ coated cotton fabric using complete composite design[J]. Current Applied Physics, 2021, 31:158-170.
[18]	杨豆豆, 孟家光, 白亚琴, 等. 纯棉针织物的纳米抗紫外整理[J]. 纺织高校基础科学学报, 2020, 33(2):11-16.
	YANG Doudou, MENG Jiaguang, BAI Yaqin, et al. Nano antiultraviolet finishing of cotton knitted fabrics[J]. Basic Sciences Journal of Textile Universities, 2020, 33(2):11-16.
[19]	杨旭, 陈慧. 纤维素/丝素蛋白凝胶改性棉织物的性能[J]. 上海纺织科技, 2023, 51(9):43-50.
	YANG Xu, CHEN Hui. Properties of cotton fabric modified with cellulose /silk fibroin gel[J]. Shanghai Textile Science & Technology, 2023, 51(9):43-50.
[20]	NAKATA K, FUJISHIMA A. TiO₂ photocatalysis: design and applications[J]. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2012, 13(3):169-189.
[21]	CARDONA Y, WEGRZYN A, MISKOWIEC P. Catalytic photodegradation of organic compounds using TiO₂/pillared clays synthesized using a nonconventional aluminum source[J]. Chemical Engineering Journal, 2022. DOI:10.1016/j.cej.2022.136908.

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样品	元素	质量分数/%	原子分数/%
原棉织物	C	39.63	46.65
原棉织物	O	60.37	53.35
TiO₂整理棉织物	C	33.73	42.25
	O	58.96	55.45
	Ti	7.31	2.30
蒙脱土整理棉织物	C	37.24	44.63
	O	60.10	54.06
	Al	0.50	0.27
	Si	1.86	0.95
	Ti	0.31	0.09
TiO₂/蒙脱土整理棉织物	C	34.58	43.36
	O	57.28	53.93
	Al	0.23	0.13
	Si	0.45	0.24
	Ti	7.47	2.35

织物	UPF值	UVA透过率/%	UVB透过率/%
原棉织物	27.3	3.90	3.80
TiO₂整理棉织物	30+	3.26	1.95
蒙脱土整理棉织物	50+	2.48	1.69
TiO₂/蒙脱土整理棉织物	100+	1.81	0.87

皂洗次数	UPF值
皂洗次数	原棉织物	蒙脱土整理棉织物	TiO₂整理棉织物	TiO₂/蒙脱土整理棉织物
0	27.3	30+	50+	100+
10	25.3	30+	50+	100+
20	22.4	30+	50+	100+
30	19.7	30+	50+	50+
40	22.2	27.5	50+	50+
50	20.5	25.2	50+	50+

织物	白度/%		断裂强力/N
织物	正面	反面	断裂强力/N
原棉织物	82.46	87.69	309.2
TiO₂整理棉织物	70.23	75.26	280.0
蒙脱土整理棉织物	78.54	81.12	299.4
TiO₂/蒙脱土整理棉织物	61.2	66.18	277.7

织物	硬挺度	柔软度	光滑度
原棉织物	47.36	82.73	84.01
TiO₂整理棉织物	51.80	79.72	82.77
蒙脱土整理棉织物	50.33	81.77	82.63
TiO₂/蒙脱土整理棉织物	51.42	80.20	83.06

蒙脱土协同TiO₂整理棉织物的功能性

Functionality of cotton fabrics finished by montmorillonite combined with TiO₂

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