含硫杯[4]芳烃银系配合物在织物上的抗菌性能

纺织学报 ›› 2008, Vol. 29 ›› Issue (5): 64-66.

含硫杯[4]芳烃银系配合物在织物上的抗菌性能

李磊¹;郑利民²;咸春颖²

1.安徽工程科技学院纺织面料安徽省高校重点实验室安徽芜湖241000;2.东华大学化学与化工学院上海201620

收稿日期:2007-06-05 修回日期:2007-11-09 出版日期:2008-05-15 发布日期:2008-05-15

Anti-bacterial performance of complexes of sulfur calix[4]arene with silver on fabrics

LI Lei;ZHENG Limin;XIAN Chunying

1.Anhui Provincial Key Laboratory of Textile Fabric;Anhui University of Technology and Science;Wuhu;Anhui 241000;China;2.College of Chemistry and Chemical Engineering;Donghua University;Shanghai 201620;China

Received:2007-06-05 Revised:2007-11-09 Online:2008-05-15 Published:2008-05-15

摘要/Abstract

摘要： 为提高银系抗菌剂的稳定性,用银的络合离子替代银离子,将杯芳烃应用在纺织品抗菌整理中。利用含硫杯[4]芳烃具有可修饰性和对银离子有很好的络合作用等特点,制备了一系列新型杯芳烃银系配合物,并证明其对大肠埃希菌ATCC25922、铜绿假单胞菌ATCC27853、金黄色葡萄球菌ATCC29213和白色念珠菌ATCC10231有良好的抗菌性能。将杯芳烃含银配合物作为抗菌剂整理到棉织物上,整理后的棉织物经10次水洗后,对大肠埃希菌ATCC25922、金黄色葡萄球菌ATCC29213和白色念珠菌ATCC10231仍有良好的抗菌效果。

Abstract: For improving the stability of the Ag-type inorganic antimicrobial materials,new complexes of calix[4] arene with silver were prepared,in which silver complex ions were used for substitution for silver ions.The product was used as antimicrobial agent for finishing textiles.Since modified derivatives of calixarene as receptors can form complex compounds with silver ions,the products have good antimicrobial activities against E.coli ATCC25922,pseudomonas aeruginosa ATCC27853,staphylococcus aureus ATCC29213 and Candidaalbicans ATCC10231.The cotton fabrics treated with these products still remain excellent antimicrobial abilities against E.coli ATCC25922,staphylococcus aureus ATCC29213 and Candidaalbicans ATCC10231 after 10 laundering cycles.

李磊;郑利民;咸春颖. 含硫杯[4]芳烃银系配合物在织物上的抗菌性能[J]. 纺织学报, 2008, 29(5): 64-66.

LI Lei;ZHENG Limin;XIAN Chunying. Anti-bacterial performance of complexes of sulfur calix[4]arene with silver on fabrics[J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(5): 64-66.

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