纺织学报 ›› 2010, Vol. 31 ›› Issue (12): 73-77.

• 染整与化学品 • 上一篇    下一篇

二氧化硅溶胶在棉织物上吸附的动力学研究

宋林艳;马晓光;孟令翔;张莹   

  1. 天津工业大学改性与功能纤维天津市重点实验室
  • 收稿日期:2009-12-03 修回日期:2010-07-09 出版日期:2010-12-15 发布日期:2010-12-15
  • 通讯作者: 马晓光

Study on kinetics of silica sol adsorption in cotton fabrics

SONG Linyan;MA Xiaoguang;MENG Lingxiang;ZHANG Ying

  

  1. Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University
  • Received:2009-12-03 Revised:2010-07-09 Online:2010-12-15 Published:2010-12-15
  • Contact: Xiao-Guang MA

摘要:

为确定二氧化硅溶胶在棉织物上的吸附动力学,采用硅钼蓝法对其进行了研究。通过对Langmuir吸附模型和Freundlich吸附模型的比较,确定二氧化硅溶胶在织物上的吸附符合Langmuir吸附模型;通过对不同初始浓度溶胶液性能的测定,确定了其反应级数为一级;通过测定不同吸附温度下残液中硅浓度的方法得到了不同温度下的吸附速率常数,其活化能为13.56 kJ/mol,指前因子A0为1.287s-1。

Abstract:

Silicon-molybdenum blue method was employed to study the kinetics of silica sol adsorption in cotton fabrics. Comparative study of Langmuir and Freundlich adsorption models showed that the former model was more applicable to the silica adsorption in cotton fabrics. The reaction order of the adsorption was gotten by measuring the adsorption of sol solution with different initial concentrations, and it was first-order. Absorption rate constants were gotten by determining the concentration of silica in residue after adsorption at different temperatures. The activation energy was 13.56kJ/mol, and the preexponential factor A0 was 1.287s-1.

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