纺织学报 ›› 2010, Vol. 31 ›› Issue (6): 21-24.

• 纤维材料 • 上一篇    下一篇

热处理对PTFE牵伸性能的影响

郭占军;陈建勇;郭玉海;张华鹏;唐红艳   

  1. 浙江理工大学先进纺织材料与制备技术教育部重点实验室
  • 收稿日期:2009-05-25 修回日期:2009-10-16 出版日期:2010-06-15 发布日期:2010-06-15
  • 通讯作者: 唐红艳

Effect of heat treatment on properties of PTFE drawing

GUO Zhan-jun; CHEN Jian-yong;, GUO Yu-hai; ZHANG Hua-peng; TANG Hong-yan   

  1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-Tech University), Ministry of Education
  • Received:2009-05-25 Revised:2009-10-16 Online:2010-06-15 Published:2010-06-15
  • Contact: TANG Hongyan

摘要:

为用膜裂法制备高强度的PTFE(polytetrafluoroethylene聚四氟乙烯)长丝,以单向拉伸膜经膜裂制成的PTFE基带为原料,在加以适当张力的条件下,经不同加热温度及加热时间等处理后,再经加捻、热牵伸和热定型制备了PTFE长丝。采用SEM观察表面形貌,DSC测试熔融温度和结晶度,单纤维强力仪测试力学性能。结果表明,热处理使得PTFE长丝的结晶度降低,导致PTFE长丝断裂伸长率大幅提高,可以在很大程度上提高PTFE长丝的牵伸倍数,因此,在膜裂法制备PTFE长丝的前期进行适当的热处理,有利于加工成高强度、低细度的PTFE缝纫线。

Abstract:

One-way stretching PTFE(polytetrafluoroethylene)membrane which had been subjected to film-splitting was used as starting material for preparing high-tenacity PTFE filaments, the film-splitting process was adopted for manufacturing the filaments under proper tension, heat treatment including different temperatures and treatting durals, twisting, hot drawing and heat setting. The surface morphology of the resulting filaments was observed by SEM, the melting temperature and crystallinity were tested by differential scanning calorimeter, and mechanical properties were tested by single fiber tensile instrument. The results showed that the lower crystallinity of the filaments caused by heat-treatment led to great improvement of the elongation at break, thus enhancing the drawing ratio. Appropriate heat treatment before making PTFE filament with fiber-splitting method,therefore,is conducive to processing PTFE into sewing threads with high-tenacity and good fineness.

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