纺织学报 ›› 2012, Vol. 33 ›› Issue (1): 65-68.

• 染整与化学品 • 上一篇    下一篇

水性超细碳黑在N-甲基吗啉-N-氧化物溶液中的分散稳定性

张凯1,付少海2,田安丽2,王潮霞2,张霞2   

  1. 生态纺织教育部重点实验室(江南大学)
  • 收稿日期:2011-01-17 修回日期:2011-09-05 出版日期:2012-01-15 发布日期:2012-01-10
  • 通讯作者: 付少海 E-mail:shaohaifu@hotmail.com

Study on the dispersion stabilities of ultrafine carbon black in N-methyl morpholine-N-oxide solution

  • Received:2011-01-17 Revised:2011-09-05 Online:2012-01-15 Published:2012-01-10

摘要: 采用直接分散法和乳液聚合法分别制备了可用于Lyocell纤维原液着色用的水性分散型超细碳黑和包覆型超细碳黑,研究了不同方法得到超细碳黑的粒子大小以及在N-甲基吗啉-N-氧化物(NMMO)溶液中的分散稳定性。研究结果表明包覆型超细碳黑的平均粒径明显小于分散型超细碳黑,包覆型超细碳黑在NMMO溶液中的离心稳定性和耐热稳定性高于分散型超细碳黑,NMMO溶液中加入包覆型超细碳黑,其粘度明显下降,且加入量越大,粘度下降越明显。

Abstract: The waterborne ultrafine carbon black dispersion which was used in dope dyeing for Lyocell fiber were prepared by using direct dispersing method and emulsion polymerization method,respectively,and the particle size which obtained with different method and their dispersion stabilities in the N-methyl morpholine-N-oxide (NMMO) solution were further investigated.Experimental results revealed that emulsion polymerization method was suitable for preparation of nanoscale waterborne carbon dispersion.The centrifugal and antitemperature stabilities of encapsulated carbon in NMMO solution were obviously better than dispersing carbon.The apparent viscosity of NMMO solution decreased when added some encapsulated carbon, the more amount of encapsulated carbon added,the lower viscosity of NMMO solution was.

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