有机-无机复合膜导电织物的制备与表征

纺织学报 ›› 2012, Vol. 33 ›› Issue (5): 25-30.

有机-无机复合膜导电织物的制备与表征

卞学海,赵亚萍,孟云,蔡再生

东华大学生态纺织教育部重点实验室

收稿日期:2011-06-30 修回日期:2011-09-29 出版日期:2012-05-15 发布日期:2012-05-15
通讯作者: 蔡再生 E-mail:zshcai@dhu.edu.cn
基金资助:
教育部科学技术研究重点项目；中央高校基本科研业务费专项资金资助项目

Preparation and characterization of conductive fabric with organic-inorganic composite film

BIAN Xue-Hai, ZHAO Ya-Ping, MENG Yun, CAI Zai-Sheng

Key Laboratory of Science & Techonlogy of Eco-Textile, Ministry of Education, Donghua University

Received:2011-06-30 Revised:2011-09-29 Online:2012-05-15 Published:2012-05-15
Contact: CAI Zai-Sheng E-mail:zshcai@dhu.edu.cn

摘要/Abstract

摘要： 将粒径分布均匀的纳米Fe3O4颗粒、甲基三甲氧基硅烷均匀分散在由十二烷基苯磺酸钠在水中形成的微胶束中，在酸催化条件下，甲基三甲氧基硅烷在纳米Fe3O4颗粒表面发生水解缩合，制备了包覆均匀的纳米SiO2/Fe3O4磁流体。通过两步法在涤棉织物表面沉积纳米磁性颗粒与聚苯胺导电聚合物的复合膜以制备有机-无机复合膜导电织物，与聚苯胺单层膜导电织物相比，该有机-无机复合膜导电织物具有更低的电阻率，且电阻率随着纳米磁性颗粒含量的增加呈现减小趋势。

关键词: 纳米SiO₂∕Fe₃O₄磁流体, 聚苯胺单层膜, 有机-无机复合膜, 导电织物

Abstract: Fe3O4 nanoparticles with uniform size were dispersed in the sodium dodecyl benzenesulfonate (SDBS) micelles together with methyltrimethoxysilane (MTMOS). In the presence of hydrochloric acid nano-scale SiO2/Fe3O4 magnetic fluids were prepared by the hydrolysis and polycondensation process of MTMOS on the surface of Fe3O4 nanoparticles. Conductive textiles based on organic-inorganic composite films with polyaniline and nano-magnetic particles were prepared by two-step method, which had lower resistivity compared with conductive textiles based on polyaniline single-layer film, and the resistivity decreased with the addition amount of nano-magnetic particles.

Key words: nano-scale SiO₂∕Fe₃O₄magnetic fluid , polyaniline single-layer film , organic-inorganic composite film , conductive fabric

中图分类号:

TS 195

卞学海, 赵亚萍, 孟云, 蔡再生. 有机-无机复合膜导电织物的制备与表征[J]. 纺织学报, 2012, 33(5): 25-30.

BIAN Xue-Hai, ZHAO Ya-Ping, MENG Yun, CAI Zai-Sheng. Preparation and characterization of conductive fabric with organic-inorganic composite film[J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(5): 25-30.

参考文献

相关文章 7

[1]	张舒缪旭红 RAJI Rafiu King 孙婉. 经编导电针织物的应变—电阻传感性能[J]. 纺织学报, 2018, 39(02): 73-77.
[2]	乐珮珮王少伟李晓强葛明桥. 氧化还原一步法制备聚苯胺/银复合导电织物[J]. 纺织学报, 2014, 35(4): 37-0.
[3]	徐文龙，熊杰，徐勤，刘志才，焦玉雪，陈虎. 化学镀银涤纶织物的制备及其性能[J]. 纺织学报, 2011, 32(9): 42-46.
[4]	狄剑锋;唐俊云. 聚苯胺/锦纶/氨纶复合导电织物的制备工艺[J]. 纺织学报, 2011, 32(4): 43-47.
[5]	唐俊云;狄剑锋. 聚苯胺复合导电织物的研究进展[J]. 纺织学报, 2011, 32(3): 148-152.
[6]	王进美;朱长纯;李毅;胡军岩. 纳米管状聚苯胺织物涂层与导电及微波屏蔽性能[J]. 纺织学报, 2005, 26(4): 10-13.
[7]	南燕;张燕;施楣梧. 用非金属导电纤维开发纯涤纶抗静电织物[J]. 纺织学报, 2001, 22(02): 4-6.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed