甲基丙烯酰胺接枝蚕丝的活性染料染色性能

纺织学报 ›› 2012, Vol. 33 ›› Issue (6): 59-65.

甲基丙烯酰胺接枝蚕丝的活性染料染色性能

钱红飞,方帅军,刘蒋英,屠海镇

绍兴文理学院纺织服装学院

收稿日期:2011-08-15 修回日期:2012-03-01 出版日期:2012-06-15 发布日期:2012-06-04
通讯作者: 钱红飞 E-mail:qhf@usx.edu.cn
基金资助:
浙江省自然科学基金资助项目；浙江省优先主题重大工业项目

Dyeing properties of methacrylamide-grafted silk with reactive dyes

QIAN Hong-Fei, FANG Shuai-Jun, LIU Jiang-Ying, TU Hai-Zhen

School of Textile Engineering and Apparel Design, Shaoxing University

Received:2011-08-15 Revised:2012-03-01 Online:2012-06-15 Published:2012-06-04

摘要/Abstract

摘要： 为了较好地了解甲基丙烯酰胺单体接枝蚕丝的染色性能，作者通过热综合、红外光谱和X-衍射这三种方法，对增重蚕丝与未增重蚕丝进行分析。在此基础上，详细研究其活性染料的上染与固色速率曲线、提升性等染色性能，并与未增重蚕丝作比较。结果表明，接枝增重并未改变纤维内部的晶型结构和丝素主链的分子结构，而结晶度有所降低，对活性染料的吸附性和提升性有所降低。

关键词: 接枝蚕丝 , 甲基丙烯酰胺 , 结构分析 , 活性染料 , 染色性能

Abstract: In order to understand the dyeing properties of grafted silk with methacrylamide. The authors analyzed the structure of both the grafted and non-grafted silk by means of the three methods such as TG/DTA, FT-IR spectroscopy and X-ray diffraction. On these bases, their dyeing properties of reactive dyes including mainly the dyeing fixation rate curve and build up property was investigated in detail, and compared with each other. The results indicated that the graft treatment remained the crystalline and molecular structure of silk fibroin unchanged, but the crystallinity of fiber, adsorption and the build up property of reactive dyes was also reduced after weighting.

Key words: grafted silk , methacrylamide , structural nanlysis , reactive dye , dyeing property

中图分类号:

TS 193.1

钱红飞, 方帅军, 刘将英, 屠海镇. 甲基丙烯酰胺接枝蚕丝的活性染料染色性能[J]. 纺织学报, 2012, 33(6): 59-65.

QIAN Hong-Fei, FANG Shuai-Jun, LIU Jiang-Ying, TU Hai-Zhen. Dyeing properties of methacrylamide-grafted silk with reactive dyes[J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(6): 59-65.

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