纺织学报 ›› 2014, Vol. 35 ›› Issue (12): 17-0.

• 纤维材料 • 上一篇    下一篇

接枝阳离子茧衣对印染废水中染料的吸附

  

  • 收稿日期:2013-12-16 修回日期:2014-09-16 出版日期:2014-12-15 发布日期:2014-12-16
  • 通讯作者: 张光先 E-mail:zgx656472@sina.com

Study on dye adsorption of grafted cationic cocoon floss in printing and dyeing wastewater

  • Received:2013-12-16 Revised:2014-09-16 Online:2014-12-15 Published:2014-12-16
  • Contact: ZHANG Guang-Xian E-mail:zgx656472@sina.com

摘要:  研究了2,3-环氧丙基三乙基氯化铵对茧衣接枝阳离子的改性,并研究了改性茧衣对3支活性染料、2支酸性染料和1支直接染料的吸附作用。红外光谱分析表明,2,3-环氧丙基三乙基氯化铵主要接枝在茧衣的氨基上;粒子表面电位分析表明,改性茧衣表面电位从-56.2 mV提高到-23.2 mV;改性茧衣对废水中染料的吸附速率很快,大量吸附都在前2~4 min完成;改性茧衣对酸性染料、直接染料的脱色率很高,对活性染料的脱色率稍弱;改性茧衣阳离子接枝率越高,对染料的吸附量越大。接枝率为0.31%~2.70%的改性茧衣对酸性染料、直接染料及活性染料的平衡吸附量分别为16.0%~81.3%(g/g)、31.2%~50.6%(g/g)、5.16%~32.4%(g/g)。由此表明,改性茧衣对染料具有很强的吸附能力,是一种具有潜力的印染废水处理方法。

Abstract: Abstract The study of cationic grafting to cocoon floss with 2,3-epoxypropyl triethylammonium chloride(GTA) and the dye absorption of the modified cocoon floss that conclude three branches of reactive dyes, two branches of acid dyes and one branch of direct dye. Through the infrared spectrum of modified cocoon floss, it shows that 2,3-epoxypropyl triethylammonium chloride is mainly grafted on the amino of cocoon floss. And the particle surface potential analysis shows that the value of modified cocoon's surface potential increases from -56.2 mV to -23.2 mV. Also the dye adsorption rate of modified cocoon floss is very fast and the value of absorption is big, especially a large number of the adsorption is completed in the first few minutes. And the decolorization rates of acid and direct dyes are bigger than reactive dyes. The cationic grafting rate of modified cocoon floss is higher, the dye adsorption capacity is greater. For example, when the grafting rate of modified cocoon floss is 0.31%~2.70%, the equilibrium adsorption values of acid dyes, direct dyes and reactive dyes are 16.0%~81.3% (g/g), 31.2%~50.6% (g/g) and 5.16%~32.4% (g/g), which shows that the modified cocoon floss has a very strong ability to absorb dyes. And also, this is a potential method of the treatment of printing and dyeing wastewater.

中图分类号: 

  • 中图分类号:S886.9
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