磁控溅射纳米纤维基银膜的结构和性能

纺织学报 ›› 2014, Vol. 35 ›› Issue (4): 32-0.

磁控溅射纳米纤维基银膜的结构和性能

李超荣舒顺新谢勇刘秋艳

浙江理工大学先进纺织材料与制备技术教育部重点实验室

收稿日期:2013-03-20 修回日期:2013-11-18 出版日期:2014-04-15 发布日期:2014-04-14
通讯作者: 李超荣 E-mail:crli@zstu.edu.cn
基金资助:
国家自然科学基金资助项目

Structure and properties of Ag coatings on nanofibers prepared by magnetron sputtering

Received:2013-03-20 Revised:2013-11-18 Online:2014-04-15 Published:2014-04-14

摘要/Abstract

摘要： 在室温条件下采用直流磁控溅射方法，在醋酸纤维素(CA)纳米纤维表面沉积纳米银(Ag)薄膜，采用扫描电子显微镜(SEM)和透射电子显微镜(TEM)对不同溅射功率的纳米银膜的形貌和微结构进行表征；利用X射线衍射分析了纳米银膜的结晶状态；同时研究了在不同溅射功率条件下制备的沉积纳米Ag膜复合纳米纤维的光学透射性能。实验结果表明：纳米结构银薄膜由极其微小的均匀性较好的粒子组成，随着溅射功率的增加，组成纳米Ag薄膜的Ag粒子尺寸增大，薄膜的致密性和均匀性增加；制备的Ag薄膜均呈面心立方的多晶结构，并且结晶性能随着溅射功率的增加而逐渐增加，抗紫外线透射能力明显增强。

关键词: 磁控溅射, 纳米纤维, 银薄膜, 透光率

Abstract: Nanoscale silver (Ag) functional films were prepared on the surface of cellulose acetate nanofiber at room temperature by DC magnetron sputtering process. The surface morphology and microstructure of silver films were characterized by scanning electron microscope and transmission electron microscopy. X-ray diffraction measurements were carried out to examine crystalline state of silver films.The transmission properties of the nanocomposite fiber with silver films prepared under different sputtering power were analyzed. The results showed that silver films was formed by nanosize and homogeneous particles. It showed that increase in sputtering power lead to increase in the dimension of silver particles as well as the evenness and compactness of films. The results showed that the particle diameters, crystal properties and ultraviolet absorption gradually increase along with the increase of sputtering power. The as-prepared silver films form face-centered cubic of polycrystalline structure. The ultra-violet(UV) absorption by nanofiber with silver films was enhanced by increasing the sputtering power.

Key words: magnetron sputtering, nanofiber, silver coating, transmisivity

李超荣舒顺新谢勇刘秋艳. 磁控溅射纳米纤维基银膜的结构和性能[J]. 纺织学报, 2014, 35(4): 32-0.

参考文献

[1] XIONG Y Q, WU H, GUO Y, et al. Preparation and characterization of nanostructured silver films deposited by radio frequency magnetron sputtering[J].Thin Solid Films, 2000(300-303): 602-606.
[2] 严国良, 苏英.抗菌卫生纺织品的现状与展望[J].金山油化纤，2001,(3): 37-40.
YANG Guoliang, SU Ying. Current status and prospect of antibacterial sanitary textile[J]. Jinshan Oil Chemical Fiber, 2001, (3): 37-40.
[3] 阎均, 龚羽.抗菌织物及其抗菌性能的评价[J]. 上海纺织科技, 2005, 33(3): 62-64.
YANG Jun, GONG Yu. Anti-bacterial fabric and the evaluation of its property[J]. Shanghai Textile Science and Technology, 2005, 33(3): 62-64.
[4] JIANG S Q, NEWTON E, YUEN C W M, et al. Chemical silver piating and its application to textile fabric design[J]. Journal of Applied Polymer Science, 2005, 96: 919-926.
[5] Gould P. Textiles gain intelligence[J]. Materials Today, 2003, 6(10): 38-43.??
[6] 洪剑寒, 王鸿博, 魏取福等. 磁控溅射法制备纳米Ag薄膜的AFM分析和导电性能[J].纺织学报, 2006, 27(9): 14-17.
HONG Jianhai, WANG Hongbo, WEI Qufu, et al. AFM analysis and conductivity of nano-structured silver films deposited by magnetron sputtering[J]. Journal of Textile Research, 2006, 27(9): 14-17.
[7]王鸿博, 赵晓燕, 洪剑寒等. PET基纳米结构Ag薄膜结构及导电性能[J].纺织学报, 2007, 28 (2): 52-55.
WANG Hongbo, ZHAO Xiaoyan, HONG Jianhan, et al. Microstructure and conductivity of nanostructured silver films deposited on PET fabric[J]. 2007, 28(2): 52-55.
[8] 王鸿博, 何艳丽, 高卫东等. PLA基纳米银薄膜的抗菌性能[J].纺织学报, 2008, 29(6): 52-55.
WANG Hongbo, HE Yanli, GAO Weidong, et al. Antibacterial properties of PLA nanwovens deposited with nanostructured silver films[J]. Journal of Textile Research, 2008, 29（6）: 52-55.
[9] 赵锡钦.溅射镀膜技术的应用[J].电子机械工程, 1999, 79(3): 58-61.??
ZHAO Xiqin. Application of sputtering coating technology [J]. Electronic mechanical engineering, 1999, 79(3): 58-61.?
[10] XU Y, Wu N, WEI Q F, PI X B. Preparation and the light transmittance of TiO2 deposited fabrics[J]. Journal of Coatings Technology and Research, 2009, 6 (4): 549-555.
[11] SUN J C, YANG T P, DU G T, et al. Influence of annealing atmosphere on ZnO thin films grown by MOCVD[J]. Applied Surface Science, 2006, 253: 2066-2070.??
[12] WEI Q F, XIAO X L, HOU D Y, et al. Characterization of nonwoven material functionali zed by sputter coating of copper[J].Surface Coatings Technology, 2008, 202: 2535-2539.
[13] PETMCCIOLI M, FENICE M, PICCIONI P, et a1. Efects of Stirrer speed and Bufering Agents on the Production of Glucose Oxidase and Catalase by Penicillium variable in Benehtop Bioreactor[J]. Enzyme and Microbial Technology, 1995, 17: 336-339.
[14] NISHIKAWA Y, KAWATA Y, NAGAI J. Efect of Triton X-10 on Catalase Production by Aspergillusterreus 06123[J]. Journal of Fermentation and Bioengineering, 1993, 76: 235-236.

相关文章 15

[1]	吴小娟余妙晶舒慧郑怡筱葛烨倩 . 过温保护层合纳米纤维隔膜的制备及其性能[J]. 纺织学报, 2018, 39(07): 21-26.
[2]	陈洪立焦晓宁柯鹏. 取向增强复合锂离子电池隔膜的制备及其性能[J]. 纺织学报, 2018, 39(07): 8-14.
[3]	张博亚李佳慧张如全李建强. 静电纺聚丙烯腈/硫酸铜纳米纤维膜的制备及其性能[J]. 纺织学报, 2018, 39(07): 15-20.
[4]	王航庄旭品董锋石磊康卫民徐先林程博闻. 溶液喷射纺纳米纤维制备技术及其应用进展[J]. 纺织学报, 2018, 39(07): 165-173.
[5]	王迎杨云魏春艳宋欢季英超孙玉雍张欣. 沉积静电纺聚丙烯腈纳米纤维膜窗纱的制备及其性能[J]. 纺织学报, 2018, 39(04): 14-18.
[6]	靳世鑫辛斌杰郑元生. 静电纺丝法宏量制备纳米纤维的研究进展[J]. 纺织学报, 2018, 39(03): 175-180.
[7]	王永鹏刘梦竹路大勇. 用静电纺丝法制备可交联高性能聚合物纳米纤维[J]. 纺织学报, 2018, 39(01): 6-10.
[8]	李树锋刘高华谢小军韩永兴张艳程博闻. 同轴静电纺丝参数对聚丙烯腈中空碳纳米纤维形态与炭化收率的影响[J]. 纺织学报, 2017, 38(12): 1-6.
[9]	康卫民范兰兰邓南平何宏升鞠敬鸽程博闻 . 静电纺多孔碳纳米纤维制备与应用研究进展[J]. 纺织学报, 2017, 38(11): 168-176.
[10]	李晴碧刘琴顾迎春彭旭李静静蒋洁陈胜. 复合静电纺超细聚丙烯腈纳米纤维的制备[J]. 纺织学报, 2017, 38(11): 16-21.
[11]	贾琳王西贤张海霞覃小红. 防紫外线聚丙烯腈复合纳米纤维的制备及其性能[J]. 纺织学报, 2017, 38(10): 1-6.
[12]	陈锋姬忠礼齐强强. 静电纺聚丙烯腈纳米纤维复合滤材的制备及其气液过滤性能[J]. 纺织学报, 2017, 38(09): 8-13.
[13]	贾琳王西贤张海霞覃小红. 聚丙烯腈/二氧化钛纳米纤维的紫外线防护性能[J]. 纺织学报, 2017, 38(07): 18-22.
[14]	王遥朱青胡春艳王栋阎克路. 改性聚乙烯醇-乙烯共聚物纳米纤维膜对重金属离子的吸附性能[J]. 纺织学报, 2017, 38(06): 11-16.
[15]	王利君熊杰骆菁菁赵兴艳赵新飞. 聚乳酸-聚己内酯/丝素蛋白三元复合纳米纤维膜支架的结构与性能[J]. 纺织学报, 2017, 38(05): 8-13.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed