纺织学报 ›› 2015, Vol. 36 ›› Issue (10): 12-16.

• 纤维材料 • 上一篇    下一篇

壳聚糖纤维的热稳定性和燃烧性能

  

  • 收稿日期:2014-10-27 修回日期:2015-04-18 出版日期:2015-10-15 发布日期:2015-10-12

Thermal stability and combustion behavior of chitosan fiber

  • Received:2014-10-27 Revised:2015-04-18 Online:2015-10-15 Published:2015-10-12

摘要:

为了解壳聚糖纤维的热稳定性和燃烧性能,采用热重(TG)法测试了纤维的热学特征,对纤维耐热性能和极限氧指数进行了测试,用红外光谱法分析了受热后纤维结构的变化。结果表明:壳聚糖纤维的TG曲线有三个失重台阶,在270℃左右开始热分解,900℃分解完全,残炭量8.6%;纤维热稳定性好,耐湿热性优于耐干热性,随干热和湿热处理温度和时间的增加,纤维性能呈下降趋势,断裂伸长率下降幅度大于断裂强力;壳聚糖纤维极限氧指数38%,燃烧特征属于难燃纤维。

Abstract:

TG was used to analyze the thermal stability and combustion behavior of chitosan fiber, heat-resistance and limiting oxygen index of chitosan fiber were tested, change of the fiber’s microstructure after heated was investigated using infrared spectrometry. The result showed that the chitosan fiber’s TG curves appear three weightloss bands, it begins to decompose at about 270℃and decomposes completely at 900℃ ,the amount residual carbon is 8.6%.The thermal stability is also good enough for demand of chitosan fiber, its wet heat resistance is better than dry heat resistance. Fiber’s properties decrease with the increase of heating temperature and time, the greater decrease in breaking elongation than in tensile strength. The limiting oxygen index of chitisan fiber is 38%,the combustion characteristics are similar with that of burning-resisting fiber.

中图分类号: 

  • TS 102.212
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