含氟聚丙烯酸酯乳液整理剂的性能及其应用

纺织学报 ›› 2016, Vol. 37 ›› Issue (09): 100-105.

含氟聚丙烯酸酯乳液整理剂的性能及其应用

收稿日期:2015-10-12 修回日期:2016-03-16 出版日期:2016-09-15 发布日期:2016-09-19

Preparation and application of fluorine-containing acrylate copolymer emulsion as finishing agent

Received:2015-10-12 Revised:2016-03-16 Online:2016-09-15 Published:2016-09-19

摘要/Abstract

摘要：

为了探讨含氟聚合物在亚麻织物上的应用效果，以甲基丙烯酸十二氟庚酯（G04）为改性单体，丙烯酸正丁酯（BA）、甲基丙烯酸甲酯（MMA）为软、硬单体，丙烯酸（AA）为功能单体，采用半连续种子乳液聚合制备氟改性的丙烯酸酯共聚物乳液，并将其用于整理亚麻织物。利用红外光谱仪、透射电子显微镜、粒径分析仪、接触角测量仪等对产物结构与性能进行表征与分析，探讨经其整理后亚麻织物透湿透气性及断裂强力的变化。结果表明：所得含氟共聚乳液胶粒呈核壳结构，其粒径属于纳米级；经其整理的亚麻织物对水接触角可达130°，且织物断裂强力有所增加，透湿透气性略有降低。

关键词: 含氟聚丙烯酸酯, 核壳聚合, 亚麻织物, 疏水性, 织物整理

Abstract:

In order to explore the application effects of fluoropolymer on linen fabric, a fluorine-containing acrylate copolymer emulsion was prepared by semi-continuous seeded emulsion copolymerization using dodecafluloroheptry methacrylate (G04) as modified monomer, butylacrylate (BA) and methylacrylate (MMA) as soft and bard monomer, respectively, and acrylic acid sa functional monomer; ana it was applied to finishing linen fabric. Structure and properties of the product were characterized and analyzed by FTIR, TEM, PSD and CA tester, respectively. Water and air permeability and breaking strength of the treated fabric were investigated. The result showed that the obtained fluorine-containing acrylate copolymer emulsion had a core-shell structure, and the microsphere size was at nanometer. After the linen fabric was treated with fluorine-containing copolymer, the contact angle to water was up to 130°, and the breaking strength of fabric was increased. The water and air permeability of fabric decreased slightly.

Key words: fluorine-containing acrylate, core-shell polymerization, linen fabric, hydrophobicity, fabric finishing

隋智慧杨康乐陈杰赵欣. 含氟聚丙烯酸酯乳液整理剂的性能及其应用[J]. 纺织学报, 2016, 37(09): 100-105.

参考文献

相关文章 15

[1]	高树珍迟文锐王兵兵汪亮. 磷-氮耐氯阻燃整理剂的合成及其应用[J]. 纺织学报, 2018, 39(06): 101-105.
[2]	张严李永强邵建中邹超谭道明 . 氦等离子体接枝聚合棉织物的疏水改性[J]. 纺织学报, 2016, 37(07): 99-103.
[3]	侯彦敏吴明华余德游鲍进跃. 功能石墨烯改性水性聚氨酯及其性能[J]. 纺织学报, 2015, 36(10): 80-0.
[4]	蒋亚君邱莹丹王霁龙章倩邱夷平. 应用1-辛烯涂层与常压等离子体处理的苎麻纤维疏水性能改性[J]. 纺织学报, 2015, 36(06): 7-0.
[5]	王晓宋志云郝军黄成徐明媚. 紫外光接枝丙烯酸亚麻织物阳离子染料染色热力学[J]. 纺织学报, 2012, 33(12): 49-52.
[6]	王雪;金剑;肖长发. 疏水改性聚对苯二甲酸乙二醇酯的合成与表征[J]. 纺织学报, 2011, 32(4): 12-17.
[7]	王晓;马海涛;李淳;杨启鹏;刘小东. 紫外光接枝丙烯酸亚麻织物的服用性能[J]. 纺织学报, 2010, 31(8): 73-77.
[8]	杨金库;董永春;郭瑾;刘春燕. 低温制备纳米TiO2溶胶整理棉织物对染料的降解[J]. 纺织学报, 2010, 31(7): 69-73.
[9]	安秋凤;付永山;许永静. 氟代聚丙烯酸酯乳液的制备及应用[J]. 纺织学报, 2008, 29(8): 81-84.
[10]	冯家好;张华.;李俊. 液氨/交联处理后亚麻织物的服用性能[J]. 纺织学报, 2008, 29(8): 63-66.
[11]	潘文艳;刘彦军;孙祥山;王伟. 乳液型含氟织物整理剂的性能及应用[J]. 纺织学报, 2007, 28(9): 80-83.
[12]	纵瑞龙;王建明;郝新敏. 染色工艺对亚麻织物染色性能的影响[J]. 纺织学报, 2007, 28(1): 73-76.
[13]	于娜;李淳. 等离子体引发亚麻接枝改性方法的优化设计[J]. 纺织学报, 2006, 27(3): 86-89.
[14]	崔毅华. 气囊材料及其设计的研究[J]. 纺织学报, 2004, 25(06): 133-134.
[15]	黄故. 高压水流整理对织物透气性和刚度的影响[J]. 纺织学报, 2004, 25(06): 17-18.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed