纺织学报 ›› 2016, Vol. 37 ›› Issue (09): 90-93.

• 染整与化学品 • 上一篇    下一篇

酯型儿茶素的热稳定性及其上染蚕丝效果

  

  • 收稿日期:2015-06-09 修回日期:2016-05-26 出版日期:2016-09-15 发布日期:2016-09-19

Heat stability of estercatechins and their dyeing effects on silk

  • Received:2015-06-09 Revised:2016-05-26 Online:2016-09-15 Published:2016-09-19

摘要:

为阐明酯型儿茶素的氧化聚合作用及其对蚕丝染色效果的影响,采用超高效液相色谱串联四极杆飞行时间质谱分析了表没食子儿茶素没食子酸酯(EGCG)、没食子儿茶素没食子酸酯(GCG)和表儿茶素没食子酸酯(ECG)等儿茶素染液的热稳定性。结果表明:儿茶素受热不稳定,转化程度也有差异;单一成分时,ECG的转化率最高,GCG的最低;多种成分共存时,GCG和ECG的协同效应较强,转化率相近。研究EGCG、GCG和ECG在蚕丝上的着色效果发现:EGCG、GCG 和ECG等比例染色时,蚕丝对酯型儿茶素的吸附率为ECG>GCG>EGCG;不同比例混染时,蚕丝对酯型儿茶素的吸附率相近,EGCG与GCG的着色能力较ECG强。可见ECG的热稳定性不会影响蚕丝的吸附率,且其着色程度较浅,因而更适于用作植物染色剂。

关键词: 酯型儿茶素, 热稳定性, 蚕丝, 染色

Abstract:

In order to illustrate the oxidation and polymerization of estercatechins and their effects on the coloring performanceof solk, the heat stability of EGCG,GCG and EGCG was analyzed by UPLC-Q-TOF/MS. The results showed that when estercatechins were heated, their conversion rates were different. Moreover, the conversion rate of ECG was highest and GCG was the lowest when one component existed. However, when two or more ingredients coexist, their synergistic effects beween GCG and ECG were stronger and theru conversion rates were similar. The dyeing effects of EGCG, GCG and ECG in silk were also analyzed, It is  found that the catechin absorpted rate of silk was ECG>GCG> EGCG when dyeing at the same proportion, and the catechin absorpted rate of silk was nearer. Besides, it was proved that the coloring strength of EGCG and GCG were stronger when dyeing with different proportions. Through comparing, ECG was more suitable to be used as plant dyeing agent because its heat stability would not affect the adsorption rate, and its coloring degree was lower.

Key words: estercatechins, heat stability, silk, dye

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