纺织学报 ›› 2017, Vol. 38 ›› Issue (04): 80-84.doi: 10.13475/j.fzxb.20160404905

• 染整与化学品 • 上一篇    下一篇

姜黄染色织物的pH值敏感变色性能

  

  • 收稿日期:2016-04-18 修回日期:2017-01-11 出版日期:2017-04-15 发布日期:2017-04-17

Discoloration property for pH-sensitivity of fabric dyed by turmeric

  • Received:2016-04-18 Revised:2017-01-11 Online:2017-04-15 Published:2017-04-17

摘要:

为开发pH值敏感变色织物,研究了pH值对姜黄染色织物颜色变化的影响,利用高效液相色谱法对姜黄提取物主要成分进行分析,测试了不同pH 值条件下姜黄提取液的吸收光谱、姜黄染色织物的上染率、K/S值和染色牢度,利用颜色特征值对姜黄染色织物在不同pH值下的变色情况进行表征。结果表明:植物染料姜黄的主要成分为姜黄素,姜黄素分子在碱性条件下会电离成阴离子,引起颜色变化;随溶液pH 值的增加,姜黄提取液的吸收峰会产生红移,且吸收强度增加,提取液在酸性条件时呈黄色,当提取液pH 值大于8 时,溶液呈红棕色;姜黄对丝织物的染色性能好于棉织物。在pH值由中性向碱性转变时,姜黄染色织物会产生显著的变色,染色织物色相值变小,颜色由黄色域向红色域转变。

关键词: 变色纺织品, 姜黄, 植物染料, pH敏感织物

Abstract:

In order to develop pH-sensitive color changing fabrics, the influence of pH on the color change of fabrics of fabrics dyed by turmeric were studied. The main chemical compositions of dye extracted from turmeric were analyzed by high performance liquid chromatography (HPLC). The absorption spectra of turmeric solution at different pH values were tested. The dye uptake and the color fastness of fabric dyed by trumeric were measured. The color changing properties at different pH values of samples of samples dyed by turmeric were evaluation by means of the values of CIELAB. The results show that the main chemical component of vegetable dye extracted from turmeric is curcumin. The curcumin molecules are ionized into anions under alkaline conditions, and the color of curcumin changes. With the pH value of the solutions increasing, the absorption peaks of the trumeric extraction solution have red shift and the absorption intenstity increases. The color of the turmeric extraction solution is yellow under acid condition. When the pH wvlue of the cxtracted liquid is greater than 8, the solution color is reddish brown. The dyeing property of curcumin for silk fabric is better than for cotton fabric. The color of fabric dyed by curcumin has a significant change when the pH walue is changed from neutrality to alkality. The hue value becomes lower, and the fabric color changes from yelow to red.

Key words: color changing fabric, turmeric, vegetable dye, pH-sensitive color changing

[1] 陈莉 张蓓. 植物染料黄芩的化学成分及其防紫外线性能[J]. 纺织学报, 2016, 37(4): 86-0.
[2] 刘剑 陈克 周旸 赵丰 彭志勤 胡智文. 微型光纤光谱技术在植物染料鉴别与光照色牢度评估中的应用[J]. 纺织学报, 2014, 35(6): 85-0.
[3] 刘祥霞 杜文琴 吴翠. 植物染料分子状态与其上染关系[J]. 纺织学报, 2013, 34(9): 84-0.
[4] 侯秀良;赵宽;赵国英;李昭楠;胡晓峰. 采用叶绿素铜钠盐染绿色毛织物的方法[J]. 纺织学报, 2010, 31(6): 95-99.
[5] 周家伟;程万里. 环氧交联剂EH对苏木植物染料的固色作用[J]. 纺织学报, 2006, 27(4): 39-43.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!