纺织学报 ›› 2017, Vol. 38 ›› Issue (05): 93-97.doi: 10.13475/j.fzxb.20160706006
摘要:
为解决自清洁纺织品的耐久性问题,简化加工工艺,以丙烯酸树脂与纳米TiO2 为原料,采用不同的加工工艺,在涤纶机织物表面进行涂层整理,制备了具有自清洁性能的涂层织物,用分解亚甲基蓝的方法对涂层织物的自清洁性能进行表征。采用扫描电子显微镜(SEM)和能谱仪(EDS)对涂层织物的表面形貌及元素组成进行分析。结果表明:不同涂层工艺会影响织物的自清洁效果;一定范围内,涂层织物的自清洁性能随纳米TiO2 质量浓度的增加而提高,当TiO2 质量浓度达到30g/L 时,继续增大TiO2质量浓度,自清洁效果提升不明显;在经过不同类型以及不同次数的摩擦牢度测试后,自清洁效果保持良好。
[ 1] 杜文琴. 荷叶效应在拒水自洁织物上的应用[J]. 印染,2001,09:36-37+43-0. Du Wenqin. Lotus effect in the application of repellent self-cleaning fabrics[J]. Dyeing and Finishing, 2001,09:36-37+43-0. [ 2] 沈艳琴,武海良,吴长春等.纺织装饰墙布结构设计与性能分析[J].西安工程大学学报,2008,22(3):269-274. Shen Yanqin,Wu Hailiang,Wu Changchun. Structure design and performance analysis of textile wall paper[J]. Journal of Xi'an Polytechnic University, 2008,22(3):269-274. [ 3] Nagappan Saravanan, Park Ji Hye, Sung, A Reum等. Superhydrophobic hybrid micro-nanocomposites for non-stick and self-cleaning coatings [J].COMPOSITE INTERFACES,2014,21(7):597-609. [ 4] Zhanglian Xu, Miyazaki K., Hori T. Fabrication of polydopamine-coated superhydrophobic fabrics for oil/water separation and self-cleaning[J].Applied Surface Science,2016,370: 243-51. [ 5] Fujishima A,Honda K.Electrochemical Photolysisof Water at a Semiconductor Elect rode[J].Nature,1972,238 ( 5358) : 37-38. [ 6] Carey J H, Lawrence J, Tosine H M. Photodechlorination of PCB’s in the presence of titanium dioxide in aqueous suspensions [J]. Bull of Environ. Contam. Toxical,1976,16(6):697-701. [ 7] 朱琳芳.纳米二氧化钛的改性及其降解有机物的研究[D].河南师范大学,2010. Zhu Linfang. The research of nanometer titanium dioxide modification and the degradation of organics[D]. Henan Normal University,2010. [ 8] Yuranova T, Mosteo R, Bandara J等. Self-cleaning cotton textiles surfaces modified by photoactive SiO2/TiO2 coating[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006,244(1-2): 160-167. [ 9] Zohoori S, Karimi L, Nazari A. Photocatalytic Self-cleaning Synergism Optimization of Cotton Fabric using Nano SrTiO3 and Nano TiO2[J]. FIBRES & TEXTILES IN EASTERN EUROPE,2014,22(2):91-95. [10] Xu Zhanglian, Miyazaki K, Hori T. Fabrication of polydopamine-coated superhydrophobic fabrics for oil/water separation and self-cleaning[J]. APPLIED SURFACE SCIENCE, 2016,370:243-251. [11] 叶凤英. 纳米TiO2及其复合水溶胶的制备及在纺织品功能整理中的应用研究[D].上海工程技术大学,2014. Ye Fengying. The preparation and functional finishing in textiles of nano TiO2 and compound hydrosol[D]. Shanghai University Of Engineering Science,2014. [12] 许静. 纳米二氧化钛的低温制备及其在织物上的应用[D].东华大学,2009. Xu Jing. Low temperature preparation of nano titanium dioxide and its application on the fabrics[D].Donghua University,2009. [13] Choi T, Kim JS, Kim JH. Transparent nitrogen doped TiO2/WO3 composite films for self-cleaning glass applications with improved photodegradation activity [J]. ADVANCED POWDER TECHNOLOGY,2016,27(2):347-353. [14] PathanH M, KimW Y, Jung K D, et al .A chemical route to room-temperature synthesis of nanocrystalline TiO2 thin films[ J] .Appl Surf Sci ,2005 ,246:72 -76. [15] Mane R S , Lee W J , Pathan H M , et al. Nanocrystalline TiO2-ZnO thin films Fabrication and application to dye-sensitized solar cells[ J]. JPhys Chem B, 2005 , 109 :24254 -24259. [16] Janus Magdalena, Zatorska Justyna, Czyzewski Adam, Bubacz Kamila, Kusiak-Nejman Ewelina, Morawski Antoni W. Self-cleaning properties of cement plates loaded with N,C-modified TiO2 photocatalysts[J]. APPLIED SURFACE SCIENCE, 2014,330:200-206. [17] Zhang Baolong, Chen Baishun, Shi Keyu, etal.Preparationand characterization of nano crystalgrain TiO2 porousmicrosphere [J] . Applied Catalysis B Enviromental, 2003(40):253 -258. [18] Kale, Bandu Madhukar et al. Coating of cellulose-TiO2 nanoparticles on cotton fabric for durable photo catalytic self-cleaning and stiffness[J]. Carbohydrate polymers,2016,150:107-13. |
[1] | 王嘉欣 田秀枝 蒋学 王鸿博 高卫东. 二醛 β-环糊精/壳聚糖改性对涤纶织物亲水性能的影响[J]. 纺织学报, 2018, 39(07): 82-88. |
[2] | 秦传香 鲍志敏 戴礼兴 梅锋. 新型萘酰亚胺类荧光染料的合成及其染色应用[J]. 纺织学报, 2018, 39(07): 74-81. |
[3] | 蓝舟 瞿建刚 王春梅 徐俊芳 钱佳琪. 纤维基钒酸铋的制备及其光催化性能[J]. 纺织学报, 2018, 39(06): 89-95. |
[4] | 易兵 胡倩 杨辉琼 阳海 李良臣 区泽棠. 酸性红37光催化降解动力学的响应曲面法优化及其转化机制[J]. 纺织学报, 2018, 39(06): 81-88. |
[5] | 吕赛龙 霍瑞亭 贾国强. 光催化自清洁纺织品的制备及其性能[J]. 纺织学报, 2018, 39(05): 87-91. |
[6] | 李冰蕊 潘家豪 王挺 吴礼光 许智勇. 用吸附相反应技术制备弱光响应的铈掺杂TiO2复合光催化剂[J]. 纺织学报, 2018, 39(05): 67-73. |
[7] | 郑君红 李亮 刘让同 张丹. 羊毛角蛋白的制备及其对涤纶织物的整理[J]. 纺织学报, 2018, 39(03): 92-97. |
[8] | 卢声 林杰 路艳华 黄凤远 程德红. 用含三嗪结构苯基磷酸酯的涤纶织物阻燃整理[J]. 纺织学报, 2018, 39(03): 98-102. |
[9] | 李庆 张莹 樊增禄 朱炜. Cu-有机骨架对染料废水的吸附和可见光降解[J]. 纺织学报, 2018, 39(02): 112-118. |
[10] | 冯雅妮 张梅 罗胜利 白玉颖 司马义· 艾沙江 邱夷平 蒋秋冉. 光催化除甲醛苎麻织物的低温复合制备[J]. 纺织学报, 2017, 38(12): 106-111. |
[11] | 李静 王晓 邵伟 崔永珠 魏春艳. 改性活性染料对涤纶织物的紫外光引发接枝染色[J]. 纺织学报, 2017, 38(11): 91-96. |
[12] | 吉强 王晓 戚俊然 崔永珠 吕丽华. 光接枝丙烯酸棉纤维素基TiO2/C光催化剂的制备与光催化性[J]. 纺织学报, 2017, 38(10): 75-80. |
[13] | 解昌峰 刘波 孙建平 唐人成 龙家杰. 活性染料染色棉织物的水溶液浸渍光催化剥色[J]. 纺织学报, 2017, 38(09): 81-88. |
[14] | 吕丽华 毕吉红 于 翔 钱永芳 赵玉萍. 废弃涤纶织物/氯化聚乙烯复合材料的隔声性能[J]. 纺织学报, 2017, 38(08): 50-54. |
[15] | 张圣易 丁志荣 杨艳艳. 蒸镀超疏水涤纶织物的制备及其疏水性能[J]. 纺织学报, 2017, 38(04): 85-89. |
|