纺织学报 ›› 2019, Vol. 40 ›› Issue (02): 173-180.doi: 10.13475/j.fzxb.20180801808

• 综合述评 • 上一篇    

基于碳纤维及其织物的柔性锂电池电极研究进展

陈悦, 赵永欢, 褚朱丹, 庄志山, 邱琳琳, 杜平凡()   

  1. 浙江理工大学 材料与纺织学院、丝绸学院, 浙江 杭州 310018
  • 收稿日期:2018-08-06 修回日期:2018-12-18 出版日期:2019-02-15 发布日期:2019-02-01
  • 通讯作者: 杜平凡
  • 作者简介:陈悦(1995—),女,硕士生。主要研究方向为可穿戴纺织结构柔性锂电池。

Research progress of flexible lithium battery electrodes based on carbon fibers and their fabrics

CHEN Yue, ZHAO Yonghuan, CHU Zhudan, ZHUANG Zhishan, QIU Linlin, DU Pingfan()   

  1. Silk Institute, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2018-08-06 Revised:2018-12-18 Online:2019-02-15 Published:2019-02-01
  • Contact: DU Pingfan

摘要:

随着可穿戴技术的快速发展,对柔性锂电池的需求日益增加,将电化学性能优异的活性电极材料与柔性纳米碳基材料进行复合,是目前制备高性能柔性锂电池电极的热门研究方向。本文主要对碳纤维及其织物在锂离子和锂硫电池柔性电极材料中的研究与应用情况进行综述,总结了制备柔性复合电极材料的不同方法及其进展,包括静电纺丝技术、水热法、热处理、涂覆、磁控溅射、原子层沉积和热刻蚀等,所获得的电极材料均在某方面表现出优异性能,例如可逆容量高、循环性能优异、力学强度增强等。最后对基于碳纤维及其织物的柔性锂电池电极的未来发展提出了展望。

关键词: 柔性锂电池, 电极材料, 碳纤维, 碳纤维织物, 可穿戴技术

Abstract:

With the rapid development of wearable technology, the demand for flexible lithium batteries is increasing. The combination of active electrode materials with excellent electrochemical properties and flexible nano-carbon-based materials is a hot research direction for the preparation of high-performance flexible lithium battery electrodes. In this paper, the research and application of carbon fiber and fabric in flexible electrode materials of lithium ion and lithium sulfur battery were reviewed. The different methods and progress of preparing flexible composite electrode materials are summarized, including electrospinning technology, hydrothermal method, heat treatment, coating, magnetron sputtering, atomic layer deposition and thermal etching. All of the obtained electrode materials show excellent performance in some aspects, such as high reversible capacity, excellent cycle performance, and enhanced mechanical strength, etc. Finally, the prospect of the development of flexible lithium battery electrodes based on carbon fiber and fabric was put forward.

Key words: flexible lithium battery, electrode material, carbon fiber, carbon fiber fabric, wearable technology

中图分类号: 

  • TS176.5

图1

MnO / CNF复合膜制备示意图"

图2

PVP/P123/TEOS的热解电纺膜合成HPCNF布的示意图以及制备用于锂硫(Li-S)电池的无粘合剂阴极的柔性S/HPCNF复合材料"

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