纺织学报 ›› 2019, Vol. 40 ›› Issue (03): 175-182.doi: 10.13475/j.fzxb.20180402608

• 综合述评 • 上一篇    下一篇

彩色聚合物微球的制备及其在纺织品印染中应用的研究进展

王东伟1,2, 房宽峻1,3(), 刘秀明1, 张健飞1,4, 舒大武1, 张鑫卿5   

  1. 1.天津工业大学 纺织科学与工程学院, 天津 300387
    2.中原工学院 纺织学院, 河南 郑州 450007
    3.山东省生态纺织协同创新中心, 山东 青岛 266071
    4.天津工业大学 先进纺织复合材料教育部重点实验室, 天津 300387
    5.河南工程学院 材料与化学工程学院, 河南 郑州 450007
  • 收稿日期:2018-04-13 修回日期:2018-10-17 出版日期:2019-03-15 发布日期:2019-03-15
  • 通讯作者: 房宽峻
  • 作者简介:王东伟(1978—),女,博士生。主要研究方向为纺织品清洁染整技术。
  • 基金资助:
    国家重点研发计划资助项目(2017YFB0309800);国家重点研发计划资助项目(2016YFC0400503)

Preparation of colored polymer microspheres and research progress thereof in textile dyeing and printing

WANG Dongwei1,2, FANG Kuanjun1,3(), LIU Xiuming1, ZHANG Jianfei1,4, SHU Dawu1, ZHANG Xinqing5   

  1. 1. School of Textile Science and Technology, Tianjin Polytechnic University, Tianjin 300387, China
    2. School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    3. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, Shandong 266071, China
    4. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China
    5. School of Materials and Chemical Engineering, Henan University of Engineering, Zhengzhou, Henan 450007, China
  • Received:2018-04-13 Revised:2018-10-17 Online:2019-03-15 Published:2019-03-15
  • Contact: FANG Kuanjun

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摘要：

为弥补纺织品着色用染料和颜料存在的不足,开发彩色聚合物微球作为新型色素是有效途径之一。介绍了聚合物微球的制备方法,综述了近年来国内外制备彩色聚合物微球的3种方法:聚合包覆法、直接染色法和表面修饰法,从彩色聚合物微球的粒径尺寸及单/窄分散性、染料在聚合物微球表面的吸附量及吸附稳定性、纯度和功能性4个方面探讨了由不同方法所制得的彩色聚合物微球的特点。结果表明:将彩色聚合物微球用于织物的染色和印花,可获得较高的颜色深度和鲜艳度,主要色牢度指标均达到服用性能要求;彩色聚合物微球具有染料色彩鲜艳和有机颜料耐久性好等优点,在纺织品印染方面具有良好的应用前景。

关键词: 新型色素, 彩色聚合物微球, 纺织品, 染色, 印花

Abstract:

In order to make up the inadequacy of dye and pigment used in textile dyeing and printing, the preparation of the colored polymer microspheres may be one of the effective ways to solve the problem. The preparation methods of the polymer microspheres were introduced. The three methods recently developed in preparation of the colored polymer microspheres, including the entrapment method, the direct staining method and the surface modification method, as well as their research progress were reviewed. The characteristics of the colored polymer microspheres prepared by various methods were analyzed and compared from four aspects, which include the size and single/narrow dispersion, the adsorption capacity and stability of the dye on the surface of the polymer microspheres, purity and functionality. The results show that the application of colored polymer microspheres in dyeing and printing of textiles achieve higher color depth and brightness, and the main color fastness can satisfy the requirement of wearability. With the advantages of good chromatic properties of dyes and good durability of organic pigments, the colored polymer microspheres show a good prospect in textile dyeing and printing.

Key words: novel colorant, colored polymer microsphere, textile, dyeing, printing

中图分类号: 

  • TS194.9

表1

聚合物微球制备方法的比较"

制备方法 微球尺寸/μm 分散度 表面活性剂 引发剂 反应介质 主要特点
乳液聚合 <1 较宽 乳化剂 水溶性 水相 粒径较小
悬浮聚合 20~1 000 较宽 悬浮剂 油溶性 水相 粒径较大
分散聚合 0.1~10 较窄 稳定剂 水溶性或油溶性 水相或超临界CO2或有机溶剂 单或窄分散性好
沉淀聚合 0.1~100 较窄 无 水溶性或油溶性 水相或超临界CO2或有机溶剂 产物纯净
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