紫外光固化密胺树脂的合成及涂层织物性能测试

doi:10.13475/j.fzxb.20180603604

纺织学报 ›› 2019, Vol. 40 ›› Issue (06): 64-67.doi: 10.13475/j.fzxb.20180603604

紫外光固化密胺树脂的合成及涂层织物性能测试

张思¹^,², 吴敏¹^,²()

1.生态纺织教育部重点实验室(江南大学), 江苏无锡 214122
2.江南大学纺织服装学院, 江苏无锡 214122

收稿日期:2018-06-08 修回日期:2019-03-18 出版日期:2019-06-15 发布日期:2019-06-25
通讯作者: 吴敏
作者简介:张思(1994—),女,硕士生。主要研究方向为高性能树脂的应用研究。
基金资助:
中央高校基本科研业务费专项资金资助项目(JUSRP51723B);政策引导类计划(产学研合作)-前瞻性联合研究项目(BY2015019-12)

Synthesis of UV curing melamine resin and performance testing of its coating fabric

ZHANG Si¹^,², WU Min¹^,²()

1. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
2. College of Textiles and Garment, Jiangnan University, Wuxi, Jiangsu 214122, China

Received:2018-06-08 Revised:2019-03-18 Online:2019-06-15 Published:2019-06-25
Contact: WU Min

摘要/Abstract

摘要：

采用丙烯酸羟乙酯(HEA)改性甲醚化密胺树脂(HMMM),引入了不饱和C=C双键,增加密胺树脂的光固化性能,成功合成了氨基丙烯酸酯(HEA-MF),制备得到紫外光(UV)固化密胺树脂,并利用红外光谱分析了产物的结构;制备了光固化密胺树脂膜和涂层织物,借助热重分析仪表征膜的热性能,并对涂层织物的力学性能、硬挺度、耐磨性、防水透湿性和透气性等进行分析。结果表明:在300 ℃以下,光固化膜结构稳定,具有较好的热稳定性,350 ℃质量开始快速减少;涂层后织物断裂强力、硬挺度和耐磨性均提高,织物断裂伸长率和透湿透气性有所下降,但涂层织物防水性能突出。

关键词: 密胺树脂, 紫外光固化, 氨基丙烯酸酯, 涂层织物, 防水性

Abstract:

In order to prepare UV curable melamine resin,hydroxyethyl acrylate (HEA) was used to modify methyl etherified melamine resin (HMMM). The unsaturated C=C double bond was introduced to increase the photocurability of melamine resin.The structure of the product was characterized by infrared spectroscopy.As a result,amino acrylate (HEA-MF) is successfully synthesized.Then,the photocurable melamine resin film and coated fabric were prepared,and the thermal property of the film was characterized by Thermal Gravity Analysis(TGA).The mechanical properties,stiffness,wear resistance,waterproof,moisture permeability and air permeability of coated samples were analyzed.The results show that under 300 ℃,the UV-cured film has stable structure and good thermal stability,it begins to lose weight quickly at 350 ℃.After coating,the breaking strength,stiffness and abrasion resistance of the fabric are improved.The fabric elongation at break,moisture permeability and air permeability are adversely affected,but the waterproof properties of the coated fabric are outstanding.

Key words: melamine resin, UV curing, amino acrylate, coating fabric, waterproof

中图分类号:

TS194

张思, 吴敏. 紫外光固化密胺树脂的合成及涂层织物性能测试[J]. 纺织学报, 2019, 40(06): 64-67.

ZHANG Si, WU Min. Synthesis of UV curing melamine resin and performance testing of its coating fabric[J]. Journal of Textile Research, 2019, 40(06): 64-67.

图/表 6

图1

图2

图3

表1

表2

表3

参考文献 11

[1]	马跃辉, 王炜, 蒋志康. 光固化技术在纺织印染中的应用进展[J]. 印染助剂, 2018,35(5):12-17.
	MA Yuehui, WANG Wei, JIANG Zhikang. Application of UV curing technology in textile dyeing and printing[J]. Textile Auxiliaries, 2018,35(5):12-17.
[2]	南旭莹, 任晓峰, 黄益, 等. 光固化技术在纺织染整中的应用[J]. 印染, 2017,43(7):50-55.
	NAN Xuying, REN Xiaofeng, HUANG Yi, et al. Application of UV curing technology in textile dyeing and printing[J]. China Dyeing & Finishing, 2017,43(7):50-55.
[3]	邵瑞梦, 张梅, 于范芹, 等. 三聚氰胺甲醛树脂改性的研究进展[J]. 广东化工, 2016,43(24):92-93,121.
	SHAO Ruimeng, ZHANG Mei, YU Fanqin, et al. Research progress in modification of melamine formaldehyde resin[J]. Guangdong Chemical Industry, 2016,43(24):92-93,121.
[4]	张本刚, 吴志刚, 雷洪. 三聚氰胺树脂增韧改性研究进展[J]. 绿色科技, 2018(8):185-187.
	ZHANG Bengang, WU Zhigang, LEI Hong. Research progress in toughening modification of melamine resin[J].Journal of Green Science and Technology, 2018(8):185-187.
[5]	李昭. 三聚氰胺树脂的合成工艺研究[J]. 山东化工, 2015,44(19):26-27,30.
	LI Zhao. Study on the synjournal of melamine resin[J]. Shandong Chemical Industry, 2015,44(19):26-27,30.
[6]	熊冕, 马迎春, 王姣姣, 等. 三聚氰胺甲醛树脂研究与应用进展[J].广东化工, 2013, 40(22):68,74.
	XIONG Mian, MA Yingchun, WANG Jiaojiao, et al. Research and application of melamine resin[J].Guangdong Chemical Industry, 2013, 40(22):68,74.
[7]	刘丹丹, 王欣, 刘甜, 等. 快速成型光固化树脂的制备[J]. 工程塑料应用, 2014,42(4):23-26.
	LIU Dandan, WANG Xin, LIU Tian, et al. Preparation of stereolithography resin[J]. Engineering Plastics Application, 2014,42(4):23-26.
[8]	ARVIN Z Y, JONAS M, SAHOUANI D C. Highly functional methacrylated bio-based resins for UV-curable coatings[J].Progress in Organic Coatings, 2018(122):219-228.
[9]	LILIAN Boton, JOHN Marc Puguan, MUHAMMAD Latif, et al. Synjournal and properties of quick-drying UV-curable hyperbranched waterborne polyurethane coating[J].Progress in Organic Coatings, 2018(125):201-206.
[10]	宋玉. UV固化聚氨酯膜的制备及其在织物表面的应用[D]. 无锡:江南大学, 2014: 12-15.
	SONG Yu. Preparation of UV curable polyurethane film and its application in the fabric surface[D]. Wuxi:Jiangnan University, 2014: 12-15.
[11]	那英, 杨福斌, 陈运能. 聚氨酯涂层棉织物性能研究[J]. 棉纺织技术, 2017,45(6):34-36.
	NA Ying, YANG Fubin, CHEN Yunneng. Property study of polyurethane coated cotton fabric[J]. Cotton Textile Technology, 2017,45(6):34-36.

相关文章 15

[1]	杨婉秋刘晓艳于伟东. 多层防刺材料中间隔织物的缓冲作用[J]. 纺织学报, 2019, 40(04): 51-54.
[2]	胡勇杰. 纳米二氧化硅/聚醚共聚乙酰胺防水透气涂层织物的研制及其性能[J]. 纺织学报, 2018, 39(10): 104-109.
[3]	吕赛龙霍瑞亭贾国强. 光催化自清洁纺织品的制备及其性能[J]. 纺织学报, 2018, 39(05): 87-91.
[4]	蓝杰蕊沈锦玉李玖明陈建勇郭玉海张华鹏 . 紫外光固化技术对聚丙烯非织造布的亲水改性[J]. 纺织学报, 2017, 38(05): 98-103.
[5]	贾国强霍瑞亭李文君. 光催化自清洁涂层纺织品的制备[J]. 纺织学报, 2017, 38(05): 93-97.
[6]	杨帆陈远辉顾晨成冒海燕王潮霞殷允杰. 紫外光固化水性聚氨酯丙烯酸酯黏合剂的印花性能[J]. 纺织学报, 2016, 37(3): 82-86.
[7]	郭囊括李丽辉代方银陈杨敬凌霄. 柔性多轴向经编聚氨酯涂层织物的拉伸性能[J]. 纺织学报, 2016, 37(11): 59-063.
[8]	陈丽华. 不同种类防水透湿织物的性能及发展[J]. 纺织学报, 2012, 33(7): 149-156.
[9]	朱桂英;张瑞林. Canny算子在织物防水性能自动识别中的应用[J]. 纺织学报, 2008, 29(3): 122-125.
[10]	徐旭凡. 多功能聚氨酯涂层织物的制备及性能[J]. 纺织学报, 2006, 27(3): 71-73.
[11]	郭建生;胡大艳. 微胶囊的制备及其在涂层织物透气整理上的应用[J]. 纺织学报, 2006, 27(12): 84-87.
[12]	徐旭凡;王善元. 聚氨酯转移涂层织物的透湿防水性能[J]. 纺织学报, 2005, 1(3): 82-84.
[13]	李玮茹;张士俊;俞建勇. 粘接式气囊接口受力及接口临界长度的研究[J]. 纺织学报, 2005, 26(1): 92-94.
[14]	潘云芳. 防水透湿涂层织物的发展及工艺探讨[J]. 纺织学报, 2004, 25(04): 94-95.
[15]	徐旭凡. PU湿法防水透湿涂层织物的研究[J]. 纺织学报, 2003, 24(06): 75-76.

Metrics

Viewed

Full text

137

HTML			PDF

Just accepted	Online first	Issue	Just accepted	Online first	Issue
0	0	3	0	0	134

From	Others	local

Times	32	105
Rate	23%	77%

Abstract

817

Just accepted	Online first	Issue

0	0	817

From	Others	local

Times	610	207
Rate	75%	25%

Cited

Web of Science	Crossref	ScienceDirect	Search for Citations in Google Scholar >>


This page requires you have already subscribed to WoS.

Shared

Discussed

实验样品	断裂强力/ N	断裂伸长率/%
未处理涤/棉织物	1 108.2	17.51
UV照射涤/棉织物	460.0	20.29
HEA-MF涂层织物	1 181.4	8.94

实验样品	方向	弯曲长度/cm				磨损率/%
实验样品	方向	1	2	3	4	磨损率/%
未处理涤/	经	4.59	4.57	4.73	4.68	3.55
棉织物	纬	4.84	4.51	4.57	4.48
HEA-MF	经	10.65	11.06	10.40	11.03	1.39
涂层织物	纬	10.46	11.13	10.84	10.63

实验样品	透湿量/(g·(m²·24 h)^-1)	静水压/kPa
HEA-MF涂层织物	373	18.03
未处理涤/棉织物	3 235	—

紫外光固化密胺树脂的合成及涂层织物性能测试

Synthesis of UV curing melamine resin and performance testing of its coating fabric

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 11

相关文章 15

Metrics

本文评价

推荐阅读 0