纺织学报 ›› 2019, Vol. 40 ›› Issue (09): 97-101.doi: 10.13475/j.fzxb.20180702105

• 染整与化学品 • 上一篇    下一篇

等离子体预处理对聚吡咯/涤纶经编导电织物结构和性能的影响

林佳濛, 缪旭红(), 万爱兰   

  1. 江南大学 纺织服装学院, 江苏 无锡 214122
  • 收稿日期:2018-07-10 修回日期:2019-03-27 出版日期:2019-09-15 发布日期:2019-09-23
  • 通讯作者: 缪旭红
  • 作者简介:林佳濛(1995—),女,硕士生。主要研究方向为智能纺织品。
  • 基金资助:
    江苏省自然科学基金项目(BK20151129);国家轻工技术与工程一流学科自主课题资助项目(2018-28)

Influence of plasma pretreatment on structure and properties of polypyrrole/polyester warp knitted conductive fabric

LIN Jiameng, MIAO Xuhong(), WAN Ailan   

  1. School of Textiles and Clothing, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2018-07-10 Revised:2019-03-27 Online:2019-09-15 Published:2019-09-23
  • Contact: MIAO Xuhong

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摘要：

为改善导电高聚物在涤纶经编针织物上的附着效果,采用常温常压等离子体预处理方法对涤纶织物进行表面改性处理,并通过原位聚合法制备了聚吡咯/涤纶导电针织物,研究了等离子体预处理对聚吡咯在涤纶针织物上附着效果的影响,借助扫描电子显微镜和电阻仪分析了导电织物的微观形貌以及平磨前后方阻值的变化。结果表明:等离子体预处理方法可增加聚吡咯在涤纶上的附着量,改善聚吡咯在涤纶上的附着牢度,提高导电织物导电层在平磨过程中的保持程度,且附着量与等离子体预处理次数存在相关性:当等离子体预处理次数为4时,聚吡咯在涤纶针织物上的附着效果最佳。

关键词: 常温常压等离子体, 聚吡咯, 涤纶针织物, 附着效果, 导电织物

Abstract:

In order to improve the adhesion effect of conductive polymer on polyester warp knitted fabric, the surface of the fabric was modified by atmospheric pressure plasma treatment, and the conductive knitted fabric was prepared by in-situ polymerization. The influence of plasma pretreatment on the adhesion of polypyrrole to polyester knitted fabrics was studied. The micro-morphology of conductive fabrics was observed by a scanning electron microscopy, and the square resistance of conductive fabrics before and after flat grinding was measured by a resistometer. The results show that plasma pretreatment can increase the adhesion of polypyrrole to polyester fibers, improve the adhesion fastness of polypyrrole to polyester fibers, and improve the retention of conductive layers of conductive fabrics in flat grinding. The results are related to the times of plasma pretreatments. The adhesion effect of polypyrrole on polyester knitted fabrics is the best when the times of plasma pretreatment is 4.

Key words: atmospheric temperature and pressure plasma, polypyrrole, polyester knitted fabric, adhesion effect, conductive fabric

中图分类号: 

  • TS186.1

图1

聚合反应方程式"

表1

试样及其处理条件"

试样编号 处理条件
0# 仅清洗的涤纶织物原样
1# 吡咯聚合
2# 常温常压等离子体处理2次+吡咯聚合
3# 常温常压等离子体处理3次+吡咯聚合
4# 常温常压等离子体处理4次+吡咯聚合
5# 常温常压等离子体处理5次+吡咯聚合
6# 常温常压等离子体处理6次+吡咯聚合
7# 碱减量处理+吡咯聚合

图2

试样的扫描电镜照片"

图3

不同等离子体处理后涤纶织物的红外光谱图"

表2

平磨前后织物的方阻值"

试样
编号		 平磨前 平磨后 方阻值
增加量/
(kΩ·□-1)
方阻值/
(kW·□-1)		 CV值/% 方阻值/
(kW·□-1)		 CV值/%
1# 30.22 14.3 46.92 14.7 16.70
2# 1.96 2.4 2.05 2.6 0.09
3# 0.96 2.7 1.06 2.9 0.10
4# 0.09 3.5 0.12 3.8 0.03
5# 0.11 4.6 0.15 4.9 0.04
6# 0.23 3.7 0.27 3.9 0.04
7# 18.12 13.9 27.70 14.1 9.58

图4

试样平磨前后的照片"

[1] 张庆伟, 霍歆彤, 李青. 聚吡咯导电织物的制备及性能研究[J]. 北京服装学院学报(自然科学版), 2013,33(4):19-24.
ZHANG Qingwei, HUO Xintong, LI Qing. Preparation and properties of polypyrrole conductive fabric[J]. Journal of Beijing Institute of Fashion Technology(Natural Science Edition), 2013,33(4):19-24.
[2] 李昕, 钱晶, 付中玉. 聚苯胺基导电织物的制备及其电致变色性能研究[J]. 北京服装学院学报 (自然科学版), 2009,29(2):12-17.
LI Xin, QIAN Jing, FU Zhongyu. Preparation and electrochromic properties of polyphenylamine-based conductive fabrics[J]. Journal of Beijing Institute of Fashion Technology (Natural Science Edition), 2009,29(2):12-17.
[3] SUN J, YAO L, GAO Z, et al. Surface modification of PET films by atmospheric pressure plasma-induced acrylic acid inverse emulsion graft polymerization[J]. Surface and Coatings Technology, 2010,204(24):4101-4106.
doi: 10.1016/j.surfcoat.2010.05.038
[4] KELLER M, RITTER A, REIMANN P, et al. Comparative study of plasma-induced and wet-chemical cleaning of synthetic fibers[J]. Surface and Coatings Technology, 2005,200(1-4):1045-1050.
doi: 10.1016/j.surfcoat.2005.01.098
[5] MEHMOOD T, KAYNAK A, DAIX J, et al. Study of oxygen plasma pre-treatment of polyester fabric for improved polypyrrole adhesion[J]. Materials Chemistry and Physics, 2014,143(2):668-675.
doi: 10.1016/j.matchemphys.2013.09.052
[6] GARG S, HURREN C, KAYNAK A. Improvement of adhesion of conductive polypyrrole coating on wool and polyester fabrics using atmospheric plasma treat-ment[J]. Synthetic Metals, 2007,157(1):41-47.
doi: 10.1016/j.synthmet.2006.12.004
[7] MONTARSOLO A, VARESANO A, MOSSOTTI R, et al. Enhanced adhesion of conductive coating on plasma-treated polyester fabric: a study on the ageing effect[J]. Journal of Applied Polymer Science, 2012,126(4):1385-1393.
doi: 10.1002/app.v126.4
[8] 贾彩霞, 陈平, 王乾, 等. 常压空气等离子体对连续纤维的在线改性[J]. 材料研究学报, 2015,29(1):10-16.
JIA Caixia, CHEN Ping, WANG Qian, et al. On-line modification of continuous fiber by atmospheric air plasma[J]. Journal of Materials Research, 2015,29(1):10-16.
[9] RAMELOW U S, MA J H, DARBEAU R. Electrical conductivities of polypyrrole reacted with dopant solutions[J]. Materials Research Innovations, 2001,5(1):40-49.
doi: 10.1007/s100190100129
[10] 朱嫦娥, 任丽, 王立新, 等. 炭黑吸附聚合制备聚吡咯/炭黑导电复合材料[J]. 复合材料学报, 2005(3):45-48.
ZHU Chang'e, REN Li, WANG Lixin, et al. Preparation of polypyrrole/carbon black conductive composites by adsorption polymerization of carbon black[J]. Journal of Composites, 2005 (3):45-48.
[11] LEE S J, YUN C, PARK C H. Electrically conductive and superhydrophobic textiles via pyrrole polymerization and surface hydrophobization after alkaline hydrolysis[J]. Textile Research Journal, 2018, https://doi.org/10.1177/0040517518773371.
doi: 10.1080/0002889758507210 pmid: 1111270
[12] MEHMOOD T, DAI X J, KAYNAK A, et al. Improved bonding and conductivity of polypyrrole on polyester by gaseous plasma treatment[J]. Plasma Processes and Polymers, 2012,9(10):1006-1014.
doi: 10.1002/ppap.201200046
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