纺织学报 ›› 2019, Vol. 40 ›› Issue (10): 42-47.doi: 10.13475/j.fzxb.20180908106

• 纤维材料 • 上一篇    下一篇

同轴静电纺多孔氧化锌薄膜制备及其光催化性能

辛民岳, 郑强, 吴江丹, 梁列峰()   

  1. 西南大学 纺织服装学院, 重庆 400715
  • 收稿日期:2018-09-28 修回日期:2019-07-17 出版日期:2019-10-15 发布日期:2019-10-23
  • 通讯作者: 梁列峰
  • 作者简介:辛民岳(1993—),男,硕士生。主要研究方向为静电纺薄膜材料。
  • 基金资助:
    国家自然科学基金项目(41573106)

Preparation of porous ZnO films by coaxial electrospinning and photocatalytic performance thereof

XIN Minyue, ZHENG Qiang, WU Jiangdan, LIANG Liefeng()   

  1. College of Textile and Garment, Southwest University, Chongqing 400715, China
  • Received:2018-09-28 Revised:2019-07-17 Online:2019-10-15 Published:2019-10-23
  • Contact: LIANG Liefeng

RichHTML

8

PDF (PC)

194

摘要：

为制备轻质且具有大比表面积的光催化剂,针对静电纺丝中聚合物载体大都有污染且不可再生的问题,以丝素蛋白为载体,通过同轴静电纺丝制备醋酸锌/丝素(ZnAc/SF)纳米纤维薄膜,然后浸渍于硫化钠(Na2S)溶液中制备硫化锌(ZnS)/SF纳米纤维薄膜,最后经煅烧得到ZnS/C纳米纤维薄膜和多孔ZnO薄膜。借助X射线衍射仪、X射线光电子能谱仪、扫描电子显微镜、紫外-可见分光光度计对薄膜的结构和性能进行表征,并通过亚甲基蓝催化降解实验研究其光催化性能。结果表明:多孔ZnO薄膜是由10~20 nm颗粒组成的介孔网络组织,具有吸收紫外线能力,比ZnS/C纳米纤维薄膜有更强的光催化作用,对亚甲基蓝的降解效率可达99.5%;多孔ZnO薄膜可进行回收利用,4次循环后降解效率达91%。

关键词: 印染废水, 多孔ZnO薄膜, 同轴静电纺丝, 光催化性能, 回收利用

Abstract:

In order to prepare light photocatalysts with large specific surface area, aiming at the problem that most of polymer carriers in electrospinning are polluted and non-renewable, ZnAc/silk fibroin(SF) nanofiber films were prepared by coaxial electrospinning using silk fibroin as carrier, and then ZnAc/SF nanofiber films were immersed in Na2S solution to prepare ZnS/SF nanofiber films. Finally, porous ZnO films were obtained by calcination. The structure, element composition, surface morphology and optical properties of the samples were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Scanning electron microscope and UV-Vis absorption spectra. Besides, the photocatalytic performance of samples were studied by MB degrading tests. The results show that the porous ZnO film is a mesoporous network composed of 10-20 nm nanoparticles with the capability of absorbing ultraviolet light. The film is stronger in photocatalytic activity than the ZnS/C nanofiber film, and has the degradation efficiency of methylene blue up to 99.5%. In addition, porous ZnO films can be easily recycled and reused, and the degradation efficiency reaches 91% after four cycles.

Key words: dyeing waste water, porous ZnO film, coaxial electrospinning, photocatalytic property, recycling

中图分类号: 

  • TQ340.64

图1

样品的扫描电镜照片"

图2

多孔ZnO薄膜的透射电镜照片"

图3

样品的XPS光谱图"

图4

样品的紫外-可见吸收光谱曲线"

图5

样品的XRD图谱"

图6

MB自降解的紫外-可见吸收光谱图"

图7

不同条件下MB的紫外-可见吸收光谱"

图8

多孔ZnO薄膜光降解MB的紫外-可见光谱图"

图9

多孔ZnO薄膜对印染废水光降解的紫外-可见光谱"

[1] 殷巧巧, 乔儒, 童国秀. 离子掺杂氧化锌光催化纳米功能材料的制备及其应用[J]. 化学进展, 2014,26(10):1619-1632.
YIN Qiaoqiao, QIAO Ru, TONG Guoxiu. Preparation and photocatalytic application of ion-doped ZnO functional nanomaterials[J]. Progress in Chemistry, 2014,26(10):1619-1632.
[2] JEON P J, LEE Y T, LIM J Y, et al. Black phosphorus-zinc oxide nanomaterial heterojunctionfor p-n diode and junction field-effect transistor[J]. Nano Letters, 2016,16(2):1293-1298.
doi: 10.1021/acs.nanolett.5b04664 pmid: 26771206
[3] HONG R Y, LI J H, CHEN L L, et al. Synjournal surface modification and photocatalytic property of ZnO nanoparticles[J]. Powder Technology, 2009,189(3):426-432.
doi: 10.1016/j.powtec.2008.07.004
[4] 王艳香, 孙健, 范学运, 等. 直接沉淀法制备纳米ZnO粉体[J]. 中国陶瓷, 2007,43(11):31-33,37.
WANG Yanxiang, SUN Jian, FAN Xueyun, et al. Preparation of nanometer-sized ZnO powder by direct precipitation method[J]. China Ceramics, 2007,43(11):31-33,37.
[5] WANG X, ZHANG Q, WAN Q, et al. Controllable ZnO architectures by ethanolamine-assisted hydrothermal reaction for enhanced photocatalytic activity[J]. The Journal of Physical Chemistry C, 2011,115(6):2769-2775.
doi: 10.1021/jp1096822
[6] 许淑燕, 张培培, 熊杰. 氧化锌纳米纤维的制备及其光催化性能[J]. 纺织学报, 2011,32(3):15-20.
XU Shuyan, ZHANG Peipei, XIONG Jie. Preparation and photocatalytic properties of ZnO nanofibers[J]. Journal of Textile Research, 2011,32(3):15-20.
[7] JANG J S, YU C J, CHOI S H, et al. Topotactic synjournal of mesoporous ZnS and ZnO nanoplates and their photocatalytic activity[J]. Journal of Catalysis, 2015,254(1):144-155.
doi: 10.1016/j.jcat.2007.12.010
[8] SHAMI Z, SHARIFI-SANJANI N. A well-designed three-dimensional ternary hierarchical co-axial ZnO@ZnS heteroarchitecture decorated electrospun carbon hollow tube nanofibrous mat: improved ultraviolet-light photocatalytic performance[J]. Crystengcomm, 2013,16(5):910-921.
doi: 10.1039/C3CE41513A
[9] UDDIN M T, NICOLAS Y, et al. Nanostructured SnO2-ZnO heterojunction photocatalysts showing enhanced photocatalytic activity for the degradation of organic dyes[J]. Inorganic Chemistry, 2012,51(14):7764-7773.
doi: 10.1021/ic300794j pmid: 22734686
[10] LU F, CAI W, ZHANG Y. ZnO hierarchical micro/nanoarchitectures: solvothermal synjournal and structurally enhanced photocatalytic performance[J]. Advanced Functional Materials, 2008,18(7):1047-1056.
doi: 10.1002/(ISSN)1616-3028
[11] WANG X, ZHAO P, LI Y, et al. Modifying the mechanical properties of silk fiber by genetically disrupting the ionic environment for silk formation[J]. Biomacromolecules, 2015,16(10):3119-3125.
doi: 10.1021/acs.biomac.5b00724 pmid: 26302212
[12] ZHANG H, LIU Y, ZHOU Y. Preparation of magnetic PET fabric loaded with Fe3O4 nanoparticles by hydrothermal method[J]. Journal of The Textile Institute Proceedings and Abstracts, 2015,106(10):1078-1088.
[13] YAYAPAO O, THONGTEM T, PHURUANGRAT A, et al. Synjournal and characterization of highly efficient Gd doped ZnO photocatalyst irradiated with ultraviolet andvisible radiations[J]. Materials Science in Semiconductor Processing, 2015,39:786-792.
doi: 10.1016/j.mssp.2015.06.039
[14] JIA Y, YU Y, CHENG X, et al. Fabrication of a photo-catalytic cell using polymer-based composite films and investigation of its performance in the degradation of methyl blue[J]. RSC Adv, 2015,5(33):25830-25839.
doi: 10.1039/C5RA02764K
[15] SARKAR S, MAKHAL A, BORA T, et al. Hematoporphyrin-ZnO nanohybrids: twin applications in efficient visible-light photocatalysis and dye-sensitized solar cells[J]. ACS Applied Materials & Interfaces, 2012,4(12):7027-7035.
doi: 10.1021/am302288m pmid: 23186038
[16] WANG L, HUANG S, SUN Y. Low-temperature synjournal of hexagonal transition metal ion doped ZnS nanoparticles by a simple colloidal method[J]. Applied Surface Science, 2013,270:178-183.
doi: 10.1016/j.apsusc.2012.12.160
[1] 李庆, 管斌斌, 王雅, 刘天卉, 张洛红, 樊增禄. 光敏剂敏化Cu-有机骨架对活性深蓝K-R 的高效光催化降解[J]. 纺织学报, 2020, 41(10): 87-93.
[2] 赵芷芪, 李秋瑾, 孙月静, 巩继贤, 李政, 张健飞. 磁性氧化石墨烯/ 聚丙烯胺盐酸盐微胶囊在染料吸附中的应用[J]. 纺织学报, 2020, 41(07): 109-116.
[3] 李思捷, 张彩丹. 聚天冬氨酸基纤维水凝胶的制备及其释药性能[J]. 纺织学报, 2020, 41(02): 20-25.
[4] 罗佳妮, 李丽君, 张晓思, 邹汉涛, 刘雪婷. 氧化石墨烯掺杂TiO2改性活性炭纤维[J]. 纺织学报, 2020, 41(01): 8-14.
[5] 陈冬芝, 杨晓刚, 陈艳霞, 刘琳, 陈彬, 崔科丛, 张勇. 亚麻废纱制备纤维素基絮凝材料及其混凝工业废水性能 [J]. 纺织学报, 2020, 41(01): 88-95.
[6] 徐春霞, 降帅, 韩阜益, 徐芳, 刘丽芳. 纤维素纳米纤丝气凝胶制备及其对亚甲基蓝的吸附性能[J]. 纺织学报, 2019, 40(10): 20-25.
[7] 李树锋, 程博闻, 罗永莎, 王辉, 徐经伟. 聚丙烯腈基活性中空碳纳米纤维制备及其性能[J]. 纺织学报, 2019, 40(10): 1-6.
[8] 陈欣, 张家琳, 王纪冬, 李晓强, 葛明桥. 电絮凝技术在废弃涤纶醇解液脱色中的应用[J]. 纺织学报, 2019, 40(10): 98-104.
[9] 周颖, 王闯, 朱佳颖, 黄林汐, 杨丽丽, 余厚咏, 姚菊明, 金万慧. 非织造布表面形貌可控氧化锌纳米粒子的构筑[J]. 纺织学报, 2019, 40(09): 35-41.
[10] 张兰河, 张明爽, 高伟围, 李正, 贾艳萍, 高敏, 凌良雄. 铝酸钴/蜂窝陶瓷催化剂的制备及其在印染废水处理中的应用[J]. 纺织学报, 2019, 40(03): 125-132.
[11] 周存 李叶燃 马悦 王闻宇 金欣 肖长发. 二氧化钛负载聚酯织物的制备及其光催化性能[J]. 纺织学报, 2018, 39(11): 91-95.
[12] 王建坤 郭晶 张昊 郑帼. 交联氨基淀粉对亚甲基蓝染料的吸附性能[J]. 纺织学报, 2018, 39(11): 103-110.
[13] 李树锋 刘高华 谢小军 韩永兴 张艳 程博闻. 同轴静电纺丝参数对聚丙烯腈中空碳纳米纤维形态与炭化收率的影响[J]. 纺织学报, 2017, 38(12): 1-6.
[14] 贾艳萍 姜成 郭泽辉 张兰河 张海丰. 印染废水深度处理及回用研究进展[J]. 纺织学报, 2017, 38(08): 172-180.
[15] 夏鑫 李群华 周惠敏 魏取福 张向武. 皮芯结构Sn∕C包覆碳杂化纳米纤维的制备及其在锂离子负极材料中的应用[J]. 纺织学报, 2014, 35(8): 1-0.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发