纺织学报 ›› 2019, Vol. 40 ›› Issue (11): 94-99.doi: 10.13475/j.fzxb.20181003006

• 染整与化学品 • 上一篇    下一篇

平幅轧染中针织物形变对染色的影响

王秋平1,2, 毛志平1,3, 钟毅1,2(), 徐红1,2, 张琳萍1,2   

  1. 1.东华大学 化学化工与生物工程学院, 上海 201620
    2.东华大学 生态纺织教育部重点实验室, 上海 201620
    3.东华大学 纺织科技创新中心, 上海 201620
  • 收稿日期:2018-10-17 修回日期:2019-03-13 出版日期:2019-11-15 发布日期:2019-11-26
  • 通讯作者: 钟毅
  • 作者简介:王秋平(1992—),女,硕士生。主要研究方向为针织物平幅连续染色。
  • 基金资助:
    国家重点研发计划资助项目(2017YFB0309700)

Influence of knitted deformation on dyeing in flat pad dyeing

WANG Qiuping1,2, MAO Zhiping1,3, ZHONG Yi1,2(), XU Hong1,2, ZHANG Linping1,2   

  1. 1. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
    2. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    3. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
  • Received:2018-10-17 Revised:2019-03-13 Online:2019-11-15 Published:2019-11-26
  • Contact: ZHONG Yi

摘要:

针对平幅轧染中针织物易形变、张力不均带来皱褶和染色不匀等问题,通过选用多种化学结构活性染料对棉针织物进行浸轧染色,借助方差分析的手段,考察针织物在不同拉伸形变条件下固色后染料结构对染色性能的影响。结果表明:针织物采用不同活性基活性红实施平幅轧染,无论在横向还是纵向张力拉伸条件下预烘及汽蒸固色,拉伸对针织物的染色与匀染影响较小;由于染料结构的差异导致棉针织物对染料的吸附固色不同,不同的染料对同一种针织物的浸轧染色提升力有所区别;染中浅色时轧染可节省更多染料,尤其对于活性红WBRH(KN型),轧染色深明显高于浸染,更推荐轧染方式;染色后针织物皂洗牢度大于或等于4级。

关键词: 针织物, 平幅, 形变, 轧染, 活性染料

Abstract:

In view of the challenge in the pad-dyeing of open width knitted fabric, which leads to unleveled dyeing and crease formation caused by varying tension during the dyeing operation, reactive dyes of various chemical structures were adopted to pad-dye cotton knitted fabric, and the influence of the dye structure on the dyeing performance of the cotton knitted fabric under different tensile deformation conditions after fixation was investigated by means of variance analysis. The results showed that when the pad-dye cotton knitted fabric are subjected to open width pad-dyeing with reactive red of different active groups, and prebaked and fixed by steaming under the transverse or longitudinal tensioning condition, the tension has small influence on the dyeing and the level dyeing of the knitted fabric; and the difference in the dye structures causes different absorption and fixation of the cotton knitted fabric to dyes, thus, different dyes have difference in the pad-dyeing lifting power to the same knitted fabric. When dyeing in light colors, pad-dyeing can save more dye, especially for reactive red WBRH (KN type), the color depth of pad-dyeing is significantly higher than that of dip dyeing. The dyeing performance and levelness were not affected and the washing color fastness were greater than or equal to 4 grades.

Key words: knitted fabric, open width, deformation, pad dyeing, reactive dye

中图分类号: 

  • TS193.5

表1

轧染染料浓度与浸染对应值"

轧染染料质量浓度/(g·L-1) 浸染染料用量/%(o.w.f) 轧染染料质量浓度/(g·L-1) 浸染染料用量/%(o.w.f)
5 0.40 40 3.08
10 0.79 50 3.81
20 1.57 60 4.53
30 2.33

图1

活性红染料提升力曲线"

图2

预烘时横向拉伸率对色深的影响"

表2

预烘时横向拉伸率对色深影响的方差分析"

染料 组间离均
平方和
组内离均
平方和
检验
统计量
P 临界值
活性红WBRH 0.003 0.086 0.21 0.93 4.18
活性红P-BN 0.041 0.656 0.39 0.81 4.18
活性红L-S 0.266 3.102 0.54 0.71 4.18

图3

预烘时纵向拉伸率对色深的影响"

表3

预烘时纵向拉伸率对色深影响的方差分析"

染料 组间离均
平方和
组内离均
平方和
检验
统计量
P 临界值
活性红WBRH 0.001 0.056 0.05 0.99 4.18
活性红P-BN 0.003 0.536 0.04 1.00 4.18
活性红L-S 0.113 2.180 0.32 0.86 4.18

图4

汽蒸时横向拉伸率对色深的影响"

表4

汽蒸时横向拉伸率对色深影响的方差分析"

染料 组间离均
平方和
组内离均
平方和
检验
统计量
P 临界值
活性红WBRH 0.006 0.060 0.68 0.61 4.18
活性红P-BN 0.029 0.525 0.35 0.84 4.18
活性红L-S 0.243 4.013 0.38 0.82 4.18

图5

汽蒸时纵向拉伸率对色深的影响"

表5

汽蒸时纵向拉伸率对色深影响的方差分析"

染料 组间离均
平方和
组内离均
平方和
检验
统计量
P 临界值
活性红WBRH 0.003 0.056 0.32 0.86 4.18
活性红P-BN 0.065 0.475 0.86 0.50 4.18
活性红L-S 0.069 1.362 0.32 0.86 4.18

表6

针织物平幅连续轧染与浸染各项牢度对比"

染料 染色方式 K/S 皂洗牢度/级 干摩擦牢度/级 湿摩擦牢度/级
褪色 沾色 横向 纵向 横向 纵向
活性红
WBRH
轧染 13.62 4~5 4~5 5 4~5 4 4
浸染 4.35 4~5 5 5 5 4~5 4
活性红
P-BN
轧染 11.01 4 5 4~5 5 4 4
浸染 6.98 4~5 5 5 4~5 4~5 4~5
活性红
L-S
轧染 18.52 4~5 4~5 4~5 4 3~4 3~4
浸染 18.45 4~5 5 5 4~5 4 4
[1] 林光兴. 针织业: 增长最快的行业之一[J]. 纺织服装周刊, 2005(11):11.
LIN Gangxin. Knitting industry: one of the fastest growing industries[J]. Textile Appaerl Weekly, 2005(11):11.
[2] 徐顺成. 针织物平幅连续化前处理工艺与设备[J]. 针织工业, 2011(5):34-36.
XU Shuncheng. Knitted fabric flat continuous pretreatment process and equipment[J]. Knitting Industries, 2011(5):34-36.
[3] 何叶丽. 针织物的平幅加工[J]. 印染, 2004,30(1):48-49.
HE Yeli. Flat processing of knitted fabrics[J]. China Dyeing & Printing, 2004,30(1):48-49.
[4] 赵文杰, 张晓云, 钟毅, 等. 棉针织物的冷轧堆前处理与染色[J]. 纺织学报, 2016,37(6):76-82.
ZHAO Wenjie, ZHANG Xiaoyun, ZHONG Yi, et al. Gold pad-batch pretreatment and dyeing of wtton knits[J]. Journal of Textile Research, 2016,37(6):76-82.
doi: 10.1177/004051756703700203
[5] 尹苗苗, 岳晓丽, 钟毅, 等. 针织物冷轧堆染色收卷张力设计[J]. 纺织学报, 2017,38(4):73-79.
YI Miaomiao, YUE Xiaoli, ZHONG Yi, et al. Knitted fabric winding tension of cold pad batch dyeing[J]. Journal of Textile Research, 2017,38(4):73-79.
[6] MINAPOOR S, AJELI S, HASANI H, et al. Investigation into the curling behavior of single jersey weft-knitted fabrics and its prediction using neural network model[J]. Journal of the Textile Institute, 2013,104(5):550-561.
doi: 10.1080/00405000.2012.752124
[7] 顾源祥. 拉幅机与针织物的低张力整理[J]. 国外纺织技术, 1988(15):32-35.
GU Yuanxiang. Low tension finishing of tenter and knitted fabric[J]. Foreign Textile Technology, 1988(15):32-35.
[8] 陈立秋. 针织平幅连续印染的节能减排:二[J]. 染整技术, 2010,32(11):48-53.
CHEN Liqiu. Energy saving and emission reduction of knitted flat continuous printing and dyeing: 2[J]. Textile Dyeing and Finishing Journal, 2010,32(11):48-53.
[9] 王菊. 棉针织物活性染料冷轧堆染色[D]. 上海: 东华大学, 2014: 23-24.
WANG Ju. Cold pad-batch dyeing of cotton knitted fabric with reactive dyes[D]. Shanghai: Donghua University, 2014: 23-24.
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