纺织学报 ›› 2020, Vol. 41 ›› Issue (06): 168-173.doi: 10.13475/j.fzxb.20190304306

• 综合述评 • 上一篇    下一篇

电泳沉积碳纳米管和氧化石墨烯修饰碳纤维表面的研究进展

李莉萍1, 吴道义1, 战奕凯1, 何敏1,2()   

  1. 1.贵州大学 材料与冶金学院, 贵州 贵阳 550025
    2.国家复合改性聚合物材料工程技术研究中心, 贵州 贵阳 550014
  • 收稿日期:2019-03-15 修回日期:2020-02-03 出版日期:2020-06-15 发布日期:2020-06-28
  • 通讯作者: 何敏
  • 作者简介:李莉萍(1995—),女,硕士生。主要研究方向为碳纤维表面修饰及其与锦纶6复合材料性能。
  • 基金资助:
    国家自然科学基金资助项目(51663006);贵州省科技计划项目(黔科合基础 [2016] 1025号)

Review on carbon fiber surface modification using electrophoretic deposition of carbon nanotubes and graphene oxide

LI Liping1, WU Daoyi1, ZHAN Yikai1, HE Min1,2()   

  1. 1. College of Materials and Metallurgy, Guizhou University, Guiyang, Guizhou 550025, China
    2. National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang, Guizhou 550014, China
  • Received:2019-03-15 Revised:2020-02-03 Online:2020-06-15 Published:2020-06-28
  • Contact: HE Min

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摘要：

针对碳纤维表面极性官能团少,化学活性低,与基体间的界面结合强度弱等问题,综述了国内外关于电泳沉积碳纳米管和氧化石墨烯修饰碳纤维提高其复合材料力学性能的最新研究进展。阐述了在不同的电泳沉积工艺下,分别在碳纤维表面引入碳纳米管和氧化石墨烯,对修饰碳纤维表面及其复合材料力学性能的影响。总结了影响电泳沉积修饰碳纤维效果的因素,并提出了相应的建议。展望了电泳沉积修饰碳纤维表面的研究发展方向,指出对碳纤维、碳纳米管和氧化石墨烯进行预处理,添加辅助工艺的电泳沉积设备制造将会成为未来的重要研究方向。

关键词: 碳纤维, 电泳沉积, 碳纳米管, 氧化石墨烯, 复合材料, 力学性能

Abstract:

Carbon fiber (CF) surface has few polar functional groups, and hence is chemically inactive, leading to weak interface bonding strength with the matrix in composites. Aiming at this problem, this article reviewed the latest research progress in carbon fiber surface modification with electrophoretic deposition of carbon nanotubes and graphene oxide to improve the mechanical properties of composites. Based on the adoption of the electrophoretic deposition processes, the work on carbon fiber surface modification with carbon nanotubes and graphene oxide and the effect of the fiber modification on mechanical properties of modified carbon fiber and their composite materials were described. The factors affecting the effect of electrophoretic deposition on modified carbon fibers were summarized, and corresponding suggestions were put forward. The research trend in carbon fiber surface modification based on the use of electrophoretic deposition was explained, and the paper pointed out that pretreatment of carbon fiber, carbon nanotubes and graphene oxide, and the addition of auxiliary electrophoretic deposition equipment manufacturing will become an important research direction in the future.

Key words: carbon fiber, electrophoretic deposition, carbon nanotube, graphene oxide, composite material, mechanical property

中图分类号: 

  • TQ342.74

图1

电泳沉积碳纳米管的碳纤维扫描电镜照片(×13 000)"

图2

CNT/Cu杂化纳米结构的图示"

图3

电泳沉积碳纳米管修饰碳纤维示意图"

图4

电泳沉积氧化石墨烯的碳纤维扫描电镜照片"

图5

电泳沉积氧化石墨烯修饰碳纤维设备"

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