纺织学报 ›› 2020, Vol. 41 ›› Issue (07): 67-71.doi: 10.13475/j.fzxb.20190504005

• 纺织工程 • 上一篇    下一篇

离散树脂成型复合材料的防刺与服用性能

马飞飞()   

  1. 上海固甲新材料科技有限公司, 上海 201620
  • 收稿日期:2019-05-13 修回日期:2020-03-22 出版日期:2020-07-15 发布日期:2020-07-23
  • 作者简介:马飞飞(1987—),男,硕士。主要研究方向为柔性防刺材料的生产工艺、制备过程及性能表征。E-mail: pds98741236@126.com

Stab-resistant performance and wearability of composite materials made by discrete resin molding

MA Feifei()   

  1. Shanghai Sturdy Armor New Material Technology Co., Ltd., Shanghai 201620, China
  • Received:2019-05-13 Revised:2020-03-22 Online:2020-07-15 Published:2020-07-23

摘要:

为平衡防刺服的防刺性能及穿着舒适性,采用软硬结合的设计理念,提出了一种离散树脂成型复合材料的成型工艺。选用改性聚碳酸酯薄片,以离散状态按照设计图案黏结在涤纶与芳纶基布面料上制备柔性防刺复合材料,探讨不同种类离散树脂成型复合材料的防刺性能,并研究该复合材料的透气性能与弯曲性能。结果表明:芳纶基布离散树脂成型复合材料的穿刺强度是涤纶基布离散树脂成型复合材料的2倍;4层离散树脂成型复合材料与40层叠层芳纶平纹布的防刺性能相当,并显著降低了材料厚度和质量;离散树脂成型复合材料的柔软性能良好,且透气性能优异。

关键词: 防刺服, 防刺性能, 离散树脂, 防刺复合材料, 芳纶织物, 服用性能

Abstract:

In order to balance the stab-resistant performance and the wear comfort of stab-resistant body armor, a new discrete resin composite molding process was developed based on the design concept combining of soft and hard sessions. Discrete modified polycarbonate particles were solidified on the polyester and aramid base fabric according to the designed pattern. The stab-resistant performance as well as the breathability and bending performance of different types of discrete resin composites were studied. The results indicate that the stab strength of the aramid composites is twice as high as that of the polyester composites. The stab resistance of 4 layers of discrete resin composites is similar to that of 40 layers of aramid woven fabric, and composites thickness and weight are reduced significantly. It is also found that the composite has good softness and excellent breathability.

Key words: stab-resistant body armor, stab-resistant performance, discrete resin, stab-resistant composite, aramid fabric, wearability

中图分类号: 

  • TS941

图1

离散树脂成型复合材料试样"

表1

基布面料规格参数"

编号 织物
种类
织物
组织
密度/(根·(10 cm)-1) 面密度/
(g·m-2)
厚度/
mm
经向 纬向
1# 涤纶 平纹 208 148 210.50 0.24
2# 芳纶 平纹 134 128 280.00 0.35

图2

离散树脂成型工艺模具"

表2

单层防刺材料试样参数"

编号 材料种类 面密度/(g·m-2) 厚度/mm
3# 涤纶防刺复合材料 1 880.00 1.82
4# 芳纶防刺复合材料 2 130.00 1.95

表3

单层材料的防刺性能"

编号 材料
种类
穿刺
强力/N
穿刺深度/
mm
2# 芳纶平纹织物 12.93±3.18 7.14±1.05
3# 涤纶防刺复合材料 128.00±4.65 8.25±0.86
4# 芳纶防刺复合材料 230.52±5.22 8.72±0.93

图3

材料准静态穿刺前后形态照片"

表4

3种不同规格叠层试样的防刺性能"

试样
编号
组织
结构
防刺层厚度/
mm
穿透深度/
mm
穿透层面密度/
(g·m-2)
穿透状态
5# 4层涤纶防刺复合材料 7.40±1.12 7.40±1.12 7 520.00±12 第4层基布刚刚穿透
6# 4层芳纶防刺复合材料 8.10±0.79 6.20±0.86 6 390.00±10 第4层薄片有刺痕未穿透
7# 40层芳纶平纹织物 14.50±1.24 13.40±1.09 10 640.00±13 穿透38层余2层

图4

复合材料各层穿刺形貌照片 注:F1、F2、F3、F4分别为正面的各层形貌;B1、B2、B3、B4分别为反面的各层形貌。"

表5

3种试样弯曲性能测试结果"

编号 防刺材料种类 弯曲长度/
cm
抗弯刚度/
(mN·cm)
2# 芳纶平纹织物 2.52±0.85 4.48±0.82
3# 涤纶防刺复合材料 7.84±1.15 905.95±1.48
4# 芳纶防刺复合材料 8.74±1.06 1 422.05±0.64
[1] BLYTH P H, ATKINS A G. Stabbing of metal sheets by a triangular knife: an archaeological investigation[J]. International Journal of Impact Engineering, 2002(27):459-473.
[2] KIM H, NAM I. Stab-resisting behavior of polymeric resin reinforced aramid fabrics[J]. Journal of Applied Polymer Science, 2012,123(5):2733-2742.
[3] STILLMAN B. Aramid fabrics to offer stab-resistance: US, 9749849[P]. 2017-08-29.
[4] 钟智丽, 薛兆磊, 孙涵, 等. 三维机织物防刺性能研究[J]. 纺织科学与工程学报, 2018(10):19-23.
ZHONG Zhili, XUE Zhaolei, SUN Han. et al. Study on stab-resistant property of three-dimensional woven fabric[J]. Journal of Textile Science and Engineering, 2018(10):19-23.
[5] GURGEN S, KUHAN M C. The stab resistance of fabrics impregnated with shear thickening fluids including various particle size of additives[J]. Composites Part A:Applied Science & Manufacturing, 2017,94:50-60.
[6] 陆振乾, 许玥. 剪切增稠液浸渍超高分子量聚乙烯织物的防锥刺性能[J]. 纺织学报, 2018,39(10):58-62.
LU Zhenqian, XU Yue. Study on stab-resistant performance of shear thickening fluids impregnated ultra-high-molecular-weight polyethylene fabric[J]. Journal of Textile Research, 2018,39(10):58-62.
[7] 晏义伍, 曹海琳, 赵金华. 纳米混杂Kevlar/Surlyn 复合材料的制备与防刺性能研究[J]. 中国个体防护装备, 2012(3):5-9.
YAN Yiwu, CAO Hailin, ZHAO Jinhua. Preparation and stab resistance of nano hybrid Kevlar/Surlyn composites[J]. China Personal Protection Equipment, 2012(3):5-9.
[8] SHIN M K, BOMMY L, SHI H K. Synergistic toughening of composite fibers by self-alignment of reduced graphene oxide and carbon nanotubes[J]. Nature Communications, 2012. DOI:10.1038/ncomms1661.
doi: 10.1038/s41467-020-20809-6 pmid: 33483495
[9] 马飞飞, 谢正权, 徐永红. 柔性防刺材料、防刺体的结成型方法: 201410025009.8[P]. 2014-01-20.
MA Feifei, XIE Zhengquan, XU Yonghong. A bonding method for flexible stab-resistant materials and extra body: 201410025009.8[P]. 2014-01-20.
[10] 许冬梅, 虎龙, 艾青松, 等. 无纬布型软质防弹防刺服的防护性能研究[J]. 合成纤维, 2018,47(11):24-26.
XU Dongmei, HU Long, AI Qingsong, et al. Research on the protection performance of UD soft bullet-proof and stab-resistant clothing[J]. Synthetic Fiber in China, 2018,47(11):24-26.
[11] 邱茂伟, 王府梅. 机织物透气性能的预测研究[J]. 纺织学报, 2005,26(4):73-75.
QIU Maowei, WANG Fumei. Study on the prediction of woven fabrics air permeability[J]. Journal of Textile Research, 2005,26(4):73-75.
[12] 毕凯. 纺织品透气性检测设备测试结果比较[J]. 科技经济导刊, 2018,26(20):84.
BI Kai. Comparison of testing results of textile air permeability testing equipment[J]. Technology and Economic Guide, 2018,26(20):84.
[1] 陈洁如, 邱诗苑, 杨青青, 周熠. 基于可调张力装置的芳纶织物交织阻力研究[J]. 纺织学报, 2021, 42(01): 67-72.
[2] 李美真, 赵士毅, 冯艳丽, 郭晓卿, 于晓庆. F-12 芳纶织物输送带的制备及其性能[J]. 纺织学报, 2020, 41(12): 87-93.
[3] 陈立富, 于伟东. 人造金刚石填充聚酰亚胺树脂基复合材料防刺性能[J]. 纺织学报, 2020, 41(05): 38-44.
[4] 李聃阳, 王瑞, 刘星, 张淑洁, 夏兆鹏, 阎若思, 代二庆. 剪切增稠液对不同结构芳纶织物防刺性能的影响[J]. 纺织学报, 2020, 41(03): 106-112.
[5] 王新厚, 张琳梅, 孙晓霞. 柔性防刺涤纶/碳化硅织物的制备及其防刺性能[J]. 纺织学报, 2019, 40(06): 171-175.
[6] 杨婉秋, 刘晓艳, 于伟东. 多层防刺材料中间隔织物的缓冲作用[J]. 纺织学报, 2019, 40(04): 51-54.
[7] 谢娇 王家俊 俞秋燕 KHOSO Nazakat Ali 赵佳佳. 碳纳米管/聚合物温差发电复合纺织材料的制备及其性能[J]. 纺织学报, 2018, 39(11): 50-55.
[8] 刘慧慧 王云仪. 纸尿裤服用性能测评研究进展[J]. 纺织学报, 2018, 39(06): 175-182.
[9] 李静 王晓 邵伟 崔永珠 魏春艳. 改性活性染料对涤纶织物的紫外光引发接枝染色[J]. 纺织学报, 2017, 38(11): 91-96.
[10] 邢京京 钱晓明. 织物的防刺机制及刀具形状对防刺性能的影响[J]. 纺织学报, 2017, 38(08): 55-61.
[11] 方东根 沈雷 胡哲. 智能服装材料及其在安全性服装中的应用[J]. 纺织学报, 2015, 36(12): 158-164.
[12] 潘志娟 朱思敏 欧佩玉 眭建华. PTT/绢丝混纺织物的风格及服用性能[J]. 纺织学报, 2014, 35(8): 163-0.
[13] 吴鲜鲜 俞涤美 张红霞 姚佳 康凌峰 祝成炎. 咖啡碳纤维混纺织物的性能[J]. 纺织学报, 2014, 35(7): 48-0.
[14] 王维明 虞波 周丹红 冯云. 碱氧处理对阳离子可染中空聚酯针织物服用性能的影响[J]. 纺织学报, 2014, 35(4): 88-0.
[15] 吴菲非 于高杰 陈雁. 磁性纤维含量对针织面料服用性能的影响[J]. 纺织学报, 2014, 35(3): 27-0.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!