纺织学报 ›› 2020, Vol. 41 ›› Issue (11): 34-40.doi: 10.13475/j.fzxb.20200307207

• 纤维材料 • 上一篇    下一篇

纤维素/氧化纤维素/南极磷虾蛋白复合抗菌纤维的制备与表征

马跃1, 郭静1,2(), 殷聚辉1, 赵秒1,2, 宫玉梅1,2   

  1. 1.大连工业大学 纺织与材料工程学院, 辽宁 大连 116034
    2.辽宁省功能纤维及复合材料工程技术中心, 辽宁 大连 116034
  • 收稿日期:2020-03-27 修回日期:2020-08-15 出版日期:2020-11-15 发布日期:2020-11-26
  • 通讯作者: 郭静
  • 作者简介:马跃(1994—),女,硕士生。主要研究方向为高分子材料加工与改性。
  • 基金资助:
    国家自然科学基金项目(51773024,51373027);辽宁省教育厅科学研究项目(J2020046)

Preparation and characterization of cellulose/dialdehyde cellulose/Antarctic krill protein antibacterial fibers

MA Yue1, GUO Jing1,2(), YIN Juhui1, ZHAO Miao1,2, GONG Yumei1,2   

  1. 1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian, Liaoning 116034, China
    2. Functional Fiber and Composite Materials Engineering Technology Research Center in Liaoning Province, Dalian, Liaoning 116034, China
  • Received:2020-03-27 Revised:2020-08-15 Online:2020-11-15 Published:2020-11-26
  • Contact: GUO Jing

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摘要：

为改善纤维素/磷虾蛋白(C/AKP)复合纤维的可降解性和抗菌性,在原液中加入氧化纤维素(DAC)制备C/DAC/AKP纺丝原液,采用湿法纺丝技术分别在H2SO4/Na2SO4/ZnSO4和H2SO4/Na2SO4/KAl(SO4)2凝固浴中凝固后制得复合纤维,研究了DAC及凝固浴组分对纤维分子间作用、体外降解、抑菌以及热稳定等结构和性能的影响。结果表明:在相同的凝固浴中,相比于C/AKP复合纤维,C/DAC/AKP复合纤维体系内分子间氢键含量从24.26%增加至32.96%,热稳定性提高7.5%,降解性也有所改善;凝固浴中KAl(SO4)2的加入会提高纤维的分子间氢键以及热稳定性,同时C/AKP和C/DAC/AKP复合纤维均具有良好的抗菌效果,在生物材料方面具有良好的应用前景。

关键词: 纤维素, 南极磷虾蛋白, 氧化纤维素, 湿法纺丝, 抗菌性, 抗菌纤维

Abstract:

In order to improve the degradability and antibacterial properties of cellulose/krill protein (C/AKP) composite fibers, C/DAC/AKP spinning solutions were prepared by adding dialdehyde cellulose (DAC) into the C/AKP solution. Fibers were produced from the C/DAC/AKP spinning solution using wet spinning technology, which was coagulated in H2SO4/Na2SO4/ZnSO4 and H2SO4/Na2SO4/KAl(SO4)2 coagulation bath. The effects of DAC and coagulation bath components on the structures and properties of the fibers, such as intermolecular action, in vitro degradation, bacteriostasis and thermal stability, were investigated. The results show that using the same coagulation bath, the C/DAC/AKP composite fibers, demonstrate an increase of 24.26% to 32.96% in intermolecular hydrogen bonds in the system and a 7.5% increase in thermal stability compared to that for the C/AKP composite fibers, together with improved degradability. It is also made clear that the addition of KAl(SO4)2 in the coagulation bath improves the intermolecular hydrogen bond content and thermal stability of the fibers. It is illustrated that both C/AKP and C/DAC/AKP composite fibers have good antibacterial activity, and have good application prospects for biomaterials.

Key words: cellulose, Antarctic krill protein, dialdehyde cellulose, wet spinning, antibacterial property, antibacterial fiber

中图分类号: 

  • TQ340.41

图1

C、DAC、AKP和DAC/AKP的红外光谱图"

图2

C/DAC/AKP和C/AKP复合纤维的红外光谱图"

表1

不同凝固浴制备的C/DAC/AKP和C/AKP复合纤维氢键拟合结果"

纤维编号 氢键类型 键名 波数/cm-1 平均峰面积 氢键比例/% 总氢键比例/%
C/DAC/AKP-1 自由羟基 —OH 3 633 3.26 3.76 3.76
分子内氢键 OH…OH 3 442 53.83 62.06 63.27
多聚体 3 113 1.05 1.21
分子间氢键 OH…π 3 569 10.48 12.08 32.96
OH…醚O 3 245 17.85 20.58
OH…N 3 061 0.26 0.30
C/DAC/AKP-2 自由羟基 —OH 3 614 4.30 5.97 5.97
分子内氢键 OH…OH 3 432 43.08 59.73 61.03
多聚体 3 118 0.94 1.30
分子间氢键 OH…π 3 545 11.02 15.28 33.00
OH…醚O 3 247 12.55 17.40
OH…N 3 063 0.23 0.32
C/AKP-1 自由羟基 —OH 3 643 0.98 1.19 1.19
分子内氢键 OH…OH 3 437 58.99 71.55 74.55
多聚体 3 125 2.47 3.00
分子间氢键 OH…π 3 578 9.39 11.39 24.26
OH…醚O 3 237 10.19 12.37
OH…N 3 061 0.41 0.50
C/AKP-2 自由羟基 —OH 3 635 2.06 2.58 2.58
分子内氢键 OH…OH 3 442 51.92 65.06 66.57
多聚体 3 110 1.24 1.51
分子间氢键 OH…π 3 576 8.69 10.89 30.85
OH…醚O 3 238 15.63 19.59
OH…N 3 056 0.29 0.37

图3

C/DAC/AKP和C/AKP复合纤维的热稳定性曲线"

图4

C/DAC/AKP和C/AKP复合纤维的表面形貌(×200)"

图5

C/DAC/AKP及C/AKP复合纤维的降解率"

图6

C/DAC/AKP及C/AKP复合纤维的结晶曲线"

图7

C/DAC/AKP和C/AKP复合纤维的抗菌效果图"

图8

C/DAC/AKP复合纤维的EDS能谱图"

图9

C/AKP复合纤维的EDS能谱"

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