磁控溅射纳米膜与不同纺织基材的结合牢度

doi:10.13475/j.fzxb.20201008308

纺织学报 ›› 2021, Vol. 42 ›› Issue (02): 135-141.doi: 10.13475/j.fzxb.20201008308

磁控溅射纳米膜与不同纺织基材的结合牢度

刘明雪¹, 赵倩¹, 王晓辉¹, 刘琼溪²^,³, 邵建中¹()

1.浙江理工大学生态染整技术教育部工程研究中心, 浙江杭州 310018
2.广东欣丰科技有限公司, 广东江门 529300
3.北京纳米生色科技有限公司, 北京 100089

收稿日期:2020-10-29 修回日期:2020-11-21 出版日期:2021-02-15 发布日期:2021-02-23
通讯作者: 邵建中
作者简介:刘明雪(1994—),女,硕士生。主要研究方向为生态染整技术。
基金资助:
国家自然科学基金项目(51773181)

Bonding fastness of magnetron sputtering nano-films with various textile substrates

LIU Mingxue¹, ZHAO Qian¹, WANG Xiaohui¹, LIU Qiongxi²^,³, SHAO Jianzhong¹()

1. Engineering Research Centre for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
2. Guangdong Rising Well Science & Technology Co., Ltd., Jiangmen, Guangdong 529300, China
3. Beijing Nano Color Science and Technology Co., Ltd., Beijing 100089, China

Received:2020-10-29 Revised:2020-11-21 Online:2021-02-15 Published:2021-02-23
Contact: SHAO Jianzhong

摘要/Abstract

摘要：

针对天然纤维基材上磁控溅射纳米膜易整层脱落问题,系统测试了不同纤维基材上磁控溅射结构生色膜的耐摩擦色牢度和耐皂洗色牢度,研究了样品的初始含水率和低温等离子体表面改性对磁控溅射膜与纤维基材结合牢度的影响,进而借助扫描电子显微镜并结合纤维材料的理化性能分析得出磁控溅射膜与各种纺织基材结合牢度不同的原因。结果表明:热塑性的涤纶存在软化点,磁控溅射高能粒子沉积到纤维表面时动能转化为热能,使涤纶局部达到软化点,粘结溅射粒子;棉和蚕丝没有软化点,纤维对磁控溅射粒子无熔融粘结作用,且棉和蚕丝具有高吸湿溶胀性,皂洗过程中水分子的侵入削弱纤维和纳米粒子间的作用力,致使磁控溅射膜易脱落。

关键词: 磁控溅射, 纺织基材, 结合牢度, 结构生色, 低温等离子体, 含水率, 物理生色

Abstract:

To address the problem that the magnetron sputtering nano-films on natural fiber substrates are prone to whole layer shedding, the rubbing fastness and soaping of the magnetron sputtering structural color films on different fiber substrates were systematically tested, and the effects of the initial moisture content and the low-temperature plasma surface modification on the bonding fastness of the magnetron sputtering films to the fiber substrates were investigated in detail. The underlying reasons for the different bonding fastness of the magnetron sputtering films to different fiber substrates were studied by means of scanning electron microscope analysis technique combined with the analysis on physical and chemical properties of different fiber materials. The results show that due to the softening point of the thermoplastic polyester fiber, the kinetic energy of the energetic magnetron sputtered particles is converted into thermal energy when they are deposited on the fiber surface, causing the polyester fibers to locally reach the softening point and bonding the sputtered particles. On the contrary, cotton and silk fibers have no softening point, so the fibers have no melt-bonding effect on the magnetron sputtering particles. In addition, as cotton and silk fibers have hygroscopic swelling properties, the intrusion of water molecules during the soaping process weakens the interaction force between the fibers and nanoparticles, causing the easy shedding of the magnetron sputtering nano-films.

Key words: magnetron sputtering, textile substrate, bonding fastness, structural coloration, low temperature plasma, moisture content, physical coloration

中图分类号:

TS193.5

刘明雪, 赵倩, 王晓辉, 刘琼溪, 邵建中. 磁控溅射纳米膜与不同纺织基材的结合牢度[J]. 纺织学报, 2021, 42(02): 135-141.

LIU Mingxue, ZHAO Qian, WANG Xiaohui, LIU Qiongxi, SHAO Jianzhong. Bonding fastness of magnetron sputtering nano-films with various textile substrates[J]. Journal of Textile Research, 2021, 42(02): 135-141.

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织物基材	耐摩擦色牢度		耐皂洗色牢度
织物基材	干摩	湿摩	耐皂洗色牢度
涤纶仿蚕丝^a	5	4~5	3~4
涤纶仿蚕丝^b	5	4~5	3~4
涤纶欧根纱^a	5	4	3~4
涤纶欧根纱^b	5	4~5	3~4
棉斜纹^a	4~5	4	0
棉斜纹^b	4	4	0
棉平纹^a	4	4	0
棉平纹^b	4	4	0
蚕丝斜纹绸^a	4~5	4	0
蚕丝斜纹绸^b	4	4	0
蚕丝缎纹^a	4	4	0
蚕丝缎纹^b	4	4	0

织物基材	初始含水率/%
织物基材	0	10	30	50	70	90
涤纶	3~4	3~4	3~4	3~4	3~4	3~4
棉	0	0	0	0	0	0
蚕丝	0	0	0	0	0	0

织物基材	未处理	氧等离子体处理
涤纶	3~4	4
棉	0	0
蚕丝	0	0

磁控溅射纳米膜与不同纺织基材的结合牢度

Bonding fastness of magnetron sputtering nano-films with various textile substrates

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