锦纶/棉混纺织物的耐久无氟拒水整理

doi:10.13475/j.fzxb.20200905907

纺织学报 ›› 2021, Vol. 42 ›› Issue (03): 14-20.doi: 10.13475/j.fzxb.20200905907

• 特约专栏:针织物全流程平幅印染技术 • 上一篇下一篇

锦纶/棉混纺织物的耐久无氟拒水整理

卢雪¹, 刘秀明¹(), 房宽峻¹^,², 李瀚宇³, 李翔⁴, 高闯¹

1.天津工业大学纺织科学与工程学院, 天津 300387
2.青岛大学纺织服装学院, 山东青岛 266071
3.中国纺织科学研究院有限公司, 北京 100025
4.北京中纺化工股份有限公司, 北京 100176

收稿日期:2020-09-22 修回日期:2020-12-21 出版日期:2021-03-15 发布日期:2021-03-17
通讯作者: 刘秀明
作者简介:卢雪(1997—),女,硕士生。主要研究方向为纺织品表面化学处理。
基金资助:
国家重点研发计划项目(2017YFB0309700)

Durable fluoride-free water-repellent finishing of polyamide/cotton blended fabric

LU Xue¹, LIU Xiuming¹(), FANG Kuanjun¹^,², LI Hanyu³, LI Xiang⁴, GAO Chuang¹

1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
2. School of Textiles and Clothing, Qingdao University, Qingdao, Shandong 266071, China
3. China Textile Academy, Beijing 100025, China
4. Beijing CTA Textile Chemicals Co., Ltd., Beijing 100176, China

Received:2020-09-22 Revised:2020-12-21 Online:2021-03-15 Published:2021-03-17
Contact: LIU Xiuming

摘要/Abstract

摘要：

为满足锦纶/棉混纺织物用于户外运动产品的特殊要求,采用无氟拒水剂CWR-9A对混纺织物进行拒水涂层处理,并选取黏合剂来进一步提高拒水剂与织物间的粘接牢度。探讨了拒水剂质量浓度、焙烘时间、焙烘温度、黏合剂种类、黏合剂与拒水剂体积比、洗涤次数等对混纺织物拒水效果的影响,得到锦纶/棉混纺织物拒水整理最佳工艺:CWR-9A质量浓度为120 g/L,焙烘温度为170 ℃,焙烘时间为90 s,黏合剂BD-01与拒水剂CWR-9A的体积比为1∶20。对整理后织物的表面结构和形貌进行了表征,测定了整理后织物的接触角、拒水等级等。结果表明:黏合剂BD-01的引入可显著提高无氟拒水剂与混纺织物的粘接牢度,其接触角最高为138°,拒水等级最高达到5级。

关键词: 无氟拒水剂, 锦纶/棉混纺织物, 黏合剂, 拒水整理, 粘接牢度

Abstract:

In order to meet the special requirements of polyamide/cotton blended fabrics for outdoor sports end-uses, the blended fabrics were coated with fluorine-free water-repellent agent (CWR-9A), and an adhesive was added to further improve the adhesion fastness between the water-repellent and the fabric. The effect of water-repellent mass concentration, baking time, baking temperature, adhesive type, different volume ratios of adhesives and CWR-9A, washing times were studied on water-repellent treated fabrics. For the polyamide/cotton blended fabrics, the optimal water-repellent finishing process is 120 g/L CWR-9A, temperature at 170 ℃, baking time duration 90 s, and the volume ratio of BD-01 to CWR-9A is 1∶20. The surface structure and morphology of the water-repellent agent and treated fabric were characterized, and the contact angle and water-repellent grade of the treated fabric were measured. The results indicate that adhesion fastness between polyamide/cotton blended fabrics treated with adhesive BD-01 and water repellent CWR-9A is significantly improved. The maximum contact angle is 138°, and the water-repellent grade reaches level 5.

Key words: fluorine-free water-repellent agent, polyamide/cotton blended fabric, adhesive, water repellent finishing, adhesion fastness

中图分类号:

TS195.2

卢雪, 刘秀明, 房宽峻, 李瀚宇, 李翔, 高闯. 锦纶/棉混纺织物的耐久无氟拒水整理[J]. 纺织学报, 2021, 42(03): 14-20.

LU Xue, LIU Xiuming, FANG Kuanjun, LI Hanyu, LI Xiang, GAO Chuang. Durable fluoride-free water-repellent finishing of polyamide/cotton blended fabric[J]. Journal of Textile Research, 2021, 42(03): 14-20.

图/表 10

图1

图2

图3

图4

表1

表2

图5

表3

表4

图6

参考文献 24

[1]	张华, 秦雅伟, 周永凯. 锦纶/棉混纺织物的热湿舒适性研究[J]. 棉纺织技术, 2016,44(8):27-30.
	ZHANG Hua, QIN Yawei, ZHOU Yongkai. Research on thermal and wet comfort of nylon-cotton blended fabrics[J]. Cotton Textile Technology, 2016,44(8):27-30.
[2]	李昌龄, 王文聪, 华东, 等. 锦纶基磁性纤维的制备及其性能[J]. 纺织学报, 2019,40(11):26-31,37.
	LI Changling, WANG Wencong, HUA Dong, et al. Preparation and properties of nylon-based magnetic fiber[J]. Journal of Textile Research, 2019,40(11):26-31,37.
[3]	颜东, 邓继勇, 汪南方, 等. 有机硅改性聚氨酯/丙烯酸酯共聚乳液对棉织物的抗皱整理[J]. 纺织学报, 2018,39(1):89-93.
	YAN Dong, DENG Jiyong, WANG Nanfang, et al. Anti-wrinkle finishing of cotton fabric by silicone modified polyurethane/acrylate copolymer emulsion[J]. Journal of Textile Research, 2018,39(1):89-93.
[4]	欧卫国, 杨小玲, 蔡云芸, 等. 纯棉织物的拒水拒油易去污整理[J]. 纺织科技进展, 2019(5):17-19.
	OU Weiguo, YANG Xiaoling, CAI Yunyun, et al. Water and oil repellent and easy stain removal finishing of cotton fabrics[J]. Progress in Textile Science and Technology, 2019 (5):17-19.
[5]	秦雅伟, 周永凯, 张华. 涤/棉、锦/棉混纺纱线的性能优化研究[J]. 纺织导报, 2015(10):88-90,92.
	QIN Yawei, ZHOU Yongkai, ZHANG Hua. Study on the performance optimization of polyester/cotton, nylon/cotton blended yarns[J]. China Textile Leader, 2015(10):88-90,92.
[6]	DU J, ZHANG L, DONG J, et al. Preparation of hydrophobic nylon fabric[J]. Journal of Engineered Fibers & Fabrics, 2016,11(1):31-37.
[7]	张阳, 王瑄, 沈兰萍, 等. 锦棉户外织物的拒水拒油整理[J]. 合成纤维, 2016,45(6):42-44,48.
	ZHANG Yang, WANG Xuan, SHEN Lanping, et al. Water and oil repellent finishing of nylon cotton outdoor fabric[J]. Synthetic Fiber in China, 2016,45(6):42-44,48.
[8]	赵晓明, 刘宝成, 王锡晨, 等. 混纺拒水拒油织物的开发[J]. 纺织科学与工程学报, 2018,35(2):26-29.
	ZHAO Xiaoming, LIU Baocheng, WANG Xichen, et al. Development of water- and oil-repellent blended fabrics[J]. Journal of Textile Science and Engineering, 2018,35(2):26-29.
[9]	赵汇生, 狄剑锋. 织物的拒水拒油透气整理[J]. 中国个体防护装备, 2001(3):17-19.
	ZHAO Huisheng, DI Jianfeng. Water and oil repellent breathable finishing of fabrics[J]. China Personal Protective Equipment, 2001(3):17-19.
[10]	陆妙停. 织物拒水拒油整理综述[J]. 上海丝绸, 2001(3):14-19.
	LU Miaoting. Summary of water and oil repellent finishing of fabrics[J]. Shanghai Silk, 2001 (3):14-19.
[11]	张建国, 陈晓妹, 卢霜, 等. 无氟防水剂DM-3696在化纤面料上的应用[J]. 印染助剂, 2019,36(8):55-57.
	ZHANG Jianguo, CHEN Xiaomei, LU Shuang, et al. Application of fluorine-free waterproofing agent DM-3696 on chemical fiber fabrics[J]. Textile Auxiliaries, 2019,36(8):55-57.
[12]	顾浩, 韩杰, 杨皓, 等. 防水整理剂的发展与应用现状[J]. 纺织导报, 2019(4):20-22,24-26.
	GU Hao, HAN Jie, YANG Hao, et al. Development and application status of waterproof finishing agent[J]. China Textile Leader, 2019(4):20-22,24-26.
[13]	陈荣圻. PFOS的禁用及相关产品的替代[J]. 印染, 2008(18):41-44.
	CHEN Rongqi. Prohibition of PFOS and replacement of related products[J]. China Dyeing & Finishing, 2008 (18):41-44.
[14]	宋泽华, 李翔. 无氟防水剂对织物与粘合衬剥离强度的影响[J]. 纺织科学研究, 2019(5):77-79.
	SONG Zehua, LI Xiang. Effects of fluorine-free waterproofing agents on the peel strength of fabrics and adhesive backings[J]. Textile Science Research, 2019 (5):77-79.
[15]	王宝敬, 冼润媚, 王铁群. 无氟防水剂HIT-FM WFF在棉梭织布防水整理中的应用[J]. 印染助剂, 2016,33(7):53-56.
	WANG Baojing, XIAN Runmei, WANG Tiequn. Application of fluorine-free waterproofing agent HIT-FM WFF in waterproof finishing of cotton woven fabrics[J]. Textile Auxiliaries, 2016,33(7):53-56.
[16]	黄晨, 柯勤飞, 李祖安, 等. 纯棉水刺非织造材料的单向导水无氟整理[J]. 纺织学报, 2019,40(7):119-127.
	HUANG Chen, KE Qinfei, LI Zu'an, et al. One-way water-free fluorine-free finishing of pure cotton spunlacenon wovens[J]. Journal of Textile Research, 2019,40(7):119-127.
[17]	艾丽, 朱亚伟. 黏合剂的合成及其在分散蓝79微水印花中的应用[J]. 纺织学报, 2019,40(6):50-57.
	AI Li, ZHU Yawei. The synjournal of adhesive and its application in disperse blue 79 micro-water printing[J]. Journal of Textile Research, 2019,40(6):50-57.
[18]	孟令川. 环保型无氟无硅拒水剂DM-3616在纯棉机织物上的应用研究[D]. 上海:东华大学, 2014: 21-24.
	MENG Lingchuan. Study on the application of environmentally friendly fluoride-free and silicon-freewater repellent DM-3616 on cotton woven fabrics[D]. Shanghai: Donghua University, 2014: 21-24.
[19]	钱海洪. 短链含氟丙烯酸酯拒水拒油整理剂的制备及其应用研究[D]. 无锡:江南大学, 2018: 18-32.
	QIAN Haihong. Preparation and application of water-repellent and oil-repellent finishing agents for short-chain fluorine-containing acrylates[D]. Wuxi: Jiangnan University, 2018: 18-32.
[20]	LIU X, ZOU X, GE Z, et al. Novel waterborne polyurethanes containing long-chain alkanes: their synjournal and application to water repellency[J]. RSC Advances, 2019,9(54):31357-31369.
[21]	董永春. 纺织品整理剂的性能与应用[M]. 北京: 中国纺织出版社, 1999: 80-100.
	DONG Yongchun. Performance and application of textile finishing agent[M]. Beijing: China Textile & Apparel Press, 1999: 80-100.
[22]	LUO X, WENG Y, WANG S, et al. Superhydrophobic and oleophobic textiles with hierarchical micro-nano structure constructed by sol-gel method[J]. Journal of Sol-Gel Science and Technology, 2019,89(3):820-829.
[23]	钱海洪, 杜金梅, 傅佳佳, 等. 短链含氟丙烯酸酯拒水拒油剂的合成及应用[J]. 高分子材料科学与工程, 2019,35(2):22-28.
	QIAN Haihong, DU Jinmei, FU Jiajia, et al. Synjournal and application of water-repellent and oil-repellent agents for short-chain fluorine-containing acrylates[J]. Polymer Materials Science and Engineering, 2019,35(2):22-28.
[24]	ZENG T C, ZHANG P F, LI X X, et al. Facile fabrication of durable superhydrophobic and oleophobic surface on cellulose substrate via thiol-ene click modification[J]. Applied Surface Science, 2019,493:1004-1012.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

织物	接触角/(°)	拒水等级/级
洗涤前	135	4
洗涤1次后	129	0

黏合剂种类	接触角/(°)
468	129
468B	127
1901R	132
3602	131
FK-C	—
DF-891B	136
BD-01	138
TF-313E	—

水洗次数	水洗时间/min	接触角/(°)
1	30	137
2	60	135
3	90	133
4	120	132
5	150	130

织物类型	拒水等级/级
原布	0
CWR-9A整理	4
CWR-9A整理后水洗	0
BD-01与CWR-9A整理	5
BD-01与CWR-9A整理后水洗	4~5

锦纶/棉混纺织物的耐久无氟拒水整理

Durable fluoride-free water-repellent finishing of polyamide/cotton blended fabric

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 24

相关文章 13

Metrics

本文评价

推荐阅读 0

[1]	蔡露, 康佳良, 吕存, 何雪梅. 自交联氟化聚丙烯酸酯乳液的制备及其应用性能[J]. 纺织学报, 2021, 42(02): 161-167.
[2]	艾丽, 朱亚伟. 黏合剂的合成及其在分散蓝79微水印花中的应用[J]. 纺织学报, 2019, 40(06): 50-57.
[3]	艾丽曹红梅朱亚伟丁志平. 基于液体分散染料的微量印花技术[J]. 纺织学报, 2018, 39(09): 77-83.
[4]	吴海婷蒋小娟蔡再生. 环保阻燃型静电植绒黏合剂的合成及其应用[J]. 纺织学报, 2018, 39(06): 96-100.
[5]	杜晗笑郑振荣曹森学陈逢亮. 超疏水气凝胶涂层超高分子量聚乙烯织物的制备与表征[J]. 纺织学报, 2018, 39(04): 93-99.
[6]	李继丰杜兆芳董丹丹颜家俊许云辉梅毓. 聚丙烯非织造布拒水整理对葡萄套袋微环境的影响[J]. 纺织学报, 2017, 38(07): 101-106.
[7]	冯艳荣袁剑民王文力李伟. 水性聚丙烯酸酯涂料染色黏合剂的合成及其性能[J]. 纺织学报, 2017, 38(04): 90-96.
[8]	明悦陈英车迪. 纳米微晶纤维素的制备及其在拒水整理中的应用[J]. 纺织学报, 2016, 37(06): 1-6.
[9]	龚小舟郭依伦吴中伟高虹姜联栋陈晓钢. 经编间隔织物多层复合材料的防刺性能[J]. 纺织学报, 2014, 35(5): 55-0.
[10]	汪澜;顾相军;吴明华;林俊雄. 无皂黏合剂乳液的合成及其在静电植绒中的应用[J]. 纺织学报, 2010, 31(1): 68-75.
[11]	董俊哲;房宽峻;张霞;付少海;田安丽;王潮霞;蒋学. GMA改性聚丙烯酸酯黏合剂的应用[J]. 纺织学报, 2007, 28(7): 62-64.
[12]	孙世元;赵庆福;薛元;姜晓巍;窦海萍. 耐久型拒水PP/PE热黏合纤维的研制[J]. 纺织学报, 2007, 28(2): 14-16.
[13]	王凌;胡望明. 涤纶水刺非织造布的拒水整理与性能测试[J]. 纺织学报, 2007, 28(1): 84-86.