纺织学报 ›› 2021, Vol. 42 ›› Issue (03): 143-148.doi: 10.13475/j.fzxb.20200501806

• 染整与化学品 • 上一篇    下一篇

磁控溅射Ag/ZnO纳米薄膜涤纶织物的制备及其性能

孟灵灵1(), 魏取福2, 严忠杰1, 仲珍珍1, 王小慧1, 沈佳宇1, 陈洪炜1   

  1. 1.盐城工学院 纺织服装学院, 江苏 盐城 224051
    2.生态纺织教育部重点实验室(江南大学), 江苏 无锡 214122
  • 收稿日期:2020-05-08 修回日期:2020-12-26 出版日期:2021-03-15 发布日期:2021-03-17
  • 作者简介:孟灵灵(1980—),女,博士,副教授。主要研究方向为功能纳米纺织材料。E-mail: mllwx1022@163.com
  • 基金资助:
    江苏省生态环保重点实验室开放课题项目(JH201832);盐城市科技局项目(YKN2015011);中国纺织工业联合会科技指导性项目(2014052,2016044)

Preparation and properties of Ag/ZnO composite film deposited polyester fabrics by magnetron sputtering

MENG Lingling1(), WEI Qufu2, YAN Zhongjie1, ZHONG Zhenzhen1, WANG Xiaohui1, SHEN Jiayu1, CHEN Hongwei1   

  1. 1. College of Textile & Clothing, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
    2. Key Laboratory of Eco-Textiles(Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2020-05-08 Revised:2020-12-26 Online:2021-03-15 Published:2021-03-17

摘要:

为探讨织物结构对表面沉积纳米复合薄膜形貌及性能的影响,采用直流射频共溅法,以不同组织结构纯涤纶织物为基材,分别以金属银(Ag)与锌(Zn)为靶材,制备Ag/ZnO纳米薄膜。对表面沉积Ag/ZnO薄膜的涤纶织物的形貌结构,沉积颜色、防紫外线性能及电磁屏蔽性能进行表征。实验结果表明:非织造布表面薄膜颗粒分布较为均匀,机织布表面纳米颗粒最不平整,针织布表面纳米颗粒粒径较小,并存在部分团簇颗粒;试样表面Ag衍射峰较明显,但ZnO依然以非晶态形式存在;针织布表面沉积Ag/ZnO薄膜后,其明度最小,颜色较暗;以非织造布为基材的试样其防紫外线性能及电磁屏蔽效果最明显。

关键词: 涤纶, 织物结构, Ag/ZnO纳米薄膜, 磁控溅射, 防紫外线性能, 电磁屏蔽性能, 功能纺织品

Abstract:

In order to study the effect of polyester fabric structure on the morphology and performance of nanocomposite film deposited on the surface of fabrics, direct current (DC) and radio frequency (RF)co-sputtering methods were used to prepare Ag/ZnO films with knitted polyester fabrics of different structures as the substrate and metallic silver and zinc oxide as targets respectively. By using field emission scanning electron microscope, X-ray diffractometer, photoelectron spectrometer, computer measurement and matching system, ultraviolet transmittance tester, electromagnetic radiation tester, the films were evaluated in terms of surface structure, color analysis, UV protection and electromagnetic shielding performance. The experimental results show that the particle size of the film on the surface of the nonwoven fabric is more uniform, the surface of the woven fabric is less smooth, the surface particle of the knitted fabric is smaller, and some particle amalgamation are found. Diffraction peaks with Ag are more obvious, but ZnO still exists in amorphous form. After depositing Ag/ZnO film on the surface of knitted fabric, its brightness is the lowest and the color is dark. The samples with nonwoven fabric as substrate demonstrate the most obvious ultraviolet resistance and electromagnetic shielding effect.

Key words: polyester, fabric structure, Ag/ZnO nanocomposite film, magnetron sputtering, ultraviolet resistance, electromagnetic shielding, functional textiles

中图分类号: 

  • TS174

图1

涤纶织物的SEM照片(×150)"

图2

涤纶织物孔径大小及其分布"

图3

涤纶织物表面沉积Ag/ZnO薄膜的SEM照片(×30 000)"

图4

不同基材表面沉积Ag/ZnO薄膜的XRD谱图"

表1

试样的L*、 a*与b*值"

基材名称 L* a* b*
非织造布基材 64.68 10.3 1.06
机织布基材 78.44 0.19 5.31
针织布基材 53.39 3.59 8.28

图5

涤纶织物基材表面沉积Ag/ZnO薄膜的照片"

图6

涤纶织物表面沉积Ag/ZnO薄膜的a*、b*色度值分布图"

图7

涤纶织物基材表面沉积Ag/ZnO薄膜的透射率曲线"

图8

涤纶织物基材表面沉积Ag/ZnO薄膜的屏蔽效能"

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