纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 129-136.doi: 10.13475/j.fzxb.20200703808

• 染整与化学品 • 上一篇    下一篇

家庭洗涤对免烫棉织物性能的影响

郭恒1,2,3, 黄宏博3, 姚金波1,2, 姜会钰1,2, 夏治刚3, 王运利1,2,3()   

  1. 1.武汉纺织大学 化学与化工学院, 湖北 武汉 430200
    2.武汉纺织大学 生物质纤维和生态染整湖北省重点实验室, 湖北 武汉 430200
    3.武汉纺织大学 纺织新材料与先进加工技术国家重点实验室, 湖北 武汉 430200
  • 收稿日期:2020-07-15 修回日期:2021-04-02 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 王运利
  • 作者简介:郭恒(1995—),男,硕士生。主要研究方向为纺织品的功能整理。
  • 基金资助:
    国家重点研发计划项目(2017YFB0309200)

Effect of household washing on properties of anti-creasing cotton fabrics

GUO Heng1,2,3, HUANG Hongbo3, YAO Jinbo1,2, JIANG Huiyu1,2, XIA Zhigang3, WANG Yunli1,2,3()   

  1. 1. College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing, Wuhan Textile University, Wuhan, Hubei 430200, China
    3. State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
  • Received:2020-07-15 Revised:2021-04-02 Published:2021-07-15 Online:2021-07-22
  • Contact: WANG Yunli

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摘要：

为探究多元羧酸免烫棉织物在日常洗涤过程中免烫性能的保持情况,实验模拟了日常家庭洗涤的环境,对免烫棉织物在不同的洗涤助剂类型、不同洗涤温度、不同洗涤次数下进行洗涤处理。通过测试对比原免烫织物和不同方式洗涤后免烫棉织物的折皱回复角、断裂强力和化学结构表面形貌等,对免烫棉织物的免烫性能在洗涤过程中的保持能力进行分析。结果表明:经重复洗涤,免烫棉织物的断裂强力和折皱回复角都呈现出不同程度的降低;纤维的表面形貌及微观结构都产生了一定的变化;经80 ℃混合溶液重复洗涤处理50次后的断裂强力下降约26%,折皱回复角降低约50%;对免烫棉织物而言,在家庭洗涤过程中,高温复合重复洗涤对其免烫性能的破坏作用较大。

关键词: 家庭洗涤, 免烫棉织物, 免烫性能, 折皱回复角, 断裂强力, 多元羧酸

Abstract:

In order to study the maintenance of anti-creasing property of polycarboxylic acid anti-creasing treated cotton fabrics in the daily washing process,experiments were carried out to simulate the environment of daily household washing, where the anti-creasing cotton fabrics were washed under different detergent types, different wash-temperatures, and different wash-times. The wrinkle recovery angle, breaking strength and surface morphology of the original and post-washing fabrics were tested and compared, and the anti-creasing property of anti-creasing cotton fabrics during the washing process was analyzed.The results of the study show that after repeated washing, the wrinkle recovery angle and breaking strength of anti-creasing cotton fabrics are reduced, and the surface morphology and microstructure of the fibers demonstrate certain changes. After repeated washing of the mixed solution at 80 ℃ for 50 times, the breaking strength is reduced by about 26%, and the wrinkle recovery angle of the sample is reduced by about 50%. For anti-creasing cotton fabrics in the household washing process, high-temperature composite repeated washing show a greater destructive effect on its anti-creasing property.

Key words: household washing, anti-creasing cotton fabric, anti-creasing property, wrinkle recovery angle, breaking strength, polycarboxylic acid

中图分类号: 

  • TS195.2

表1

标准洗涤溶液配方"

洗涤液类别 洗涤液中助剂种类及质量浓度
次氯酸钠洗涤液 次氯酸钠试剂(0.5 mg/L),十二烷基苯磺酸钠(1 g/L)
蛋白酶洗涤液 蛋白酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)
脂肪酶洗涤液 脂肪酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)
复合洗涤液 次氯酸钠(0.5 mg/L),蛋白酶(0.05 g/L),脂肪酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)

表2

BTCA整理前后棉织物的性能"

织物种类 断裂强力/N 折皱回复角/(°)
原棉织物 231.4 65.4
BTCA免烫棉织物 138.7 130.7

图1

不同条件下多次洗涤后免烫棉织物的折皱回复角"

图2

不同条件下多次洗涤后免烫棉织物的断裂强力"

图3

洗涤前后免烫棉织物的表面形貌"

图4

不同温度下3种溶液洗涤处理50次后免烫棉织物的表面形貌(×1 000)"

图5

80 ℃条件下重复洗涤50次前后免烫棉织物的红外光谱"

图6

80 ℃条件下洗涤50次前后免烫棉织物的XRD图谱"

图7

不同方式洗涤处理免烫棉织物的热重曲线"

[1] 侯文双, 闵洁, 纪峰, 等. 织物紧度和抗皱整理工艺对纯棉机织物折皱回复性的影响[J]. 纺织学报, 2021, 42(1):118-124.
HOU Wenshuang, MIN Jie, JI Feng, et al. Influence of fabric tightness and anti-crease finishing on wrinkle recovery of pure cotton woven fabrics[J]. Journal of Textile Research, 2021, 42(1):118-124.
[2] 刘宇, 沈一峰, 杨雷. 新型无甲醛防皱整理剂BTP400在棉织物上的应用[J]. 纺织学报, 2016, 37(8):77-82.
LIU Yu, SHEN Yifeng, YANG Lei. Anti-crease finishing of cotton fabric with formaldehyde-free agent BTP400[J]. Journal of Textile Research, 2016, 37(8):77-82.
[3] 黄张秘, 周翔, 邢志奇, 等. 棉织物的聚羧酸无甲醛免烫整理[J]. 纺织学报, 2017, 38(1):94-99.
HUANG Zhangmi, ZHOU Xiang, XING Zhiqi, et al. Formaldehyde-free durable press finishing of cotton fabric with polycarboxylic acid[J]. Journal of Textile Research, 2017, 38(1):94-99.
[4] 肖慧, 阎克路, 纪柏林. 糖类添加剂在1, 2, 3, 4-丁烷四羧酸棉织物防皱整理中的应用[J]. 纺织学报, 2018, 39(7):89-94.
XIAO Hui, YAN Kelu, JI Bolin. Application of carbohydrate additives in 1, 2, 3, 4-butanetetracarboxylic acid anti-wrinkle finishing of cotton fabrics[J]. Journal of Textile Research, 2018, 39(7):89-94.
[5] 杨书会, 王瑞. 纯棉织物折皱回复角与其组织结构参数的关系[J]. 纺织学报, 2017, 38(4):46-49.
YANG Shuhui, WANG Rui. Relationship between pure cotton fabric's wrinkle recovery angle and its organizational structure parameters[J]. Journal of Textile Research, 2017, 38(4):46-49.
[6] 苏旭中, 魏艳红, 刘新金, 等. 纺纱方式对织物抗皱性能及拉伸弹性的影响[J]. 纺织学报, 2020, 41(4):33-38.
SU Xuzhong, WEI Yanhong, LIU Xinjin, et al. Effect of spinning method on wrinkle-resistance and tensile elasticity of fabric[J]. Journal of Textile Research, 2020, 41(4):33-38.
[7] 魏艳红, 刘新金, 谢春萍, 等. 聚酯长丝/棉复合纱斜纹织物的保形性及服用性能[J]. 纺织学报, 2019, 40(12):39-44.
WEI Yanhong, LIU Xinjin, XIE Chunping, et al. Shape retention and wearing properties of polyester filament/cotton composite yarn twill fabrics[J]. Journal of Textile Research, 2019, 40(12):39-44.
[8] 张亚惠. 免烫和阻燃织物在使用过程中功能衰败的研究[D]. 大连:大连工业大学, 2005: 4-8.
ZHANG Yahui. Research on the functional decline of anti-crease and flame retardant fabrics during use[D]. Dalian: Dalian Polytechnic University, 2005: 4-8.
[9] 胡霄睿, 孙丰鑫, 肖彩勤, 等. 基于原位力学测试的织物折皱回复性表征[J]. 纺织学报, 2020, 41(10):41-45.
HU Xiaorui, SUN Fengxin, XIAO Caiqin, et al. Characterization of wrinkle recovery of fabrics based on in-situ mechanical testing[J]. Journal of Textile Research, 2020, 41(10):41-45.
[10] HURREN A, WILCOCK A, SLATER K. The effects of laundering and abrasion on the tensile strength of chemically treated cotton print cloth[J]. Journal of The Textile Institute, 1985, 76(4):285-288.
doi: 10.1080/00405008508658511
[11] RAHEEL M. Effects of laundering on wear life of chemically treated cotton broad cloth[J]. Textile Chemists and Colorist, 1983, 15(11):23-29.
[12] CHUNG C, LCC M, CHOC E K. Characterization of cotton fabric scouring by FT-IR ATR spectroscopy[J]. Carbohydrate Polymers, 2004, 58:417-420.
doi: 10.1016/j.carbpol.2004.08.005
[13] JI Bolin, TANG Peixin, YAN Kelu, et al. Catalytic actions of alkaline salts in reactions between 1,2,3,4-butanetetracarboxylic acid and cellulose: II: esterification[J]. Carbohydrate Polymers, 2015, 132:228-236.
doi: 10.1016/j.carbpol.2015.06.070 pmid: 26256345
[14] 刘晓云, 邵建中. 棉织物的耐久性阻燃整理技术研究[J]. 浙江理工大学学报, 2008, 25(3):261-265.
LIU Xiaoyun, SHAO Jianzhong. Study on durable flame-retardant finish of cotton fabrics[J]. Journal of Zhejiang Sci-Tech University, 2008, 25(3):261-265.
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