纺织学报 ›› 2021, Vol. 42 ›› Issue (10): 120-125.doi: 10.13475/j.fzxb.20201003506

• 染整与化学品 • 上一篇    下一篇

电雾化处理对羊毛织物抗起毛起球性能的影响

周慧玲1,2, 朱俐莎1,2, 吴雄英3, 丁雪梅1,2()   

  1. 1.东华大学 服装与艺术设计学院, 上海 200051
    2.东华大学 现代服装设计与技术教育部重点实验室, 上海 200051
    3.上海海关, 上海 200135
  • 收稿日期:2020-10-20 修回日期:2021-07-12 出版日期:2021-10-15 发布日期:2021-10-29
  • 通讯作者: 丁雪梅
  • 作者简介:周慧玲(1995—),女,硕士生。主要研究方向为服装舒适性与功能服装研究。
  • 基金资助:
    中央高校基本科研业务费专项基金资助项目(2232020G-08);国家重点研发计划项目(2019YFB1706304)

Effect of electro-spraying treatment on anti-pilling performance of wool fabrics

ZHOU Huiling1,2, ZHU Lisha1,2, WU Xiongying3, DING Xuemei1,2()   

  1. 1. College of Fashion and Design, Donghua University, Shanghai 200051, China
    2. Key Laboratory of Clothing Design & Technology, Ministry of Education, Donghua University, Shanghai 200051, China
    3. Shanghai Customs, Shanghai 200135, China
  • Received:2020-10-20 Revised:2021-07-12 Published:2021-10-15 Online:2021-10-29
  • Contact: DING Xuemei

RichHTML

16

PDF (PC)

82

摘要：

针对羊毛织物在穿着时受外力摩擦作用易起毛起球的现象,采用可产生单分散小尺寸微粒的电雾化技术整理羊毛织物。实验选用常见的环保型整理剂过氧化氢和壳聚糖溶液,探究整理剂类型、溶液浓度和处理时间对羊毛织物抗起毛起球性能的影响,并通过扫描电子显微镜观察电雾化整理前后羊毛织物和纤维表面的形貌变化。结果表明:电雾化处理壳聚糖溶液产生的微粒对羊毛纤维表面起到了包裹作用,羊毛织物抗起毛起球等级最高提升1级以上;电雾化处理过氧化氢溶液对羊毛纤维表面鳞片有一定的破坏作用,羊毛织物抗起毛起球等级可提升0.5级以上;电雾化处理过氧化氢和壳聚糖溶液对羊毛织物协同整理较长时间(如240 min),织物的抗起毛起球提升效果最好。

关键词: 电雾化, 羊毛织物, 抗起毛起球, 壳聚糖, 过氧化氢

Abstract:

Wool fabrics are prone to fuzzing and pilling when they are worn by external forces. To deal with this problem, the electro-spraying technique capable of producing monodisperse micro liquid particles was used to treat wool fabrics. Commonly used finishing agents hydrogen peroxide and chitosan solution were employed in the experiments to explore the effects of finishing agent type, solution concentration and treatment time on anti-pilling performance of wool fabrics, and the morphological changes of the wool fabrics and fiber surfaces after electro-atomization finishing were observed by scanning electron microscope. The results show that the particles produced by electro-spraying chitosan solution encapsulates the surface of the wool fiber, and the anti-pilling result is increased by more than 1 level. After electro-spraying of hydrogen peroxide solution, a certain destructive effect was observed on the surface scales of the wool fiber, and the anti-pilling grade is increased by more than 0.5 level. Joint electro-spraying hydrogen peroxide and chitosan solution treatment to the wool fabrics for a long time (e.g. 240min) demonstrates the best anti-pilling effect.

Key words: electrospraying, wool fabric, anti-pilling, chitosan, hydrogen peroxide

中图分类号: 

  • TS101

图1

电雾化实验装置示意图"

图2

壳聚糖质量分数和处理时间对羊毛织物抗起毛起球性能的影响"

图3

未处理和壳聚糖整理样品的起毛起球照片"

图4

不同质量分数壳聚糖溶液整理后的纤维表面形貌(×1 000)"

图5

壳聚糖溶液整理前后的羊毛织物表面形貌(×200)"

图6

过氧化氢溶液质量分数和处理时间对羊毛织物抗起毛起球性能的影响"

图7

未处理样和过氧化氢处理样的起毛起球照片"

图8

过氧化氢溶液整理前后的羊毛纤维表面形貌"

图9

不同方式处理后羊毛织物抗起毛起球评级结果"

图10

不同方式处理下羊毛织物的起毛起球情况"

图11

3%过氧化氢和0.4%壳聚糖溶液协同整理240 min后的羊毛纤维表面形貌"

[1] 王艳, 刘阳, 贾心洁. 羊毛抗起毛起球整理工艺的研究进展[J]. 天津纺织科技, 2017(5):59-62.
WANG Yan, LIU Yang. JIA Xinjie. Review and prospect of the anti-pilling processing technology of wool[J]. Tianjin Textile Science Technology, 2017(5):59-62.
[2] 周爱晖, 范雪荣, 王强, 等. 预处理在羊毛酶法防毡缩中的作用[J]. 毛纺科技, 2008, 36(8):14-18.
ZHOU Aihui, FAN Xuerong, WANG Qiang, et al. Effects of pretreatment on wool shrink-resistance finishing with enzyme[J]. Wool Textile Journal, 2008, 36(8):14-18.
[3] 袁久刚, 王强, 范雪荣, 等. 离子液体/蛋白酶对羊毛表面的亲水化改性[J]. 纺织学报, 2010, 31(3):83-87.
YUAN Jiugang, WANG Qiang, FAN Xuerong, et al. Hydrophilic surface modification of wool by ionic liquid/protease treatment[J]. Journal of Textile Research, 2010, 31(3):83-87.
[4] 邓炳耀, 高卫东, 费燕娜. 常压等离子体处理对羊毛纤维表面性能的影响[J]. 毛纺科技, 2009, 37(12):17-19.
DENG Bingyao, GAO Weidong, FEI Yanna. Effect on surface properties of wool fiber treated with atmospheric pressure plasma[J]. Wool Textile Journal, 2009, 37(12):17-19.
[5] 陈怡秀, 赵群, 阎克路. 纤维素晶须在羊毛防毡缩整理中的应用[J]. 毛纺科技, 2013, 41(3) : 6-9.
CHEN Yixiu, ZHAO Qun, YAN Kelu. Application of cellulose whiskers on wool proofing shrink finishing[J]. Wool Textile Journal, 2013, 41(3) : 6-9.
[6] 宋伟新, 赵雪. 壳聚糖胍盐酸盐在羊毛织物抗皱整理中的应用[J]. 毛纺科技, 2018, 46(3):28-31.
SONG Weixin, ZHAO Xue. Study on crease resistant finishing process of chitosan guanidine hydrochloride for wool fabric[J]. Wool Textile Journal, 2018, 46(3):28-31.
[7] 花兆辉, 杨丹, 孙卫国. 等离子体/壳聚糖联合处理对羊毛防缩性能的影响[J]. 西安工程大学学报, 2011, 25(3):144-148.
HUA Zhaohui, YANG Dan, SUN Weiguo. The effect on shrink-resistance of wool fabric with plasma/chitosan co-processing[J]. Journal of Xi'an Polytechnic University, 2011, 25(3):144-148.
[8] WANG C X, DU M, LV J C, et al. Effect of wetting pretreatment on structure and properties of plasma induced chitosan grafted wool fabric[J]. Fibers & Polymers, 2015, 16(2):404-412.
[9] 谢珍, 杜壮, 阎克路. 蛋白酶和有机硅改性聚氨酯联合防毡缩工艺[J]. 毛纺科技, 2017, 45(9):27-33.
XIE Zhen, DU Zhuang, YAN Kelu. Anti-felting process of wool fabric by protease and polysiloxane modified waterborne polyurethane[J]. Wool Textile Journal, 2017, 45(9):27-33.
[10] 尹协振, 李芳. 电雾化、电纺丝和带电射流稳定性研究[J]. 力学与实践, 2009, 31(1):1-7.
YIN Xiezhen, LI Fang. Electrospraying, electrospinning and instability of electrified jets[J]. Mechanics in Engineering, 2009, 31(1):1-7.
[11] 张宝琪, 李振海, 张凌, 等. 凝水对纳米水离子装置净化效果影响探究[J]. 建筑热能通风空调, 2016, 35(12):41-44.
ZHANG Baoqi, LI Zhenhai, ZHANG Ling, et al. Discussion and research on performance effect of condensate water on nano-water ion purifier[J]. Building Energy & Environment, 2016, 35(12):41-44.
[12] 朱远杰, 李振海, 张宝琪, 等. 纳米水离子对异味去除效果的实验研究[J]. 建筑热能通风空调, 2018, 37(11):34-37.
ZHU Yuanjie, LI Zhenhai, ZHANG Baoqi, et al. An experimental study on the removal of odor by nano water ion generator[J]. Building Energy & Environment, 2018, 37(11):34-37.
[13] VAZE Nachiket, PYRGIOTAKIS Georgios, MENA Lucas, et al. A nano-carrier platform for the targeted delivery of nature-inspired antimicrobials using engineered water nanostructures for food safety applications[J]. Food Control, 2019, 96:365-374.
doi: 10.1016/j.foodcont.2018.09.037 pmid: 32132770
[14] VAZE Nachiket, JIANG Yi, MENA Lucas, et al. An integrated electrolysis-electrospray-ionization antimicrobial platform using engineered water nanostructures (EWNS) for food safety applications[J]. Food Control, 2018, 85:151-160.
doi: 10.1016/j.foodcont.2017.09.034 pmid: 29332999
[15] PYRGIOTAKIS Georgios, VEDANTAM Pallavi, CIRENZA Caroline, et al. Optimization of a nanotechnology based antimicrobial platform for food safety applications using engineered water nanostructures (EWNS)[J]. Sci Rep, 2016, 6:21073.
doi: 10.1038/srep21073
[16] WAITS C M, HANRAHAN B, LEE I. Multiplexed electrospray scaling for liquid fuel injection[J]. Journal of Micromechanics and Microengineering, 2010, 20(10):104-110.
[17] 李星光, 刘建河, 许晏铭. 静电雾化技术在农药喷洒中的应用研究[J]. 新型工业化, 2017, 7(9):53-57.
LI Xingguang, LIU Jianhe, XU Yanming. Study on application of pesticide spraying by electrostatic atomization technology[J]. The Journal of New Industrialization, 2017, 7(9):53-57.
[18] 施丽君, 周涓, 朱君, 等. 静电雾化技术在生物医药材料中的应用[J]. 材料导报, 2013, 27(13):138-144.
SHI Lijun, ZHOU Juan, ZHU Jun, et al. Applications of electrospraying in biomedicine and biomaterials[J]. Materials Reports, 2013, 27(13):138-144.
[19] 赵扬, 姜佳昕, 陈冬阳, 等. 气辅式多射流纳米颗粒高效静电雾化喷射[J]. 光学精密工程, 2015, 23(4):1062-1069.
ZHAO Yang, JIANG Jiaxin, CHEN Dongyang, et al. High efficiency multi-jet electrospraying of nano particles with assisted gas[J]. Optics and Precision Engineering, 2015, 23(4):1062-1069.
doi: 10.3788/OPE.
[20] MIAO P, BALACHANDRAN W, XIAO P. Formation of ceramic thin films using electrospray incone-jet mode[J]. IEEE Transactions on Industry Applications, 2002, 38(1):50-56.
doi: 10.1109/28.980346
[21] 毛惠敏. 静电雾化沉积制备薄膜材料的研究[D]. 镇江:江苏大学, 2007: 1-46.
MAO Huimin. Research on the fabrication of thin-film materials by electrostatic spray deposition tech-niques[D]. Zhenjiang: Jiangsu University, 2007: 1-46.
[22] DASDEMIR Mehmet, IBILI Hatice. Formation and characterization of superhydrophobic and alcohol-repellent nonwovens via electrohydrodynamic atomiza-tion (electrospraying)[J]. Journal of Industrial Textiles, 2016, 47(1):125-146.
doi: 10.1177/1528083716639061
[23] GÜNESOGLU C, KUT Dilek, ORHAN Mehmet. Performing the electrospraying process for the application of textile nano finishing particles[J]. Textile Research Journal, 2009, 80(2):106-115.
doi: 10.1177/0040517509106108
[24] ISLAM Saniyat, JADHAV Amit, FANG Jian, et al. Surface deposition of chitosan on wool substrate by electrospraying[J]. Advanced Materials Research, 2011, 331:165-170.
doi: 10.4028/www.scientific.net/AMR.331
[25] 王海朋. 亲疏水改性聚己内酯及电喷法制备聚合物微球涂层整理棉织物[D]. 苏州:苏州大学, 2018:45-67.
WANG Haipeng. Hydrophilic and hydrophobic modification of PCL and preparation of microsphere on cotton fabric via electrospraying[D]. Suzhou: Soochow University, 2018:45-67.
[26] 陈维国, 关立平. 壳聚糖在羊毛表面的吸附性能研究[J]. 丝绸技术, 1999, 7(1):4-7.
CHEN Weiguo, GUAN Liping. Study on the adsorption properties of chitosan on wool surface[J]. Advanced Textile Technology, 1999, 7(1):4-7.
[1] 刘淑萍 李亮 刘让同 胡泽栋 耿长军. 棉织物3-氨丙基三乙氧基硅烷阻燃整理研究[J]. , 2021, 42(10): 0-0.
[2] 周慧玲 朱俐莎 吴雄英 丁雪梅. 电雾化处理对羊毛织物抗起毛起球性能的影响[J]. , 2021, 42(10): 0-0.
[3] 刘淑萍, 李亮, 刘让同, 胡泽栋, 耿长军. 棉织物的3-氨丙基三乙氧基硅烷阻燃整理[J]. 纺织学报, 2021, 42(10): 107-114.
[4] 张帆, 张国波, 赵宇新, 张儒, 阳海, 王世豪, 汪南方. 催化氧化皂洗在涤纶/棉织物一浴染色中的应用[J]. 纺织学报, 2021, 42(09): 97-103.
[5] 潘佳俊, 夏兆鹏, 张海宝, 卢杨, 赵吉林, 王学农, 王亮, 刘雍. 牦牛绒过氧化氢/过硫酸铵脱色体系工艺优化及其机制[J]. 纺织学报, 2021, 42(04): 101-106.
[6] 何雪梅, 冒海燕, 蔡露. 壳聚糖基杂化气凝胶对活性染料的吸附性能[J]. 纺织学报, 2021, 42(02): 148-155.
[7] 于佳, 辛斌杰, 卓婷婷, 周曦. 高导电性铜/聚吡咯涂层羊毛织物的制备与表征[J]. 纺织学报, 2021, 42(01): 112-117.
[8] 汪希铭, 程凤, 高晶, 王璐. 交联改性对敷料用壳聚糖/聚氧化乙烯纳米纤维膜性能的影响[J]. 纺织学报, 2020, 41(12): 31-36.
[9] 向忠, 王宇航, 吴金波, 钱淼, 胡旭东. 过氧化氢检测方法研究进展[J]. 纺织学报, 2020, 41(10): 197-204.
[10] 刘雷艮, 沈忠安, 林振锋, 陶金. 聚乳酸/壳聚糖/Fe3O4超细纤维膜对酸性蓝MTR的吸附性能及机制[J]. 纺织学报, 2020, 41(05): 20-24.
[11] 郑宏飞, 汪瑞琪, 汪庆, 朱莹, 许云辉. 氧化壳聚糖改性抗菌蚕丝织物的制备及其性能[J]. 纺织学报, 2020, 41(05): 121-128.
[12] 王浩, 杜兆芳, 许云辉. 氧化壳聚糖/丝胶复合物的制备及其对棉织物的功能整理[J]. 纺织学报, 2019, 40(11): 119-124.
[13] 张治斌, 李刚, 毛森贤, 厉巽巽, 陈玉霜, 毛青山, 李翼, 潘志娟, 王晓沁. 丝素蛋白/壳聚糖微球制备及其抗菌性能[J]. 纺织学报, 2019, 40(10): 7-12.
[14] 安芳芳, 房宽峻, 刘秀明, 蔡玉青, 韩双, 杨海贞. 羊毛织物的蛋白酶改性对墨滴铺展及颜色性能的影响[J]. 纺织学报, 2019, 40(06): 58-63.
[15] 秦益民. 壳聚糖纤维的理化性能和生物活性研究进展[J]. 纺织学报, 2019, 40(05): 170-176.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发