纺织学报 ›› 2022, Vol. 43 ›› Issue (03): 201-209.doi: 10.13475/j.fzxb.20201104309

• 综合述评 • 上一篇    下一篇

纳米纤维负载型纳米零价铁基材料在环境修复中的应用研究进展

金旭1,2,3, 刘方1,2,3, 杜嬛4, 华超4, 公旭中4, 张秀芹1,2,3, 汪滨1,2,3()   

  1. 1.北京服装学院 材料设计与工程学院, 北京 100029
    2.北京服装学院 服装材料研究开发与评价北京市重点实验室, 北京 100029
    3.北京市纺织纳米纤维工程技术研究中心, 北京 100029
    4.中国科学院过程工程研究所 中国科学院绿色过程与工程重点实验室, 北京 100190
  • 收稿日期:2020-11-19 修回日期:2021-08-14 出版日期:2022-03-15 发布日期:2022-03-29
  • 通讯作者: 汪滨
  • 作者简介:金旭(1999—),男,硕士生。主要研究方向为功能与智能纤维材料。
  • 基金资助:
    国家重点研发计划项目(2020YFC1909605);国家级大学生创新创业训练计划项目(2020100120832);国家级大学生创新创业训练计划项目(202110012001);中国科学院绿色过程制造创新研究院联合基金项目(IAGM2020C08);北京高等学校“实培计划”项目(RCPY1903-30227);北京服装学院教改重点项目(ZDJG-1903);北京青少年创新学院“翱翔计划”项目(H2019-80)

Research progress in nanofiber supported nano zero-valent-iron based materials in environmental remediation

JIN Xu1,2,3, LIU Fang1,2,3, DU Xuan4, HUA Chao4, GONG Xuzhong4, ZHANG Xiuqin1,2,3, WANG Bin1,2,3()   

  1. 1. School of Materials Design & Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China
    2. Beijing Key Laboratory of Clothing Materials R & D and Assessment, Beijing Institute of Fashion Technology, Beijing 100029, China
    3. Beijing Engineering Research Center of Textile Nano Fiber, Beijing 100029, China
    4. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2020-11-19 Revised:2021-08-14 Published:2022-03-15 Online:2022-03-29
  • Contact: WANG Bin

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摘要：

针对纳米零价铁(nZVI)复合材料存在易团聚和难分离回收等缺陷,导致其降解效率下降、使用寿命变短等问题,首先介绍了nZVI的制备方法及负载型nZVI基材料在治理土壤污染和水体污染等领域的最新研究成果,分析了nZVI去除污染物的反应原理;重点总结归纳了聚丙烯酸/聚乙烯醇复合纳米纤维膜、壳聚糖复合纳米纤维膜、聚苯胺纳米纤维膜、碳纳米纤维膜等纳米纤维负载型nZVI基材料的制备方法及其去除污染物效果;最后提出以静电纺丝纳米纤维为代表的载体材料,可以有效抑制nZVI团聚,提高分离回收性能及拓宽其实际应用范围,是负载型nZVI基材料应用于环境修复的新型有效载体。

关键词: 纳米零价铁, 氧化还原法, 环境修复, 纳米纤维, 非金属矿物, 静电纺丝

Abstract:

Nano zero-valent-iron (nZVI) composites are associated with defects such as easy agglomeration and difficulty in separation and recovery, which lead to declined degradation efficiency and reduced service life. The preparation methods of nZVI and the latest research results of nZVI based materials in the field of soil and water pollution control were introduced. The reaction principle of nZVI to remove pollutants was discussed and analyzed. The preparation methods and pollutant removal effects of nanofiber supported nZVI based materials such as membranes made from polyacrylic acid/polyvinyl alcohol (PVA) composite nanofiber, chitosan composite nanofiber, polyaniline nanofiber and carbon nanofiber were summarized respectively. The progress review revealed that the carrier material in the form of electrospun nanofibers can effectively inhibit the agglomeration of nZVI, improve the separation and recovery performance and broaden the practical application scope. Nanofibers are shown as a new effective carrier to load nZVI based materials for environmental remediation.

Key words: nano zero-valent-iron, redox, environmental remediation, nanofiber, nonmetallic mineral, electrospinning

中图分类号: 

  • TQ340.9

图1

nZVI体系中发生的主要反应和污染物去除机制"

图2

液相还原法制备nZVI的反应过程及反应机制"

表1

不同方法制备nZVI的优缺点"

制备方法 优点 缺点
机械物理法 操作简单、快捷 制备成本高
液相还原法 合成路线简单、反应条件温、设备易实现 造成环境污染
绿色合成法 原料来源丰富、操作简单、环境友好 技术不成熟

图3

nZVI粒子生长和再固定化示意图"

图4

CA纳米纤维表面组装聚电解质多层膜后固定nZVI颗粒的示意图"

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