磷/氮阻燃剂对涤纶/棉混纺织物的阻燃整理

doi:10.13475/j.fzxb.20210507707

纺织学报 ›› 2022, Vol. 43 ›› Issue (06): 94-99.doi: 10.13475/j.fzxb.20210507707

磷/氮阻燃剂对涤纶/棉混纺织物的阻燃整理

黄益婷¹^,², 程献伟¹^,², 关晋平¹^,²(), 陈国强¹^,²

1.苏州大学纺织与服装工程学院,江苏苏州 215021
2.苏州大学现代丝绸国家工程实验室, 江苏苏州 215021

收稿日期:2021-05-27 修回日期:2022-03-24 出版日期:2022-06-15 发布日期:2022-07-15
通讯作者: 关晋平
作者简介:黄益婷(1996—),女,硕士生。主要研究方向为纺织品阻燃功能改性。
基金资助:
江苏省高校优势学科建设工程项目(2018-87);纺织行业纺织材料阻燃整理重点实验室项目(Q811580421)

Phosphorus/nitrogen-containing flame retardant for flame retardant finishing of polyester/cotton blended fabric

HUANG Yiting¹^,², CHENG Xianwei¹^,², GUAN Jinping¹^,²(), CHEN Guoqiang¹^,²

1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
2. National Engineering Laboratory for Modern Silk, Soochow University, Suzhou, Jiangsu 215021, China

Received:2021-05-27 Revised:2022-03-24 Published:2022-06-15 Online:2022-07-15
Contact: GUAN Jinping

摘要/Abstract

摘要：

为赋予涤纶/棉混纺织物良好的阻燃性能,采用生物质植酸和尿素合成植酸铵盐,通过轧—烘—焙工艺对涤纶/棉混纺织物进行整理。借助傅里叶红外光谱仪对合成阻燃剂植酸铵盐进行表征,并研究了整理后涤纶/棉混纺织物的表面形貌、热稳定性、热释放性能、阻燃性能及其阻燃机制。结果表明:整理后涤纶/棉混纺织物的阻燃性能较好,极限氧指数升高至25.6%,在垂直燃烧测试中能够自熄,炭长降低为12 cm,满足GB/T 17591—2006《阻燃织物》中B₁级阻燃性能的要求;整理后涤纶/棉混纺织物的热稳定性提高,热释放能力降低;植酸铵盐主要通过膨胀型阻燃机制提高涤纶/棉混纺织物的阻燃性能。

关键词: 功能性纺织品, 涤纶/棉混纺织物, 阻燃整理, 植酸, 支架效应, 膨胀型阻燃机制

Abstract:

The development of flame retardant polyester/cotton blended fabrics is of great interest. In this study, ammonium phytate salt was synthesized using biomass phytic acid and urea, and applied to improve the flame retardancy of polyester/cotton blended fabric through pad-dry-cure process. The ammonium phytate salt was characterized with the Attenuated total reflection Flourier transformed infrared spectra. The surface morphology, thermal stability, heat release capacity, flame retardancy and mechanism of the treated polyester/cotton blended fabric were explored. The results showed that the treated polyester/cotton blended fabrics had good flame retardancy. The LOI value of treated fabrics was increased to 25.6%. During the vertical burning test, the treated fabrics could self-extinguish and had the reduced char length of 12 cm, meeting the B₁ classification according to GB/T 17591—2006 "Flame retardant textiles". Besides, the treated fabrics showed higher thermal stability and lower heat release ability. Ammonium phytate salt improved the flame retardant properties of polyester/cotton blended fabrics through an intumescent flame retardant mechanism.

Key words: functional textile, polyester/cotton blended fabric, flame retardant finishing, phytic acid, scaffolding effect, intumescent flame retardant mechanism

中图分类号:

TQ342.21

黄益婷, 程献伟, 关晋平, 陈国强. 磷/氮阻燃剂对涤纶/棉混纺织物的阻燃整理[J]. 纺织学报, 2022, 43(06): 94-99.

HUANG Yiting, CHENG Xianwei, GUAN Jinping, CHEN Guoqiang. Phosphorus/nitrogen-containing flame retardant for flame retardant finishing of polyester/cotton blended fabric[J]. Journal of Textile Research, 2022, 43(06): 94-99.

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参考文献 20

[1]	张硕, 胡雪敏, 葛凤燕, 等. 涤纶/棉织物拒水拒油整理及性能[J]. 国际纺织导报, 2019, 47(11): 28-30,32-36.
	ZHANG Shuo, HU Xuemin, GE Fengyan, et al. Water and oil repellent finishing and properties of polyester/cotton fabrics[J]. Melliand China, 2019, 47(11): 28-30, 32-36.
[2]	陈威, 关晋平, 陈国强, 等. 涤棉混纺织物的燃烧行为[J]. 印染, 2016, 42(4): 6-8.
	CHEN Wei, GUAN Jinping, CHEN Guoqiang, et al. Combustion behavior of polyester-cotton blended fabric[J]. China Dyeing & Finishing, 2016, 42(4): 6-8.
[3]	陈威, 关晋平, 陈国强, 等. 静电层层自组装法整理多巴胺改性涤纶/棉混纺织物的阻燃性能[J]. 纺织学报, 2017, 38(9): 94-100.
	CHEN Wei, GUAN Jinping, CHEN Guoqiang, et al. The flame retardant properties of dopamine modified polyester/cotton blended fabric finished by electrostatic self-assembly method[J]. Journal of Textile Research, 2017, 38(9): 94-100.
[4]	NOROUZI M, ZARE Y, KIANY P. Nanoparticles as effective flame retardants for natural and synthetic textile polymers: application, mechanism, and optimiza-tion[J]. Polymer Reviews, 2015, 55(3): 1-30. doi: 10.1080/15583724.2014.958771
[5]	刘龙祥. 阻燃与超疏水涤棉织物的制备及其性能研究[D]. 合肥: 中国科学技术大学, 2019: 3-5.
	LIU Longxiang. Preparation and properties of flame retardant and superhydrophobic polyester/cotton fabrics[D]. Hefei: University of Science and Technology of China, 2019: 3-5.
[6]	YANGT T, GUAN J P, TANG R C, et al. Condensed tannin from Dioscorea cirrhosa tuber as an eco-friendly and durable flame retardant for silk textile[J]. Industrial Crops & Products, 2018, 115: 16-25.
[7]	张泽, 刘帅东, 崔永岩. 植酸在聚合物材料阻燃应用领域的研究进展[J]. 中国塑料, 2021, 35(3): 139-150. doi: 10.19491/j.issn.1001-9278.2021.03.019
	ZHANG Ze, LIU Shuaidong, CUI Yongyan. Research progress of phytic acid in flame retardant application of polymer materials[J]. China Plastics, 2021, 35(3): 139-150. doi: 10.19491/j.issn.1001-9278.2021.03.019
[8]	方进, 张广知, 李海波. 植酸掺杂硅溶胶协同体系对棉织物的阻燃整理[J]. 印染, 2021, 47(4): 37-42.
	FNAG Jin, ZHANG Guangzhi, LI Haibo. The flame-retardant finishing of cotton fabrics with phytic acid doped silica sol synergistic system[J]. China Dyeing & Finishing, 2021, 47(4): 37-42.
[9]	刘延松, 程春组, 王阳, 等. 生物质植酸在阻燃纺织中的应用[J]. 印染, 2020, 46(9): 64-70.
	LIU Yansong, CHENG Chunzu, WANG Yang, et al. Application of biomass phytic acid in flame retardant textiles[J]. China Dyeing & Finishing, 2020, 46(9): 64-70.
[10]	CREDICO B D, LEVI M, TURRI S. An efficient method for the output of new self-repairing materials through a reactive isocyanate encapsulation[J]. European Polymer Journal, 2013, 49(9): 2467-2476. doi: 10.1016/j.eurpolymj.2013.02.006
[11]	GHOBASHY M M, MOUSAA I M, EL-SAYYAD G S. Radiation synthesis of urea/hydrogel core shells coated with three different natural oils via a layer-by-ayer approach: an investigation of their slow release and effects on plant growth-promoting rhizobacteria[J]. Progress in Organic Coatings, 2021. 151.DOI: org/10.1016/j.porgcoat.2020.106022. doi: org/10.1016/j.porgcoat.2020.106022
[12]	陶俊杰, 王凌云, 董佳豪, 等. 植酸改性石墨烯的制备及其在防腐涂层中的应用[J]. 涂料工业, 2020, 50(2): 14-21.
	TAO Junjie, WANG Lingyun, DONG Jiahao, et al. Preparation of phytic acid modified graphene and its application in anti-corrosion coatings[J]. Paint Industry, 2020, 50(2): 14-21.
[13]	刘新华, 刘海龙, 方寅春, 等. 聚乙烯亚胺/植酸层层自组装阻燃涤纶/棉混纺织物制备及其性能[J]. 纺织学报, 2021, 42(11): 103-109.
	LIU Xinhua, LIU Hailong, FANG Yinchun, et al. Preparation and properties of polyethyleneimine/phytic acid layer-by-layer self-assembled flame retardant polyester/cotton blended fabric[J]. Journal of Textile Research, 2021, 42(11): 103-109.
[14]	刘宗法, 王钟, 戴顺华, 等. 基于磷酸酯的阻燃涤纶织物的研发[J]. 现代丝绸科学与技术, 2020, 35(3): 4-6, 40.
	LIU Zongfa, WANG Zhong, DAI Shunhua, et al. Research and development of flame retardant polyester fabric based on phosphate[J]. Modern Silk Science and Technology, 2020, 35(3): 4-6, 40.
[15]	XU F, ZHONG L, XU Y, et al. Highly efficient flame-retardant and soft cotton fabric prepared by a novel reactive flame retardant[J]. Cellulose, 2019, 26(6): 4225-4240. doi: 10.1007/s10570-019-02374-4
[16]	袁小铃, 徐丽慧, 万晶, 等. 基于疏水型二氧化硅气凝胶制备无氟自清洁超疏水棉织物[J]. 印染, 2021, 47(2): 40-44.
	YUAN Xiaoling, XU Lihui, WAN Jing, et al. Preparation of fluorine-free self-cleaning superhydrophobic cotton fabric based on hydrophobic silica aerogel[J]. China Dyeing & Finishing, 2021, 47(2): 40-44.
[17]	马亚男, 沈军炎, 骆晓蕾, 等. 高效无卤阻燃棉织物的制备及其结构与性能[J]. 纺织学报, 2021, 42(3): 122-129.
	MA Ya'nan, SHEN Junyan, LUO Xiaolei, et al. Preparation of high-efficiency halogen-free flame-retardant cotton fabric and its structure and proper-ties[J]. Journal of Textile Research, 2021, 42(3): 122-129. doi: 10.1177/004051757204200209
[18]	XU X, BAI B, MA M, et al. Surface carboxyl-activated polyester (PET) fibers decorated with glucose carbon microspheres and their enhanced selective adsorption for dyes[J]. Journal of Physics and Chemistry of Solids, 2018, 123: 378-388. doi: 10.1016/j.jpcs.2018.08.005
[19]	孙晓璐, 蔡令令, 蔡以兵, 等. 层层自组装SiO₂阻燃棉织物的制备及其性能[J]. 材料科学与工程学报, 2020, 38(5): 811-816, 830.
	SUN Xiaolu, CAI Lingling, CAI Yibing, et al. Preparation and properties of layer-by-layer self-assembled SiO₂ flame-retardant cotton fabric[J]. Chinese Journal of Materials Science and Engineering, 2020, 38(5): 811-816, 830.
[20]	吴燕祥, 关晋平, 肖文成, 等. 涤纶织物的三聚氰胺植酸盐膨胀阻燃整理[J]. 印染, 2021, 47(1): 40-43, 80.
	WU Yanxiang, GUAN Jinping, XIAO Wencheng, et al. Melamine phytate intumescent flame retardant finishing of polyester fabric[J]. China Dyeing & Finishhing, 2021, 47(1): 40-43, 80.

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质量浓度/ (g·L^-1)	质量增加率/%	极限氧指数/%	损毁长度/cm
0	0	17.1	30.0
100	10.9	24.8	30.0
200	16.3	25.6	12.0
300	27.4	28.2	10.5
400	27.8	29.3	9.5

样品	p_HRR/ (W·g^-1)	C_HR/ (J·(g·K)^-1)	T_HR/ (kJ·g^-1)	残炭率/%
阻燃整理前	441.1	236	19.9	0.4
阻燃整理后	425.7	194	8.9	12.2

样品	断裂强力/N	断裂伸长率/%	抗弯长度/mm	白度/ %
阻燃整理前	605.3	13.4	16.3	85.1
阻燃整理后	579.2	17.9	17.4	77.2

磷/氮阻燃剂对涤纶/棉混纺织物的阻燃整理

Phosphorus/nitrogen-containing flame retardant for flame retardant finishing of polyester/cotton blended fabric

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