纺织学报 ›› 2022, Vol. 43 ›› Issue (08): 88-94.doi: 10.13475/j.fzxb.20210506307

• 染整与化学品 • 上一篇    下一篇

非对称润湿特性纺织基材上高稳固光子晶体的构筑

张星月1, 韩朋帅1, 王一萌2, 张耘箫2, 周岚1,3, 刘国金1,2()   

  1. 1.浙江理工大学 先进纺织材料与制备技术教育部重点实验室, 浙江 杭州 310018
    2.浙江理工大学 浙江省纤维材料和加工技术研究重点实验室, 浙江 杭州 310018
    3.浙江省绿色清洁技术及洗涤用品重点实验室, 浙江 丽水 323000
  • 收稿日期:2021-05-24 修回日期:2022-05-17 出版日期:2022-08-15 发布日期:2022-08-24
  • 通讯作者: 刘国金
  • 作者简介:张星月(1999—),女,硕士生。主要研究方向为纺织品光子晶体结构生色。
  • 基金资助:
    国家自然科学基金项目(52003242);浙江省自然科学基金项目(LY20E030006);浙江省自然科学基金项目(LQ19E030022);国家级大学生创新创业训练计划项目(202010338003)

Construction of highly stable photonic crystals on textile substrates with asymmetric wetting characteristics

ZHANG Xingyue1, HAN Pengshuai1, WANG Yimeng2, ZHANG Yunxiao2, ZHOU Lan1,3, LIU Guojin1,2()   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    3. Zhejiang Provincial Key Laboratory of Green Cleaning Technology and Washing Products, Lishui, Zhejiang 323000, China
  • Received:2021-05-24 Revised:2022-05-17 Published:2022-08-15 Online:2022-08-24
  • Contact: LIU Guojin

摘要:

为提升纺织基材上光子晶体结构色的耐久性,从印花色浆性能和基材润湿性2个角度切入,以具有自交联特性的聚(苯乙烯–N–羟甲基丙烯酰胺)(P(St-NMA))胶体微球为主要成分制备印花色浆,采用丝网印花法在具有非对称润湿特性的纺织基材上构筑光子晶体生色结构,并测试制备所得光子晶体在纺织基材上的稳固性。结果表明:当印花色浆中微球质量分数为80%、自交联促进剂盐酸质量分数为5%10%时,有助于得到结构色鲜艳且结构稳固的光子晶体;采用等离子体技术可实现纺织基材的非对称润湿特性,当处理时间为3 min时,可得到正、反面接触角为56°和110°的纺织基材,且在此基材正面构筑得到的光子晶体能够兼顾结构色效果和结构稳固性。

关键词: 非对称润湿, 纺织基材, 丝网印刷, 光子晶体, 结构色

Abstract:

In order to improve the durability of structural colors produced from photonic crystals on textile substrates, a printing paste was prepared considering printing paste performance and substrate wettability, with self-crosslinking poly(styrene–N–hydroxymethylacrylamide) (P(St-NMA)) colloidal microspheres as the main component. Screen printing method was used to construct the highly stable photonic crystals on textile substrates with asymmetric wetting characteristics. The stability of photonic crystal chromogenic structure on textile substrate was tested. The results show that when the concentration of microspheres in printing paste is 80% and the concentration of self-crosslinking accelerator hydrochloric acid is 5%–10%, photonic crystals with bright color and stable structure are obtained. The asymmetric wetting characteristics of the substrate can be achieved by plasma technology. When the treatment time is 3 min, the textile substrates with face and back contact angles of 56° and 110° can be obtained respectively, and photonic crystals with both structural color effect and structural stability can be constructed on the substrate face.

Key words: asymmetric wetting, textile substrate, screen printing, photonic crystal, structural color

中图分类号: 

  • TS193.2

图1

P(St-NMA)胶体微球的FESEM和TEM图像"

图2

不同质量分数P(St-NMA)胶体微球在棉织物表面自组装所得光子晶体生色结构印花图案的数码相机照片、三维视频显微镜图像及FESEM图像"

图3

含不同质量分数盐酸的印花色浆在棉织物表面所得光子晶体生色结构印花图案的数码相机照片、三维视频显微镜图像及FESEM图像"

图4

结构色印花织物经摩擦前后的数码照片及三维视频显微镜图像"

图5

经等离子体处理不同时间后基材的接触角及印花图案"

图6

等离子体处理不同时间后织物上所得印花图案的三维视频显微镜图像和FESEM图像"

图7

等离子体处理不同时间后织物上印花图案经剥离后纤维上的FESEM图像"

图8

结构色印花织物的弯折测试过程及弯折前后三维视频显微镜图像(微球粒径为254 nm)"

图9

超声波水洗前后结构色印花织物照片及三维视频显微镜图像(微球粒径254 nm)"

图10

不同粒径胶体微球印花色浆所得结构色印花织物样品照片"

图11

不同粒径胶体微球所得结构色印花织物样品的反射率曲线"

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