纺织学报 ›› 2022, Vol. 43 ›› Issue (10): 192-199.doi: 10.13475/j.fzxb.20210608108

• 综合述评 • 上一篇    下一篇

纤维材料在柔性可穿戴锌电池中的应用进展

王津1,2, 胡开瑞2, 张刘飞3, 陈磊2()   

  1. 1.天津工业大学 艺术学院, 天津 300387
    2.天津工业大学 纺织科学与工程学院, 天津 300387
    3.中华人民共和国江阴海关, 江苏 无锡 214400
  • 收稿日期:2021-06-30 修回日期:2022-05-07 出版日期:2022-10-15 发布日期:2022-10-28
  • 通讯作者: 陈磊
  • 作者简介:王津(1975—),男,讲师,硕士。主要研究方向为智能服装柔性电池结构设计。
  • 基金资助:
    中国博士后科学基金特别资助项目(2019T120189)

Application progress of fiber materials in flexible wearable zinc batteries

WANG Jin1,2, HU Kairui2, ZHANG Liufei3, CHEN Lei2()   

  1. 1. School of Arts, Tiangong University, Tianjin 300387, China
    2. School of Textile Science and Engineering,Tiangong University, Tianjin 300387, China
    3. Jiangyin Customs District P.R. China, Wuxi, Jiangsu 214400, China
  • Received:2021-06-30 Revised:2022-05-07 Published:2022-10-15 Online:2022-10-28
  • Contact: CHEN Lei

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摘要：

为促进安全、低成本锌离子电池在柔性储能装置中的应用,以纤维材料基锌离子电池为研究对象,首先明晰了充放电过程中锌负极氧化反应及过渡金属氧化物或氧正极还原反应机制;其次探索了碳纤维、碳纳米纤维、碳纳米管纱线、金属纤维以及其他无机纤维等纤维材料,在柔性锌电池正极、负极和电解质等领域的应用研究现状,分析并类比了不同制备工艺、微结构、改性方式等对纤维基柔性电池电化学特性的调控效果,明确了影响其性能优劣的主要参数;最后提出纤维材料的结构有序化设计对于提升电池电化学性能具有显著效果,强调了天然纤维基电极材料广阔的发展前景。研究对于加速智能服装的产业化应用,助力“碳达峰、碳中和”愿景的早日实现具有积极的推动意义。

关键词: 纤维基材料, 柔性锌电池, 微结构, 电化学特性

Abstract:

In order to promote the application of zinc ion batteries with high safety and low cost in flexible energy storage devices, the paper takes fiber-based zinc ion batteries as the object and firstly clarifies the mechanism of zinc anode oxidation and transition metal oxide or oxygen positive cathode reduction in the process of charge and discharge proccess. Secondly, fibers such as carbon fiber, carbon nanofiber, carbon nanotube yarn, metal fiber and other inorganic fiber in the cathode, anode and electrolyte of flexible zinc battery are reviewed. The effects of different preparation processes, microstructure and modification strategies on the electrochemical characteristics of fiber-based flexible batteries are analyzed and compared, and the main parameters affecting its performance are defined. At last, it is proposed that the structural ordered design of fibers has a significant effect on improving the electrochemical performance of batteries, and the broad development prospect of natural fiber based electrode materials is emphasized. This paper has a positive significance for accelerating the industrial application of intelligent clothing and helping to realize the vision of "carbon peak and carbon neutralization" as soon as possible.

Key words: fiber-based material, flexible zinc battery, microstructure, electrochemical property

中图分类号: 

  • TQ028.2

表1

不同纤维材料基锌电池电化学特性对比"

正极材料 负极材料 电解质 比容量 能量密度 功率密度 循环性能 文献
钢纤维/NiCO(OH)x 不锈钢纤维/锌 PVA/Zn(CH3COO)2 5 mA·h/cm3 0.12 mW·h/cm2 32.8 mW/cm2 [43]
Mn-NiOx/Cu Zn/Li插层TiO2 PVA/KOH 19.6 mA·h/cm3 0.034 Wh·/cm3 17.5 W/cm3 20 000圈后放电容量95% [44]
NiO/CNFs/碳布 ZnO/CNFs/碳布 PVA/KOH 265 mA·h/g 7.76 mW·h/cm3 0.54 W/cm3 1 000圈后放电容量91.45% [34]
空气/N-NiSe2/碳布 锌箔 KOH/丙烯酸/
K2S2O8水凝胶		 504 mA·h/g [5]
空气/Co1-xFexO-NC/
碳布		 锌箔 KOH/醋酸锌 673 mA·h/g [10]
空气/N-Co3O4 锌包覆碳织物 碱性凝胶电解质 603.7 mA·h/g [15]
空气/Co3O4/碳纳米纤维 锌箔 KOH/ZnCl2溶液 125 mW/cm2 [21]
空气/Fe-CNFs 锌箔 KOH/醋酸锌 135 mW/cm2 [24]
空气/FeNi/N-CNTs 锌箔 KOH/醋酸锌 751 mA·h/g 917 W·h/kg 160.6 mW/cm2 960圈后无放电电压损耗 [27]
空气/Co/Co3O4杂化多孔CNFs 锌箔 KOH/Zn(CH3COO)2 748.5 mA·h/g 102 mW/cm2 [33]
空气/杂化多孔CNFs 锌箔 KOH/Zn(CH3COO)2 626 mA·h/g 776 W·h/kg 185 mW/cm2 500圈后电压间
隙增长0.13 V		 [33]
铁氰化锌/CNTs 锌/CNTs ZnSO4/纤维素 100.2 mA·h/cm3 195.4 mW·h/cm3 200圈后放电容量91.8% [39]
MnO2/CNTs 锌线 ZnCl2/PVA 290 mA·h/g 360 W·h/kg 100圈后放电容量98% [54]
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